Investigation of the hydration and dehydration of aluminium oxide-hydroxide using high frequency dielectric measurements between 300 kHz-3 GHz

Aluminium oxide exists in several forms which on addition of water give a complex range of oxide-hydroxide; boehmite, bayerite and gibbsite. High frequency dielectric measurements {300 kHz-3 GHz} are reported on the hydrated and dehydration of certain of these oxide-hydroxides. The amplitude of the observed dielectric relaxation correlates approximately with the water content, however anomalies can be observed during dehydration due to the retention of water in an immobilized form within the oxide matrix which highlights complexities in their structure and properties. These data indicate the potential of the dielectric method for quantification of the degree of hydration of an oxide in adhesive bonded structures. Two silane coupled alumina samples were studied to simulate the interface generated in the pre-treatment of real adhesive bonded structures.     

Development of manufacturing control strategies using unsupervised machine learning

This research considers the control of manufacturing systems that support job routing and process sequence flexibility. A machine learning system is presented that uses a simulation model of the target manufacturing system to discover opportunistic control rules. Learning is unsupervised and is driven by a genetic algorithm. The learning method requires very little a priori control knowledge. For this presentation, the decision-making agents are the part types being processed. Part types evolve cooperative strategies for selecting the best route through the manufacturing system based on simulated real-time information that describes the state of the system. Results are presented that demonstrate the effectiveness of the approach.     

Transporting Deformations of Face Emotions in the Shape Spaces: A Comparison of Different Approaches

Studying the changes of shape is a common concern in many scientific fields. We address here two problems: (1) quantifying the deformation between two given shapes and (2) transporting this deformation to morph a third shape. These operations can be done with or without point correspondence, depending on the availability of a surface matching algorithm, and on the type of mathematical procedure adopted. In computer vision, the re-targeting of emotions mapped on faces is a common application. We contrast here four different methods used for transporting the deformation toward a target once it was estimated upon the matching of two shapes. These methods come from very different fields such as computational anatomy, computer vision and biology. We used the large diffeomorphic deformation metric mapping and thin plate spline, in order to estimate deformations in a deformational trajectory of a human face experiencing different emotions. Then we use naive transport (NT), linear shift (LS), direct transport (DT) and fanning scheme (FS) to transport the estimated deformations toward four alien faces constituted by 240 homologous points and identifying a triangulation structure of 416 triangles. We used both local and global criteria for evaluating the performance of the 4 methods, e.g., the maintenance of the original deformation. We found DT, LS and FS very effective in recovering the original deformation while NT fails under several aspects in transporting the shape change. As the best method may differ depending on the application, we recommend carefully testing different methods in order to choose the best one for any specific application.

     

Direct activity measurements in liquid Ag−Cu alloys using a valved knudsen cell-mass spectrometer system

The primary objective of this investigation was to demonstrate a new method of measuring activities. The mass spectrometric analysis of effusates from a unique valved Knudsen cell was used to determine the activity of Ag in the liquid Ag−Cu system at 1400 K. The alloy compositions were varied from one composition extreme to the otherin situ. The system exhibits positive deviation from ideal behavior, and the results are in agreement with previous investigations and are summarized by the equation

Hygrothermal aging of rubber‐modified and mineral‐filled dicyandiamide‐cured DGEBA epoxy resin. III. Dielectric spectroscopy investigation

The effects of moisture absorption on the dielectric properties of a rubber‐modified, mineral‐filled, epoxy resin based on the diglycidyl ether of bisphenol A cured with dicyandiamide are reported. Samples of the resin were aged by immersing in deionized water, or 5% w/w NaCl solution, at elevated temperatures. Dielectric measurements were carried out over the frequency range 10^?1 to 6 × 10⁵ Hz. A featureless dielectric spectrum was observed with both real and imaginary dielectric permittivity increasing with the amount of absorbed water. The change in the dielectric properties with absorption of water was independent of presence of salt, temperature of exposure, and aging history, although a hysteresis of the hydration–dehydration process was observed at low frequencies. Two types of absorbed water were observed—water molecularly dispersed within the epoxy matrix and clustered water in spherical microcavities. The time dependence of the real dielectric permittivity measured at 10 kHz was found to closely resemble that of the water absorption, which allowed the activation energy of diffusion to be calculated from both dielectric and gravimetric data. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1011–1024, 2002; DOI 10.1002/app.10368     

Attrition mill operating characteristics

The attrition mill is a device for mechanically reducing solid particle size by intense agitation of a slurry of material being milled and coarse milling media. For example, in 10 hours of milling, specific surfaces of 40 and 25 m²/g were obtained for alumina and barite, corresponding to 38 and 56 nm equivalent spherical diameter, respectively. Size reduction rates for relatively coarse particles were first-order and increased linearly with power input to the mill. Optimum milling medium concentration corresponded to medium particles moving a distance of approximately 0.7 of their diameter before collision with another such particle. Power characteristics of the attrition mill were essentially the same as those of a radial flow turbine mixer. Laminar flow became disrupted at N_Re ≈ 200, while turbulent flow was established at N_Re > 8000. Slurries of fine powders exhibited the same linear power-average density dependence as single-phase liquids. However, a different dependence was observed with large particles.     

The reaction of activated vinyl compounds with cotton cellulose via internal catalysis

The reactions of a variety of activated vinyl compounds with cotton cellulose fabric containing quaternary ammonium hydroxide substituents were explored. Each reaction, catalyzed by the basic groups in the cellulose, was followed to or near the point of leveling off. The results are analyzed and discussed in terms of accessibility of the cellulosic compositions and in terms of the efficiency of the quaternary ammonium substituents as catalysts for the addition reactions. Estimates of relative forward rate constants (k_f) and equilibrium constants (K) for the reactions were made. The values of k_f for reactions of the vinyl compounds with the quaternary ammonium celluloses show a relative order which is similar to that for the reactions of the vinyl compounds with simple alcohols. Evidence is presented to indicate that, in some cases, the addition of vinyl compounds is accompanied by anionic-catalyzed graft polymerization.     

Studies of microhardness and mar resistance using a scanning probe microscope

Scanning probe microscopy (SPM) is in a period of rapid development. It shows great promise for characterizing coating surfaces. This paper describes modification of an SPM so that it can be used to mar the surfaces of coatings under controlled conditions and to characterize the mars. Mar resistance of coatings is analyzed in terms of a ‘three response, two mechanism model.' The three responses (fracture, elastic, and plastic) can be measured quantitatively using the SPM. Of the three responses, only two (fracture and plastic deformation) are marring mechanisms – elastic deformations recover instantaneously. In some cases mars resulting from plastic deformation may recover slowly with time or with immersion in water; this phenomenon is attributed to viscoelastic creep. Microhardness is also measured with the modified SPM. Some thermoset coatings appear to be substantially harder near their surfaces than in the mass of material, and such materials may respond quite differently to stress applied at different levels near the surface. This finding has important implications for all coating properties that are strongly influenced by the surface. A quantity called ‘micro mar resistance' is defined. It may be useful for comparing different coatings under specified conditions of marring. However, there can be no single quantity that expresses ‘mar resistance' of a coating under all conditions.     

Correlation of vapor-liquid equilibria for binary mixtures with free energy-based equation of state mixing rules: Carbon dioxide with alcohols, hydrocarbons, and several other compounds

The correlation of vapor-liquid equilibrium data for high-pressure carbon dioxide systems is of interest in a number of industrial applications, including supercritical extraction. Here, we consider the correlation of data for 12 binary systems of carbon dioxide separately with alcohols, with hydrocarbons, and with acetone, benzene, and water. The Wong-Sandler (W-S) and modified Huron — Vidal first order (MHV1) free energy-based equation of state mixing rules (the W-S and MHV1 models) were used in the calculations. Both combined equation of state+free energy models generally resulted in good correlations of the experimental data over wide ranges of temperature and pressure with temperature — independent parameters. However, for the carbon dioxide+water system, the W-S model produced an 11% average absolute deviation in pressure, while no parameter that resulted in an AAD in pressure of less than 20% could be found for the MHV1 model.     

Improved Randomized Online Scheduling of Intervals and Jobs

We study the online preemptive scheduling of intervals and jobs (with restarts). Each interval or job has an arrival time, a deadline, a length and a weight. The objective is to maximize the total weight of completed intervals or jobs. While the deterministic case for intervals was settled a long time ago, the randomized case remains open. In this paper we first give a 2-competitive randomized algorithm for the case of equal length intervals. The algorithm is barely random in the sense that it randomly chooses between two deterministic algorithms at the beginning and then sticks with it thereafter. Then we extend the algorithm to cover several other cases of interval scheduling including monotone instances, C-benevolent instances and D-benevolent instances, giving the same competitive ratio. These algorithms are surprisingly simple but have the best competitive ratio against all previous (fully or barely) randomized algorithms. Next we extend the idea to give a 3-competitive algorithm for equal length jobs. Finally, we prove a lower bound of 2 on the competitive ratio of all barely random algorithms that choose between two deterministic algorithms for scheduling equal length intervals (and hence jobs). A preliminary version of this paper appeared in Fung et al. (The 6th International Workshop on Approximation and Online Algorithmspp, vol. 5426, pp. 53–66, 2008).