Characterization of multilayer anti-fog coatings

Fog formation on transparent substrates constitutes a major challenge in several optical applications requiring excellent light transmission characteristics. Anti-fog coatings are hydrophilic, enabling water to spread uniformly on the surface rather than form dispersed droplets. Despite the development of several anti-fog coating strategies, the long-term stability, adherence to the underlying substrate, and resistance to cleaning procedures are not yet optimal. We report on a polymer-based anti-fog coating covalently grafted onto glass surfaces by means of a multistep process. Glass substrates were first activated by plasma functionalization to provide amino groups on the surface, resulting in the subsequent covalent bonding of the polymeric layers. The anti-fog coating was then created by the successive spin coating of (poly(ethylene-maleic anhydride) (PEMA) and poly(vinyl alcohol) (PVA) layers. PEMA acted as an interface by covalently reacting with both the glass surface amino functionalities and the PVA hydroxyl groups, while PVA added the necessary surface hydrophilicity to provide anti-fog properties. Each step of the procedure was monitored by XPS, which confirmed the successful grafting of the coating. Coating thickness was evaluated by profilometry, nanoindentation, and UV visible light transmission. The hydrophilic nature of the anti-fog coating was assessed by water contact angle (CA), and its anti-fog efficiency was determined visually and tested quantitatively for the first time using an ASTM standard protocol. Results show that the PEMA/PVA coating not only delayed the initial period required for fog formation but also decreased the rate of light transmission decay. Finally, following a 24 hour immersion in water, these PEMA/PVA coatings remained stable and preserved their anti-fog properties.     

Weakening the tight coupling between geometry and simulation in isogeometric analysis: From sub‐ and super‐geometric analysis to Geometry‐Independent Field approximaTion (GIFT)

This paper presents an approach to generalize the concept of isogeometric analysis by allowing different spaces for the parameterization of the computational domain and for the approximation of the solution field. The method inherits the main advantage of isogeometric analysis, ie, preserves the original exact computer‐aided design geometry (for example, given by nonuniform rational B‐splines), but allows pairing it with an approximation space, which is more suitable/flexible for analysis, for example, T‐splines, LR‐splines, (truncated) hierarchical B‐splines, and PHT‐splines. This generalization offers the advantage of adaptive local refinement without the need to reparameterize the domain, and therefore without weakening the link with the computer‐aided design model. We demonstrate the use of the method with different choices of geometry and field spaces and show that, despite the failure of the standard patch test, the optimum convergence rate is achieved for nonnested spaces.     

Sparse Adaptive Parameterization of Variability in Image Ensembles

This paper introduces a new parameterization of diffeomorphic deformations for the characterization of the variability in image ensembles. Dense diffeomorphic deformations are built by interpolating the motion of a finite set of control points that forms a Hamiltonian flow of self-interacting particles. The proposed approach estimates a template image representative of a given image set, an optimal set of control points that focuses on the most variable parts of the image, and template-to-image registrations that quantify the variability within the image set. The method automatically selects the most relevant control points for the characterization of the image variability and estimates their optimal positions in the template domain. The optimization in position is done during the estimation of the deformations without adding any computational cost at each step of the gradient descent. The selection of the control points is done by adding a L ¹ prior to the objective function, which is optimized using the FISTA algorithm.     

The effect of atmospheric moisture on crack propagation in the interface between directly bonded silicon wafers

Infra-red video sequences were taken of directly bonded silicon wafer pairs undergoing the razor blade crack length bond strength measurement in a specially designed jig. A series of tests were carried out under controlled atmospheres of nitrogen at various relative humidities. Analysis of the video images showed that the crack continues to propagate rapidly for several minutes after the blade has stopped moving, and that the presence of moisture has a strong positive influence on the rate of crack propagation under static loading. A new Maszara protocol is suggested based on modelling crack growth using our experimentally derived constants.     

Different ways of moving ahead after analysis: Changes in experiential dimensions.

Within research on psychoanalysis, the common model of analytic change conceptualizes it as structural reorganization and development of self-analytic function. The present article takes as its point of departure analytic patients who, in follow-up interviews, do not present their experience of change according to this common model. Instead of categorizing analysands as being either successful or unsuccessful cases, the article aims to develop concepts of change that pertain to the experiential domain. Themes in the self experience of three former patients are explored. The data is gathered through follow-up interviews. The interviews were conducted with an analytic approach, which provides data on transference themes. Data from the interviews is not intended to provide empirical support for outcomes, but provides material from which concepts of change can be explored and discussed. The three cases illustrate three distinct psychic dimensions: safety, meaningfulness and sameness. All the cases have in common that they show, as described by Modell (1990), a containing transference in the follow-up interviews. Based on the postulated dimensions of self-experience, and with the view that containing transference is a common theme, it is further argued that, despite showing object-dependency, these informants have undergone an experiential change that is of existential significance. This is a kind of change that, it may be argued, is beyond a structural one; one that may be conceptualized as a precondition for the kind of change assumed by the main analytic model. To develop a self-analytic function, the patient may first need to develop a containing one. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Numerical modelling of interfacial soil erosion with viscous incompressible flows

The aim of this study is to develop a numerical model for simulating surface erosion occurring at a fluid/soil interface subject to a flow process. Balance equations with jump relations are used. A penalization procedure including a fictitious domain method is used to compute the Stokes flow around obstacles, in order to avoid body-fitted unstructured meshes and instead use fast and efficient finite volume approximations on Cartesian meshes. The evolution of the water/soil interface is described by using a level set function. The ability of the model to predict the interfacial erosion of soils is confirmed by several numerical simulations.     

Possible role of hydrogen sulphide gas in self-heating of pyrrhotite-rich materials

Self-heating of sulphides poses safety, environmental and economic concerns to the mining and metallurgical industries, especially when sulphide ores or concentrates have to be stored or transported. The first target of this investigation is the self-heating of pyrrhotite (Po), the most commonly suspected mineral to trigger the phenomenon because of its fast oxidation in moist air. Following a standard experimental protocol, self-heating was assessed on samples of Po mixed with sand as an inert material. With increasing Po content, self-heating rates progressively increased but the samples visually appeared less and less oxidized. A high Po content, it was hypothesized, may give a more reducing environment favouring formation of hydrogen sulphide (H₂S). The presence of this gas could be significant for self-heating for several reasons which are discussed. The hypothesis was tested by including copper pieces to detect the gas by forming copper sulphide, and adding copper sulphate in excess which suppressed self-heating, apparently by reacting with and removing the gas.