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971.
Alkaline phosphatase activity is regulated by various hormones and growth factors at least in part through the phosphorylation of target proteins during the bone cell differentiation. To investigate the role of protein phosphorylation in alkaline phosphatase activity in MC3T3-E1 osteoblast, we used okadaic acid which is a potent specific inhibitor of serine/threonine protein phosphatases to type 1 and 2A. Alkaline phosphatase activity in cellular layer was measured by spectrophotometer using p-nitrophenyl phosphate as substrate and data were expressed as p-nitrophenyl of nmol/min/mg of protein. Okadaic acid (1-50 ng/ml) caused the inhibition of alkaline phosphatase activity in MC3TC-E1 cells. At 50 ng/ml of okadaic acid showed the maximal inhibitory effect on alkaline phosphatase activity. Okadaic acid (50 ng/ml) also inhibited alkaline phosphatase activity in all differentiation stages. These results indicate that okadaic acid inhibits alkaline phosphatase activity in MC3T3-E1 cells. 相似文献
972.
The reaction between hydrogen sulfide and lime is important, among others, as a component reaction of the hydrogen reduction
of metal sulfides in the presence of lime, and in the desulfurization of fossil fuels. The results of experiments on the kinetics
of this reaction are presented in this paper. The experiments were carried out in the temperature range 873 to 1073 K, using
a thermogravimetric analysis technique. A “pore blocking” model was found to fit the reaction rate, which was initially rapid
and leveled off at less than the complete conversion. An activation energy of 76.1 kJ/mol (18.2 kcal/g-mole) was obtained.
The reaction was first order with respect to hydrogen sulfide concentration in a gaseous mixture with hydrogen. A higher initial
moisture content in the calcium oxide particles resulted in a considerably higher reaction rate.
Formerly Graduate Student in the Department of Metallurgy and Metallurgical Engineering, University of Utah 相似文献
973.
A general model describing simultaneous independent reactions between one solid reactant and two fluid reactants is presented. Such reaction systems ar attention in the areas of oil shale retorting, direct reduction of metal oxides with reformed natural gas, coal gasification, etc.The model has been formulated in general terms so as to allow the incorporation of specific details of an actual system. The law of additive reaction t previously proposed for single fluid-solid reactions has been applied to the reaction system under consideration, and it has yielded useful approximate solutions for various aspects of the simultaneous reactions, which otherwise must be obtained by numerical methods. 相似文献
974.
S. Soepriyanto F. A. Olson H. Y. Sohn 《Metallurgical and Materials Transactions B》1989,20(2):237-242
The selective oxidation of mixed metal sulfides with lime in the presence of steam was studied as a function of the mixing
ratio of the constituents, temperature, and steam concentration. Two combinations of samples were used in this study: ZnS/PbS/CaO
and ZnS/FeS/CaO. The steam oxidizes one or both of the metal sulfides, and the hydrogen sulfide produced reacts with lime
to form calcium sulfide and regenerate steam. There is no net consumption or generation of gaseous species; therefore, this
process can be carried out in a closed system. The free energy of the reaction is negative only for certain metal sulfides,
and thus selective oxidation for mixed sulfides can be achieved. An overall rate equation developed in this work satisfactorily
predicted the experimental data obtained in the temperature range 823 to 1113 K. The potential implications of the results
of this work in the treatment of complex sulfide ores are discussed.
This paper is based on a presentation made in the T.B. King Memorial Symposium on “Physical Chemistry in Metals Processing”
presented at the Annual Meeting of The Metallurgical Society, Denver, CO, February, 1987, under the auspices of the Physical
Chemistry Committee and the PTD/ISS. 相似文献
975.
As an alternative to conventional smelting processes for producing metals from sulfide ores, which suffer from SO2 emission problems, direct reduction in the presence of lime has in recent years attracted much attention. In this work, a
mathematical model of successive gas-solid reactions in a porous pellet has been applied to the hydrogen reduction of cuprous
sulfide (Cu2S) in the presence of lime. The model has been formulated by incorporating the intrinsic kinetics of the individual reactions
obtained from separate experiments, and compared with the experimental results on the hydrogen reduction of chalcocite mixed
with lime particles. The model predictions were in good agreement with experimental measurements of the overall rate of reaction
and the degree of sulfur fixation over a wide range of experimental conditions. The mathematical model not only can predict
the performance of a given system but also enables one to design the optimum pellet properties and reaction conditions in
terms of the reaction rate and sulfur fixation.
Formerly Graduate Student in the Department of Metallurgy and Metallurgical Engineering, University of Utah. 相似文献
976.
Keun-Yong Park Minho Lee Byung-Ki Sohn 《Electronics letters》2001,37(8):495-497
The hydrogen ions present in an enzyme-immobilised membrane are diminished by hydroxide ions generated by a reduction potential. The recovery time of an ISFET glucose sensor using an electrolysis method has been reduced to <2 min in contrast to the 10 or 20 min required using a conventional method 相似文献
977.
Sang-Wook Park Hidehiro Kumazawa In-Joe Sohn 《Korean Journal of Chemical Engineering》2002,19(1):75-82
Unsteady-state absorption of CO2 into w/o emulsion was studied by experimental measurements and prediction from mathematical modeling. Absorption experiments
were performed by using a stirred vessel with a flat gas-liquid interface under 0.101 MPa and 25 °C. Continuous phase was
benzene that has larger solubility than water. Dispersed phase was an aqueous solution of NaOH and AMP. The effects of reactant
concentration, size of emulsified droplets, volume fraction of continuous phase and stirring speed on the absorption rate
of CO2 were investigated. In the mathematical model, the mechanism of CO2 absorption into the continuous phase through a gas-liquid interface was described on the basis of the penetration model,
while the subsequent absorption/reaction in the dispersed aqueous droplets was modeled by the film model. 相似文献
978.
An experimental and mathematical investigation of the removal of carbonaceous residue deposited on the ceramic substrate in the fabrication of multilayer ceramic modules has been conducted. Such carbonaceous residue is formed when the organic binder is pyrolyzed during the firing of greensheets. This paper is the second of a two-part series that reports on and discusses the principal findings of the investigation. In this paper we describe the removal of carbonaceous residue from large blocks of the multilayer ceramic module in which the diffusion of gaseous species may play a role. A mathematical model is developed using the Law of Additive Reaction Times for fluid-solid reactions, which incroporates the effects of intrinsic chemical kinetics, pore diffusion, and external mass transfer. This law gives an approximate solution to the governing equations which describe the removal of carbonaceous residue from the MLC module during firing. 相似文献
979.
980.
The thermo-migration fluxes of U, Pu and Zr in U-Pu-Zr metallic alloy fuel during irradiation in the Experimental Breeder Reactor II (EBR-II) were calculated using the constituent redistribution profiles measured in postirradiation examinations. Based on these fluxes, the diffusion coefficients, and the sums of heat of transport and enthalpy of solution for the γ, γ+ζ and δ+ζ phases in U-Pu-Zr were obtained. Using these data, the predicted concentration redistribution profiles are consistent with the measurements. The effect of minor actinide (Am and Np) addition was also examined. Am migration generally followed that of Zr with local precipitation, while Np behaved similarly to Pu. 相似文献