An instrumented oven for the monitoring of thermal reactions during the baking of sponge cake

An electric convective oven was conceived and equipped to allow monitoring thermal reactions during the baking of sponge cake. High total heat fluxes of between 6000 and 9000 W m⁻² were recorded under baking temperatures of 140-200 °C. The mapping of thermal conditions indicated satisfactory thermal homogeneity, with average temperature variations of 5 °C and maximum relative variations of the convective heat transfer coefficient of 15% on the thermal domain investigated. Internal heat and mass transfers, the extent of thermal reactions within the sponge cake and repeatability of the baking operation were all characterized by experimental measurements. Some of the main operating variables were monitored in the cake (core and surface temperatures, moisture content, levels of chemical reactants and products) and others in the baking atmosphere (temperature, humidity and concentrations of volatile compounds). Specific non-disruptive sampling devices were designed to extract data from cakes and the oven atmosphere in order to follow the kinetics of thermal reactions during the baking operation. Three phases could be identified during baking, corresponding to the relative importance of conductive and evaporative internal heat transfer regimes and to macroscopic changes in the cake structure with formation of a crust. The progress of thermal reactions was monitored with satisfactory precision in both the cake and the baking vapors: relative standard deviations of 2% and 8.7% were obtained respectively for the water content and hydroxymethylfurfural (HMF) content of three replicates during a baking operation.     

Reduction electrochimique de composes organiques en presence de tensio-actifs—I. etude polarographique de nitrobenzenes monosubstitues en milieu acide

During the polarographical reduction of substituted nitrobenzenes in acidic medium, the potential value of the four-electron reduction wave is shifted towards more negative values when BRIJ or CTAB are added.The E_{$\text{1}\text{2}$} variations, according to the surfactant concentration, indicate the formation stage of micelles. This one is only slightly modified by the nature of the substituents, used: CN, Cl, F, CH₃, OCH₃, NH₂.The differences between the E_{$\text{1}\text{2}$} values in aqueous and micellar mediums are always more important with BRIJ than CTAB, but they are similar, for the two surfactants, according to the various substituents.Plotting the E_{$\text{1}\text{2}$} and δ substituents values (according to Hammett and Taft parameters) indicates a linear variation with the same correlation coefficient with CTAB 10^?2 M, BRIJ 10^?2 M or without surfactant. The slopes are therefore quite different and measure: 0.15, 0.20, 0.24 V.The reaction kinetics are almost unmodified by CTAB additions, but strongly slowed by BRIJ additions.     

Electrode surface confinement of self-assembled enzyme aggregates using magnetic nanoparticles and its application in bioelectrocatalysis

Self-assembled enzyme aggregates, prepared from magnetic iron oxide nanoparticles, avidin, and a biotinylated redox enzyme, were shown particularly useful for the simple, fast, and efficient construction of highly enzyme-loaded electrodes with the help of a magnet. The approach was illustrated in the case of the bioelectrocatalytic oxidation of NADH by a diaphorase oxidoreductase in the presence of a ferrocene mediator. Two different self-assembling procedures were tested, taking advantage of the spontaneous aggregation of the nanoparticles in the presence of avidin and also of the multivalency binding of biotinylated diaphorase toward avidin. Activities of the bound and unbound diaphorase were systematically controlled allowing determination of the number of active biotinylated diaphorase per nanoparticle incorporated within each magnetic enzyme aggregate. An active enzyme loading capacity of up to 2.35 nmol mg-1 was found for the best nanostructured enzyme assembly, which is 200 times better than for commercialized magnetic micrometer-sized beads coated with streptavidin and saturated with diaphorase. With the help of a permanent magnet, the magnetic enzyme aggregates were finally magnetically collected as a film on the surface of a small screen-printed carbon electrode and the catalytic currents recorded by cyclic voltammetry. From the analysis of the steady-state catalytic current responses and the kinetic rate constants of biotinylated diaphorase, it was possible to determine the enzyme concentration within the magnetic films. Owing to the high enzyme loading in the aggregates of nanoparticles (i.e., 130 microM), the catalytic current responses were definitely higher than the ones measured at an electrode coated with a closed-packed monolayer of diaphorase or at an electrode covered with a film of magnetic micrometer-sized streptavidin beads saturated with diaphorase.     

Implementation of a new fuzzy vector control of induction motor

The aim of this paper is to present a new approach to control an induction motor using type-1 fuzzy logic. The induction motor has a nonlinear model, uncertain and strongly coupled. The vector control technique, which is based on the inverse model of the induction motors, solves the coupling problem. Unfortunately, in practice this is not checked because of model uncertainties. Indeed, the presence of the uncertainties led us to use human expertise such as the fuzzy logic techniques. In order to maintain the decoupling and to overcome the problem of the sensitivity to the parametric variations, the field-oriented control is replaced by a new block control. The simulation results show that the both control schemes provide in their basic configuration, comparable performances regarding the decoupling. However, the fuzzy vector control provides the insensitivity to the parametric variations compared to the classical one. The fuzzy vector control scheme is successfully implemented in real-time using a digital signal processor board dSPACE 1104. The efficiency of this technique is verified as well as experimentally at different dynamic operating conditions such as sudden loads change, parameter variations, speed changes, etc. The fuzzy vector control is found to be a best control for application in an induction motor.