WO3 and MoO3 addition effect on V2O5/TiO2 as promoters for removal of NOx and SOx from stationary sources

As an attempt to improve the catalytic activity at higher reaction temperatures between 300-450°C, various mole ratios of WO₃ were added to V₂O₅/TiO₂ catalytic systems. And also, in order to suggest a new mixed oxide catalyst system for simultaneous removal of NO_x and SO_x, from stationary sources, MoO₃-V₂O₅/TiO₂catalysts were prepared by a conventional impregnation method together with a newly introduced method of surface fixation (non-aqueous solution method). In case of WO₃ addition, at higher reaction temperature range (300–450°C), WO₃ and WO₃-V₂O₅/TiO₂ catalysts showed significant high conversion in NO reduction with NH₃ while V₂O₅/TiO₂ catalyst showed a significant change in selectivity mainly due to the excess side reaction of NH₃ oxidation. This difference in selectivity due to NH₃ oxidation at high temperature is supposed to be associated with the difference in values of surface excess oxygen between WO₃ and V₂O₅ on titania. The surface acidities of tested catalysts were relatively well correlated with the % conversion of NO at 400°C. In case of MoO₃ addition, the catalytic activity for the simultaneous removal of NO_x and SO_x were quite enhanced by the addition of MoO₃ into V₂O₅/TiO₂ catalysts. The enhanced activities were responsible for the formation of Mo=O bond on the intermediate species produced by solid solutions on MoO₃-V₂O₅/TiO₂ (aqueous). However, in the case of MoO₃-V₂O₅/TiO₂ (non-aqueous), the exact source of active site was not able to detect in IR spectra in spite of more enhanced activity was obtained in this study. After SO₂ contact, VOSO₄ is newly formed on the surface of catalyst, which supposed to be associated with the activity enhancement.     

Slip control strategy for an automatic transmission vehicle

Modern automatic transmissions equip torque converters with lock-up clutches to reduce the energy loss of hydraulic systems. Instead of simply engaging the clutch disks, the new technology of clutch slip has been developed to improve the overall efficiency of power transmission. There are two major problems with the clutch slip system. The first is how to keep the slip between the two disks within a small range and the second is when to start or stop the slip. In this paper, the second problem is discussed in view of the vehicle economy. With a simple vehicle dynamic model, the fuel economy is calculated to determine the lock-up strategy. Then the lock-up strategy is developed for a slip schedule.     

Anomalous temperature dependence and tension–compression asymmetry of Fe3Al intermetallics—an internal variable approach

Tension/compression asymmetry in the high-temperature flow and anomalous yield/flow stress of Fe–28 at% Al–5 at% Cr alloy has been investigated. Flow curves were obtained from a series of tensile and compressive load relaxation tests. Constitutive relations at each deformation conditions were formulated using the internal variable theory based on dislocation dynamics. In this study, high-temperature flow stress of selected material was to be safely described as the sum of internal stress and frictional stress. The anomaly and peak temperature of yield strength seem to be controlled by the anomaly of internal stress and the relative portion of internal and frictional stress in total flow stress, respectively. Asymmetric flow stress was observed in analogy with yield strength. In terms of constitutive parameters, critical stress for frictional flow (Σ₀) exhibited considerably higher value in compression, which physically postulates increased critical resolved shear stress (CRSS). Considering the crystallography and microstructure, it is presumably due to the ‘extrinsic’ effect of non-deviatoric stress tensor, as proposed in other studies.     

Contact analysis of impact in magnetic head disk interfaces

Three-dimensional finite element analysis of head and disk contact effects induced by impact in magnetic head disk interface (HDI) are presented. Elastic–plastic contact simulations are performed using . The entire contact–impact procedures during head disk collision under the dynamic loading of half-sine pulse acceleration with profiles of 300 and 500 g amplitude and 1.0 ms in duration are described in detail. Simulation results for the contact pressure distribution at HDI, von Mises equivalent stress, and equivalent plastic strain fields are examined and interpreted in terms of impact history. A comprehensive history of head disk relative displacement and von Mises equivalent stresses within contact region are provided and the evolution of plasticity are discussed. It is shown that finite element method can provide the simulation of the contact behavior resulting from the dynamic loading.     

Modeling of EMI response of damaged Mindlin–Herrmann rod

To ensure high sensitivity to incipient damages, electromechanical impedance (EMI) is measured at high frequencies for damage detection. In the working high-frequency range, very high vibration modes, of the order of the thousandth mode or higher, of a structural member are likely to be activated. This imposes a great difficulty on the accurate modeling of EMI response of a structure. In this paper, the reverberation matrix method (RMM) is adopted to study the dynamics of a Mindlin–Herrmann rod with surface piezoelectric patches. The rod is inhomogeneous along the axial direction so that damage-induced reduction of cross-section or Young's modulus could be easily incorporated in the model. A piecewise-homogeneous rod model is subsequently introduced to approximate the inhomogeneous rod, along with a shear lag model of interfacial bonding between the lead zirconate titanate (PZT) patches and the host rod. An analytical expression for the electric impedance (or admittance) of the coupled model of PZT patch-bonding layer-host rod system is derived. Comparison with other established results is presented. Parametric investigations are also performed to show the dynamic properties of the coupled smart structural system. The analysis in this paper provides necessary theoretical basis for damage detection of rod via the EMI signatures.     

Effects of grain size on the wear of recycled AZ91 Mg

Magnesium alloy AZ91 chips have been recycled using mechanical milling to yield samples with fine grain sizes. Together with cast samples of the same alloy, the wear behavior of these materials was studied through pin-on-disc sliding, with speeds varying from 1 to , under a normal load of 10 N. Despite the differences in grain size (0.6–) and mechanical properties, the various specimens did not differ significantly in their wear performance. Scanning electron microscopy observed abrasive wear to be dominant under low-speed sliding, and a transition to the formation of a protective mechanically mixed layer (MML) as sliding speed increased.     

Damaged layer characteristics in micro-endmilling of copper using an ultrahigh-speed air spindle

This paper presents an investigation on the characteristics of damaged layer in micro-machining by using the ultrahigh-speed air spindle. The damaged layer in metal cutting is derived from plastic deformation and transformation of metal structure. In this study, micro-cutting force, surface roughness, and plastic deformation layer according to the variation of machining conditions were investigated by experiments. The damaged layer was measured using optical microscope for the samples prepared by metallographic techniques. Its scale was dependent on cutting process parameters, especially feed per tooth. According to experimental results, it was verified that the thickness of damaged layer was increased with increasing of feed per tooth and cutting depth, also thickness of damaged layer was reduced in down-milling compared to upmilling during micro-endmilling operation.     

An evaluation method of probability of elastic-plastic fracture by 2-parameter criterion

Many researchers have made a lot of progress in studying the evaluation of fracture probability of brittle materials. However, studies of fracture probability for elastic-plasticity have not been made yet. An evaluation method for fracture probability which is grafted onto a 2-parameter criterion and statistical probability analysis is not only introduced in this study, but also applied to the simple 2-dimensional model and carbon steel piping to vealuate the effect of statistical variables.     

Analysis of a clutch damper using a discrete model

It is important to have a precise model for the clutch damper in order to simulate the entire powertrain of a vehicle and predict the responses of the system. In this research, we developed a new model in which the spring used in the clutch damper is divided into a finite number of elements. The model takes many unique properties of arc-shaped springs into consideration and is anticipated to be more precise than conventional simple models. With the model, two meaningful results were presented which can be utilized afterwards. One is a simulation concerning the peak torque transmitted via the clutch damper. The other is a simulation that shows the hysteretic characteristics of the clutch damper.