Combination of Surface Charge and Size Controls the Cellular Uptake of Functionalized Graphene Sheets

A fundamental issue for biomedical applications of graphene is the correlation between its physicochemical properties and cellular uptake mechanism. However, such studies are challenging due to the intrinsic polydispersity of graphene. In this work, a series of water soluble graphene sheets with the same polymer coverage, density of functional groups, and fluorescence intensity but three different sizes and surface charges are produced. The effect of the latter two factors and their combination on the mechanism of cellular uptake and intracellular pathways of these defined nanosheets is investigated via confocal and Raman microscopies. While positively (? NH₃⁺) and negatively (? OSO₃^?) charged sheets show an energy dependent uptake, their neutral analogs do not show any significant uptake. The cellular uptake efficacy of positively charged graphene sheets is independent of the size and occurs both through phagocytosis and clathrin‐mediated endocytosis pathways. However, cellular uptake efficacy of graphene sheets with negative surface charge strongly depends on the size of the sheets. They cross the membrane mainly through phagocytosis and sulfate‐receptor‐mediated endocytosis. This study demonstrates that the impact of the size of graphene derivatives on their cellular uptake pathways highly depends on their surface charges and vice versa.     

Nanostructured Si/Organic Heterojunction Solar Cells with High Open‐Circuit Voltage via Improving Junction Quality

Nanostructured silicon (Si) can provide improved light harvest efficiencies in organic‐Si heterojunction solar cells due to its low light reflection ratio compared with planar one. However, the associated large surface/volume ratio of nanostructured Si suffers from serious surface recombination as well as poor adhesion with organics in organic‐Si heterojunction solar cells, which leads to an inferior open‐circuit voltage (V_oc). Here, we develop a simple and effective method to suppress charge recombination as well as enhancing adhesion force between nanostructured Si and organics by incorporating a silane chemical, namely 3‐glycidoxypropyltrimethoxydsilane (GOPS). GOPS can chemically graft onto nanostructured Si and improve the aqueous organic wetting properties, suppressing surface charge recombination velocity dramatically. In addition, this chemically grafted layer can enhance adhesion force between organics and Si. In such a way, a record V_oc of 640 mV associated with a power conversion efficiency of 14.1% is obtained for organic‐nanostructured Si heterojunction devices. These findings suggest a promising approach to low‐cost and simple fabrication for high‐performance organic‐Si solar cells.     

Zum Tragverhalten von Stützen semi‐integraler Brücken

Load‐bearing behaviour of columns of integral bridges – realistic calculation of columns of integral bridges for the ultimate limit state Due to the complex and interactive load‐bearing behaviour, calculation of integral bridges is more expensive than the calculation of bridges with its superstructure uncoupled from the substructure. Apparently conservatively chosen reinforcement ratios lead to increased stiffness of the columns and thus inherently increased the constraining forces. Therefore, a greater reinforcement ratio is not imperatively connected with a better load‐bearing behaviour of the columns. To better understand the load‐bearing behavior of integral bridges, it is necessary to consider the physical non‐linearity in the calculation. In this contribution, the non‐linear behaviour of integral columns is examined by varying the cross section dimensions and the reinforcement ratios. The results are analyzed with regard to the columns ductility and the constraining forces. Finally, this contribution offers conceptual proposals, which can be used for the dimensioning of integral bridges.     

Functional Mesoporous Carbon‐Coated Separator for Long‐Life,High‐Energy Lithium–Sulfur Batteries

The lithium–sulfur (Li–S) battery is regarded as the most promising rechargeable energy storage technology for the increasing applications of clean energy transportation systems due to its remarkable high theoretical energy density of 2.6 kWh kg^?1, considerably outperforming today's lithium‐ion batteries. Additionally, the use of sulfur as active cathode material has the advantages of being inexpensive, environmentally benign, and naturally abundant. However, the insulating nature of sulfur, the fast capacity fading, and the short lifespan of Li–S batteries have been hampered their commercialization. In this paper, a functional mesoporous carbon‐coated separator is presented for improving the overall performance of Li–S batteries. A straightforward coating modification of the commercial polypropylene separator allows the integration of a conductive mesoporous carbon layer which offers a physical place to localize dissolved polysulfide intermediates and retain them as active material within the cathode side. Despite the use of a simple sulfur–carbon black mixture as cathode, the Li–S cell with a mesoporous carbon‐coated separator offers outstanding performance with an initial capacity of 1378 mAh g^?1 at 0.2 C, and high reversible capacity of 723 mAh g^?1, and degradation rate of only 0.081% per cycle, after 500 cycles at 0.5 C.     

Hindsight ≠ hindsight: Experimentally induced dissociations between hindsight components.

Hindsight bias has recently been conceived of not as a unitary phenomenon but as a conglomerate of 3 separate phenomenological manifestations (“hindsight components”; Blank, Nestler, von Collani, & Fischer, 2008): memory distortions, impressions of foreseeability, and impressions of inevitability. These components are thought to be fundamentally different in nature, to be influenced by different processes, and to serve different functions. This article provides strong evidence for the separate components view and its underlying assumptions by demonstrating theoretically predicted dissociations between the components. In Experiment 1, for example, we used a memory encoding manipulation to specifically influence the amount of hindsight memory distortion but not participants' inevitability impressions. Conversely, varying the number of provided reasons for an event outcome affected inevitability impressions but left memory distortion untouched. Similar results—using different theoretically derived manipulations—were obtained between foreseeability impressions and memory distortions (Experiment 2) and between inevitability and foreseeability impressions (Experiment 3). Theoretical and practical consequences of these results and of the separate components view are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)