Carbon fibers modified with carbon nanotubes

Carbon nanotubes were used to modify a polyacrylonitrile (PAN) polymer solution before the manufacture of the carbon fiber precursor. The modified PAN fibers were spun from a dimethylformamide solution containing a small amount of single-walled carbon nanotubes. The fibers were characterized by thermogravimetry and optical and scanning electron microscopy. Structure, morphology, and selected properties of the composite polymeric fibers and the fibers after carbonization are characterized. The mechanical properties of the fibers are examined. It is found that nanotubes in the PAN solution have a strong tendency to form agglomerates that inhibit suitable macromolecular chain orientation of the carbon fiber precursor. Fibers manufactured from such a solution have similar mechanical properties to those from a pure PAN precursor, and after carbonization the resultant carbon fibers are very weak. A comparison of pure carbon fibers and those containing nanotubes reveals slight differences in their structural ordering.     

Thermodynamic aspects of power generation in imperfect fuel cells: part II

This research continues the thermodynamic analysis of steady-state solid oxide fuel cells initiated in Sieniutycz (Sieniutycz, S., 2010, Thermodynamic aspects of power generation in imperfect fuel cells: part I. International Journal of Ambient Energy, 31 (4), 195–202). This analysis focuses on the effect of incomplete conversions in chemical reactions. A general approach is developed that attributes lowering of the cell voltage below its reversible value to polarisations and imperfect chemical conversions. Relevant model, appropriate for systems with complete conversions, is extended to imperfect cases. The performance curves of a fuel cell and the effect of typical design and operating parameters on the cell behaviour are analysed. A general result is obtained for power limits of fuel cells propelled by linear transport phenomena.     

CONTROL OF CONSTRUCTION ACTIVITIES: III. FUZZY-BASED CONTROLLER

In this paper, a real-time fuzzy-based controller of construction activities is proposed. Because of the numerous uncertainties associated with construction activities, their control requires a different approach than the traditional feedback methods. These methods are essentially based on the knowledge of a transfer function that models the input/output relationships for the controlled system. For a highly complex and uncertain system such as a construction activity, a fuzzy-based control strategy was found to be a suitable and effective approach. The proposed control system is built in two main levels, the process and the activity levels. Each level comprises two main units, namely, the fuzzy controller and the self learning algorithm. The implementation of the control actions can be performed by either manipulating the states of the variables for the purpose of improving the process output, or changing the process behavior function for the same purpose. Practical examples are presented wherever possible to illustrate the proposed control strategy.     

SCHEDULING OF NONSERIAL LINEAR PROJECTS WITH MULTIPLE NON-OVERLAPPED LOOP STRUCTURES

Existing dynamic programming formulations are utilized for the scheduling of serial linear projects. These formulations cannot, however, be used for the scheduling of nonserial linear projects. The intent of this paper is to present a nonserial dynamic programming formulation for the scheduling of linear projects with multiple non-overlapped loop structures. The objective of the nonserial dynamic programming solution is to provide for the selection of resources, interruptions, and lags for production activities that lead to the minimum project duration. The advantages of this nonserial dynamic programming approach include its ability to handle work interruption and variable production rates. In addition, the developed system produces a graphical representation of the project schedule of minimum duration. A nonserial linear project is treated herein using the proposed method.     

On the dynamic self-diffraction in methylene blue-sensitised gelatine

Dynamic self-diffraction processes have been observed and analysed for methylene blue-sensitised water-swollen gelatine (MBSG). A degenerate two-wave mixing experiment performed on thick samples of MBSG with 10 mW, 632.8 nm wavelength He Ne laser light allowed for the formation of phase- and amplitude-transient holographic gratings. Single-beam propagation characteristics through MBSG were measured with a Mach-Zehnder interferometer. The observed energy transfer between the writing beams in the two-beam coupling experiment and the considerable temporal oscillations of diffraction efficiency are explained by simple formulae. Two processes are considered: the time-dependent phase shift between the writing beams and the transverse self-phase modulation effects (self-focusing and interference ring formation).     

Concentrated Water Solution of Salts as Solvents for Reactions of Carbohydrates. Part 1: Reactions of Glucose Promoted by Concentrated Solutions of Alkaline and Alkaline Earth Metal Salts

Saturated water solutions of selected alkaline and alkaline earth metal salts have been studied whether or not they catalyze the formation of levulinic acid from glucose. The most active was a solution of magnesium chloride. Activity was further increased in the system (MgCl₂+H⁺). We observed complete inhibition of this reaction by NO₃⁻. Contrary to the generally accepted opinion that formation of hydroxymethylfurfural is only H⁺ catalyzed, we observed activity of the system formed from MgO and MgCl₂ when one starts from glucose. (MgCl₂+ MgO) in water is alkaline.     

MATHEMATIC MODEL FOR FORMABILITY CRITERIA OF SUPERPLASTIC AIR BULGING COMPONENTS

A proposal for two types of press close to die,including blank coming in die and Blank cov-ering die,and four criteria for formability is put forward in the study of the superplastic airbulge forming of the metallic thin wall components.A dimensionless weigh mathematic modelfor the criteria of superplastic air bulge forming is developed to be:Q_w=1.56(WS)/(HF)+2.37(0-π/(180)-r/(r_0)+0.19The superior formability of components is approaching,if Q_W≥1,and the worse,if Q_W<1.Itwas confirmed by practice that the above mentioned model is accurate sufficiently.