Pd/Mg(OH)2 Heterogeneous Nanocatalysts Synthesized by a Facile One-Pot Hydrothermal Method for CO Direct Esterification to Dimethyl Oxalate

Catalysis Letters - Pd-based heterogeneous nanocatalysts have wide application in chemical industry. However, the traditional synthesis process contains multi-steps such as impregnation, dry,...     

An Analytical Model Including Interface Traps and Temperature Effects in Negative Capacitance Double Gate Field Effect Transistor

Silicon - In this paper, an analytical model for negative capacitance double gate field effect transistor (NC-DG-FET) is proposed. This model includes interface traps and temperature effects, which...     

The Synthesis of Covalent Triazine-Based Frameworks via Friedel–Crafts Reactions of Cyanuric Chloride with Thienyl and Carbazolyl Derivatives for Fluorescence Sensing to Picric Acid,Iodine and Capturing Iodine

A multifunctional thiophene-based covalent triazine framework (TTPATTh) with triphenylamine as core is synthesized by Friedel–Crafts reaction of cyanuric chloride with thienyl derivative for the first time. The yield of TTPATTh (99.59%) is far higher than that of the carbazole-based CTF (TTPATCz, 47.03%). TTPATTh and TTPATCz possess high BET surface areas with 1235 and 2501 m² g^–1 as well as high pore volumes with 1.60 and 2.23 cm³ g^–1, respectively. TTPATTh and TTPATCz have high thermal stability with high thermal decomposition temperatures of 514 and 598 °C in nitrogen atmosphere. With the introduction of triazine rings, the fluorescence sensing sensitivities of TTPATTh and TTPATCz to picric acid and iodine are improved significantly. Especially for TTPATTh, the K_sv values reach 5.95 × 10⁵ and 1.61 × 10⁴ L mol^–1, and LODs reach 1.02 × 10^–12 and 1.86 × 10^–12 mol L^–1. To the best of the knowledge, this is the most sensitive value among thiophene-based porous organic polymers to PA and I₂. Furthermore, TTPATTh and TTPATCz can also adsorb iodine in vapor phase, cyclohexane solution and aqueous solution, and release iodine by heating or in ethanol solution. The efficiency of controlling the release of iodine is higher than that in ethanol.     

铸铁在700℃时氧化过程的观察

利用光学显微镜、电子探针以及扫描电镜研究了灰铁、球铁和蠕铁在７００℃时的氧化过程。结果表明：（１）灰铁的氧化主要沿石墨与基体的相界面进行，初生奥氏体枝晶对氧的侵入具有一定的阻碍作用；（２）球铁是沿晶界比先氧化来实现其间接氧化的；（３）蠕铁氧化的模式主要取决于蠕化率的高低。     

稀土含量对喷熔层组织及耐蚀性的影响

本文通过在镍基自熔合金粉末中加入不同含量的稀土，研究了稀土含量对喷熔层组织及耐蚀性的影响规律及其作用机制。结果表明，在喷熔材料中加入适量稀土，可使喷熔层组织细化、晶界净化，从而使腐蚀过程中的表面活性点减少，耐蚀性提高。     

汽车后市场准入门槛亟需设防

任何市场都是有规则的,没有标准的市场是短暂的.经销商要有一个好的经营环境,必须把这个门槛设好. 汽车后市场还需要准入门槛? 李庆云现任天津环渤海汽车城董事长并身兼天津市交易市场协会会长,在没有跨进汽车行业之前,一直觉得这样的问题多余:哪个行业没有准入门槛?等自己在天津建立环渤海汽车城之后,才意识到,中国的汽车后市场是多么需要"设防".     

Properties of poly(n‐butyl methacrylate) prepared by reverse atom transfer radical polymerization in an aqueous dispersed system

Reverse atom transfer radical polymerization (ATRP) of n‐butyl methacrylate (BMA) in waterborne media using Cu(II) complexes with azo initiators (i.e., reverse ATRP) was conducted. The influence of several factors, such as surfactant, catalyst, and reaction time, on the stability of the emulsion, the particle size, the morphology of the emulsion particles, and the control of the polymerization was investigated. The results showed great differences between ATRP and conventional emulsion polymerization, especially the nucleation mechanism and the kinetics. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1542–1547, 2003     

Effect of additives on formation of natural gas hydrate

The formation of natural gas hydrate (NGH) is studied in this work. Kinetics data of hydrate formation with no agitation were collected at various concentrations of the aqueous solutions with different additives such as alkylpolyglucside, sodium dodecyl benzene sulfonate and potassium oxalate monohydrate. Various kinds of additive increased the formation rates of NGH and its storage capacity and reduced the induction time of NGH formation. Moreover, the storage capacity, the induction time and the hydrate formation rate were influenced by the concentration of the aqueous solution.     

无芯胶管的研制、工艺现状和发展建议

20世纪60年代初,我国胶管领域自主开发创新研制了无芯胶管制造技术,并且形成定型技术,一直沿用至今,笔者参与、见证了该产品从试验到投产的全过程。本文对该产品的工艺进行了新旧对比,提出了今后发展的建议。