全文获取类型
收费全文 | 8166篇 |
免费 | 596篇 |
国内免费 | 24篇 |
专业分类
电工技术 | 152篇 |
综合类 | 16篇 |
化学工业 | 1915篇 |
金属工艺 | 302篇 |
机械仪表 | 500篇 |
建筑科学 | 137篇 |
矿业工程 | 8篇 |
能源动力 | 301篇 |
轻工业 | 752篇 |
水利工程 | 30篇 |
石油天然气 | 8篇 |
无线电 | 1405篇 |
一般工业技术 | 1722篇 |
冶金工业 | 453篇 |
原子能技术 | 122篇 |
自动化技术 | 963篇 |
出版年
2024年 | 8篇 |
2023年 | 94篇 |
2022年 | 140篇 |
2021年 | 243篇 |
2020年 | 170篇 |
2019年 | 203篇 |
2018年 | 266篇 |
2017年 | 256篇 |
2016年 | 311篇 |
2015年 | 278篇 |
2014年 | 394篇 |
2013年 | 522篇 |
2012年 | 529篇 |
2011年 | 668篇 |
2010年 | 426篇 |
2009年 | 503篇 |
2008年 | 454篇 |
2007年 | 352篇 |
2006年 | 346篇 |
2005年 | 274篇 |
2004年 | 260篇 |
2003年 | 244篇 |
2002年 | 224篇 |
2001年 | 189篇 |
2000年 | 156篇 |
1999年 | 167篇 |
1998年 | 236篇 |
1997年 | 160篇 |
1996年 | 105篇 |
1995年 | 102篇 |
1994年 | 84篇 |
1993年 | 77篇 |
1992年 | 53篇 |
1991年 | 44篇 |
1990年 | 38篇 |
1989年 | 30篇 |
1988年 | 13篇 |
1987年 | 21篇 |
1986年 | 18篇 |
1985年 | 18篇 |
1984年 | 21篇 |
1983年 | 13篇 |
1982年 | 8篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 7篇 |
1977年 | 8篇 |
1976年 | 16篇 |
1975年 | 5篇 |
1974年 | 4篇 |
排序方式: 共有8786条查询结果,搜索用时 0 毫秒
71.
72.
Zahid Hanif Zeeshan Ahmad Khan Dongho Shin Dongwhi Choi Sung Jea Park 《大分子材料与工程》2021,306(10):2100289
Cellulose nanocrystals (CNCs) incorporated with silver nanoparticles (AgNPs) photonic films have drawn considerable attention due to their plasmonic chiroptical activity. However, the exploitation of some fundamental properties for practical use such as the affinity analysis of metal nanoparticles attached to the surface of photonic films according to the solvent compatibility and antibacterial activity under physical conditions has yet not been studied. Hence, a facile process of in situ deposition of AgNPs into the chiral structure of CNC films is proposed. CNC photonic films, cross-linked by glutaraldehyde are prepared. This interaction generated the solvents-stable photonic film with a considerable amount of unreacted aldehyde functional groups that facilitates the reduction of Ag salt to AgNPs. The formed AgNPs in the photonic films show excellent stability over immersion in various polar and non-polar solvents. The post-solvent treated photonic films display excellent contact-based antibacterial behavior against gram-negative Escherichia coli. 相似文献
73.
S.?H.?Yu H.?S.?Ryoo S.?K.?HwangEmail author D.?H.?Shin 《Metals and Materials International》2003,9(2):107-114
Grain boundary character distribution in equal-channel-angular pressed Zr was studied. Using a die design of 90°/20° and an
operation temperature of 350°C. The initial grain size of 20 μm was reduced to about 270 nm with 4 passes via route Bc. The grain growth kinetics of the recrystallized state was obtained by experiment and Monte-Carlo computer simulation, respectively,
which showed good agreement. Based on kinetics and morphological characteristics, it was concluded that the grain coarsening
mechanism was governed by normal grain growth. No sign of abnormal grain growth was detected either in the experiment or in
simulation despite taking into consideration anisotropy in grain boundary energy as well as its mobility. This indicates that
grain boundaries produced by severely deformed Zr are stable against explosive coarsening. The evolution characteristics of
the microstructure in the present ECA pressed and recrystallized Zr differed from those of cold rolled Ti in that the grain
boundary misorientation distribution and texture were rather stable during grain growth.
Jointly Appointed by the Center for Advanced Aerospace Materials
This article is based on a presentation made in the 2002 Korea-US symposium on the “Phase Transformations of Nano-Materials,”
organized as a special program of the 2002 Annual Meeting of the Korean Institute of Metals and Materials, held at Yonsei
University, Seoul, Korea on October 25–26, 2002. 相似文献
74.
Koo Hyun Lee Ki Suk Nam Youl Min Park Pyung Woo Shin Deuk Yong Lee Yo-Seung Song 《Metals and Materials International》2002,8(4):381-385
Plasma nitrocarburized AISI 1020 steels were oxidized for 15, 30 and 60 min to evaluate their corrosion and microstructural properties. After plasma nitrocarburizing for 3 h at 570°C in a gas mixture comprising 85 vol.% N2, 12vol.% H2 and 3 vol.% CH4, the compound layer composed of ɛ-Fe2–3(N,C) and γ’-Fe4(N,C) phases and the diffusion layer above the matrix were observed. The top oxide layer, consisting mainly of magnetite (Fe2O4) and hematite (Fe2O3) phases, forms after post-oxidation treatment at 500°C. However, the oxide layer was severely degraded by spallation as a result of increases in post-oxidizing time. The difference in corrosion resistance should be attributed to the thickness of the top oxide layer, which was governed by post-oxidizing time. 相似文献
75.
Preparation of zeolitic adsorbents from waste coal fly ash 总被引:1,自引:0,他引:1
Power plants burning coal generate a large amount of fly ash as waste matter. The objective of this study is to produce zeolitic
adsorbents that possesses high adsorptive capacity for toxic cations. The sample was first pretreated with a High Intensity
Magnetic Separator for the removal of iron and magnetic materials (mainly Fe2O3 and TiO2). The zeolitic adsorbents were prepared under the various conditions of NaOH concentration (1–5 N), reaction time from 3
to 96 hours and at the various temperatures of 60, 80 and 100°C. The results of the experiment showed that the coal fly ash
should be synthesized with 4 N NaOH for 48 hours at 100°C in order to have good adsorptive capacity. The zeolitic adsorbents
showed higher cation exchange capacity values than the natural zeolite in removing NH
4
+
, Pb2+, Ca2+and Cd2+ions. 相似文献
76.
Polymethylphenylsilsesquioxane (PMPSQ–OH) and trimethylsilyl end‐blocked PMPSQ (PMPSQ–EC) were prepared. The thermal decomposition behavior of these polymers was studied by thermogravimetric analysis (TGA) and FT‐Raman spectroscopy. Hydroxyl‐functionalized polystyrene (PS–OH) was also prepared by anionic living polymerization. Thin hybrid films of PMPSQ/PS–OH with various blend ratios were obtained by spin‐coating on freshly cleaned glass. The surface morphology of the hybrid films was investigated by atomic force microscopy (AFM). In 80/20 PMPSQ/PS–OH hybrid film, the PS–OH component produced a very uniformly dispersed phase. This hybrid film contained small domains of PS–OH whose size ranged from 60 to 80 nm. As the content of PS–OH was increased, the domain morphology coarsened and phase inversion took place around 50 wt %. In the phase‐inversed system, the PMPSQ‐rich phase was uniformly distributed in the PS–OH‐rich continuous phase. In addition, temperature‐dependent dielectric properties of PMPSQ/PS–OH hybrids were investigated. Relaxation of the hybrids was observed with an increasing content of the PS–OH component due to the amorphous glass transition behavior of PS–OH. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2801–2812, 2003 相似文献
77.
Hyun Ju Lim Sung Jun Lee Han Gon Choi Jung Ae Kim Chul Soon Yong Sung Soo Han Seok Kyun Noh Jinho Jang Won Seok Lyoo 《应用聚合物科学杂志》2007,106(5):3268-3272
High‐molecular‐weight atactic poly(vinyl alcohol) (a‐PVA) gels loaded with (R,S)‐2‐(3‐benzoylphenyl)propionic acid (ketoprofen) were prepared from 5, 6, 7, and 8 g/dL solutions of a‐PVA with a number‐average degree of polymerization of 4000 in an ethylene glycol/water mixture with an aging method to identify the effect of the initial polymer concentration on the swelling behavior, morphology, and thermal properties of a‐PVA gels. Then, the release behavior of ketoprofen from a‐PVA gels was investigated. As the polymer concentration decreased, the ability for network formation decreased, and the degree of swelling of the a‐PVA gels increased. In addition, the enthalpy increased with an increase in the a‐PVA concentration, but the melting temperatures of the gels prepared at different initial polymer concentrations were the same; this indicated that tighter gel networks would be formed by a higher polymer chain density. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
78.
Boo Young Shin Sang Hee Jang In Jae Chung Bong Shik Kim 《Polymer Engineering and Science》1992,32(1):73-79
Two thermotropic liquid crystalline polyesters (TLCPs) with long flexible spacer groups in the main chain were prepared by melt polymerization: one was a homopolymer with only decane groups (LCPHO) and the other was a copolymer with hexane or decane groups (LCPCO) between mesogen units. These polyesters were blended with a matrix polymer of poly(ethylene terephthalate) (PET). Scanning electron microscopy (SEM) revealed the excellent interfacial adhesion between polyester and PET, and the large aspect ratio of polyester microfibrils in the blend fiber made by extruding and drawing the blend through a die. The aspect ratio was estimated by using the modified Halpin-Tsai equation. The fiber with LCPHO showed more extensive fibril formation than that with LCPCO. 相似文献
79.
Masuhiro Tsukada Hiroshi Katoh Donna Wilson Bong‐Seob Shin Takayuki Arai Ritsuko Murakami Giuliano Freddi 《应用聚合物科学杂志》2002,86(5):1181-1188
The work presented here discusses a new technique for preparing silk fibers and films with persistent antimicrobial activity through use of metallic dyestuffs during the fiber dyeing process. The length of the silk fibers investigated contracted when the fibers were immersed in concentrated neutral salt solutions, such as calcium or potassium nitrate, at elevated temperature levels. The birefringence and molecular orientation of the silk fibroin molecules became less ordered by the action of the neutral salt solutions, resulting in increased dyestuff absorption. Subsequently, contracted silk fibers were dyed with metallic dyestuffs containing Cr or Cu for the purpose of obtaining silk fibers with antimicrobial activity. Silk fibers dyed with metallic dyestuffs showed significant antimicrobial activity against the plant pathogen Cornebacterium and the human pathogen Coli bacillus. Tensile strength of the silk fibers after the salt shrinking and dyeing processes did not show a significant change, whereas the elongation at break was increased slightly. The techniques described here for preparing significantly active antimicrobial silk fibers are effective and economic ways of providing new materials for industrial and biomedical applications. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1181–1188, 2002 相似文献
80.
T. J. Shin H. K. Park S. W. Lee B. Lee W. Oh J.‐S. Kim S. Baek Y.‐T. Hwang H.‐C. Kim M. Ree 《Polymer Engineering and Science》2003,43(6):1232-1240
A series of aromatic polyimides composed of well‐defined conjugation units were synthesized form 5,5′‐bis(4‐aminophenyl)‐2,2′‐bifuryl (PFDA) and 2,2′‐bis(furyl) benzidine (FurylBZ) with various dianhydrides. The synthesized polyimides emit blue to green light with a quantum yield of 7.3–14.9%, depending on the polymer backbone. In particular, PFDA‐based polymers exhibit extremely narrow photo‐luminescence. The structure, thermal stability, refractive index and dielectric properties of the polymer films were also determined. 相似文献