Response of a proton exchange membrane fuel cell to a sinusoidal current load

The load-following capability of a proton exchange membrane fuel cell was studied by measuring the cell voltage response to a sinusoidal current load with large amplitude and varying frequency. A mathematical model was developed, incorporating mass transport and capacitive effects as well as the membrane resistance. The model was capable of separating the faradaic and capacitive currents and predicting the observed hysteresis. At frequencies of the sinusoidal current load below 1 Hz, no appreciable hysteresis in the polarisation curve was observed. When increasing the frequency above 1 Hz, a hysteresis appeared at current densities below 0.2 A cm^?2. The model related this hysteresis to capacitive effects. When using air as the cathode feed, hysteresis in the current density range 0.5 A cm^?2 and higher appeared above 1 Hz compared to 100 Hz for pure oxygen. The model revealed that hysteresis observed in this current density range was caused by oxygen transport limitations.     

Monodisperse fine aerosol generation using fluidized bed

Monodisperse, fine aerosols are needed in many applications: filter testing, experiments for testing models, and aerosol instrument calibration, among others. Usually, monodisperse fine aerosols are generated in very low concentrations, or mass flow rates, in the laboratory scale. In this work, we needed to generate aerosols with higher mass flow rate than typically available by the laboratory-scale methods, such as atomizers, nebulizers, ultrasonic generators, vibrating orifice generators, and condensation generators. Therefore, we constructed a fluidized bed aerosol generator to achieve particle mass flow rates in the range of 15-100 g/h. Monodisperse, spherical SiO₂ particles of two sizes with geometrical diameters of 1.0 and 2.6 µm were used in the aerosol generator. The aerosol generator was used at both atmospheric pressure, and at high pressures up to 5 bar (abs).The particle size, mass concentration and the net average particle charge were measured after mixing the aerosol with nitrogen. The particle size distributions with both particle sizes were monodisperse, and no particle agglomerates were entrained from the fluidized bed. The behavior of the fluidized bed generator was found to be markedly different with the two particle sizes in regard to particle concentration, presumably due to different particle charging inside the generator. After determining the net average charge of the particles, an ion source Kr-85 was used to reduce the charge of the particles. This was found to be effective in neutralizing the particles.     

Oxidative dehydrogenation of propane in a perovskite membrane reactor with multi‐step oxygen insertion

A membrane reactor incorporating a hollow fiber with successive parts of oxygen permeable and passivated surface segments has been developed and was used for the oxidative dehydrogenation (DH) of propane. This membrane geometry allows a controlled oxygen feeding into the reactor over its axial length. In the oxidative DH, the thermodynamic limitation of propane DH can be overcome. By using this novel hollow fiber membrane reactor with a Pt/Sn/K DH catalyst, oxygen separation and propene formation could be established even at temperatures as low as 625°C with long‐term stability. Combining the hollow fiber membrane and the DH catalyst, the highest propene selectivity of 75% was observed at a propane conversion of 26% and 625°C whereas the best propene yield of 36% was obtained at 675°C (48% propene selectivity). The performance of this reactor is evaluated by applying various reaction conditions. © 2010 American Institute of Chemical Engineers AIChE J, 2010     

Geschichtliche Entwicklung und aktuelle Praxis der Probebelastung — Teil 2: Entwicklung von Normen und heutige Anwendung

Im Zuge des massenhaften Einsatzes von Probebelastungen im 19. und zu Beginn des 20. Jahrhunderts zeigte sich die Notwendigkeit, deren Planung, Durchführung und Auswertung durch allgemeine Richtlinien und Normen zu stützen. Im Beitrag wird das Ringen um erste zaghafte Festlegungen beschrieben, die im Laufe der Jahre immer konkreter zu einer verwendbaren Handlungsgrundlage ausgearbeitet wurden. Unter Kritikern blieb jedoch immer die Frage über die Sicherheit und vor allem die Aussagekraft von Belastungsversuchen auf der Grundlage der verwendeten Bewertungskriterien offen. Mit der Weiterentwicklung der Berechnungsverfahren auch durch den Einsatz von Computertechnik wurden Probebelastungen von Neubauten ab den 1970‐er Jahren entbehrlich. Für auffällig gewordene bestehende Tragwerke stellt die Probebelastung jedoch auch heute noch eine — und manchmal die einzige — Methode zum Nachweis einer ausreichenden Tragfähigkeit dar. Die hierfür angewendete moderne Belastungs‐ und Messtechnologie bietet jedoch im Unterschied zur traditionellen Vorgehensweise ein hohes Maß an Sicherheit und Informationsgewinn. Historical Development and current practise of load tests in situ — Part 2: Development of standards and current practise. Because of the large demand and use of load testing in the 19th and at the beginning of the 20th century, there was the necessity to standardise the planning, execution and analysis in general guidelines and codes. This article describes the struggling and first tentative specification, which were more and more specified to an useful basis in the following years. The used criterions for the assessment have often been a reason for critics on the value and the safety of loading tests. The further development of calculation methods especially the computer technology made the load testing of new structures superfluous in the 1970s. But for existing structures loading tests are today often a — and sometimes the only — method to proof a sufficient load bearing capacity. The today used modern loading‐ and measuring technology provides, in contrast to the traditional method, a high degree of safety and structural information.     

Method and simulation program informed decisions in the early stages of building design

The early stages of building design include a number of decisions which have a strong influence on the performance of the building throughout the rest of the process. It is therefore important that designers are aware of the consequences of these design decisions. This paper presents a method for making informed decisions in the early stages of building design to fulfil performance requirements with regard to energy consumption and indoor environment. The method is operationalised in a program that utilises a simple simulation program to make performance predictions of user-defined parameter variations. The program then presents the output in a way that enables designers to make informed decisions. The method and the program reduce the need for design iterations, reducing time consumption and construction costs, to obtain the intended energy performance and indoor environment.     

Oxidative stress, genotoxicity, and vascular cell adhesion molecule expression in cells exposed to particulate matter from combustion of conventional diesel and methyl ester biodiesel blends

Our aim was to compare hazards of particles from combustion of biodiesel blends and conventional diesel (D(100)) in old and improved engines. We determined DNA damage in A549 cells, mRNA levels of CCL2 and IL8 in THP-1 cells, and expression of ICAM-1 and VCAM-1 in human umbilical cord endothelial cells (HUVECs). Viability and production of reactive oxygen species (ROS) were investigated in all cell types. We collected particles from combustion of D(100) and 20% (w/w) blends of animal fat or rapeseed oil methyl esters in light-duty vehicle engines complying with Euro2 or Euro4 standards. Particles emitted from the Euro4 engine were smaller in size and more potent than particles emitted from the Euro2 engine with respect to ROS production and DNA damage, but similarly potent concerning cytokine mRNA expression. Particles emitted from combustion of biodiesel blends were larger in size, and less or equally potent than particles emitted from combustion of D(100) concerning ROS production, DNA damage and mRNA of CCL2 and IL8. ICAM-1 and VCAM-1 expression in HUVECs was only increased by D(100) particles from the Euro4 engine. This suggests that particle emissions from biodiesel in equal mass concentration are less toxic than conventional diesel.     

Biometrie am BBI — Chancen und Randbedingungen

Der Betreiber eines Verkehrsflughafens muss Bereiche, die nicht allgemein zug?nglich sind, gegen unberechtigten Zugang sichern und darf, soweit es sich um sicherheitsempfindliche Bereiche handelt, den Zugang nur berechtigten Personen gestatten. Der Flughafenbetreiber gibt dazu an die Zutrittsberechtigten Ausweise aus, mit denen diese sich beim Betreten des Sicherheitsbereiches authentifizieren müssen. Für den neuen Flughafen Berlin-Brandenburg International BBI wird auf den Ausweisen wegen der stark wachsenden Anzahl der zu überprüfenden Personen als zus?tzliches Authentifizierungselement eine biometrische Referenz gespeichert. Bei der Auswahl des biometrischen Verfahrens sind die besonderen Bedingungen von Verkehrsflugh?fen in Betracht zu ziehen.     

A Material Model for TRIP‐Steels and its Application to a CrMnNi Cast Alloy

A material model is presented that accounts for strain rate dependent inelastic deformation and strain‐induced phase transformation in TRIP‐steels. Modifications for the kinetics equations of the strain‐induced phase transformation, introduced by Stringfellow, are proposed to overcome a drawback of Stringfellow's model. A parameter identification strategy that relies on Gauss‐Markov estimates is used to determine the model parameters from experimental data of a recently developed cast TRIP‐steel. Good agreement is observed between experimental results of the compression test and the corresponding finite element simulation employing the proposed model. This forms the basis for future applications of the material model in the design of composites and structures.     

Visuelle Analyse medizinischer Daten

In der Medizin werden gro?e Mengen an Daten generiert, die sich auf diagnostische Prozeduren, Behandlungsentscheidungen und Ergebnisse der Behandlung beziehen. Medizinische Bilddaten, z. B. Computertomografie (CT) und Kernspintomografiedaten (MRT), werden h?ufig akquiriert. Diese Daten müssen effizient analysiert werden, um klinische Entscheidungen ad?quat zu unterstützen. Insbesondere müssen Bildanalysetechniken, wie die Segmentierung und Quantifizierung anatomischer Strukturen und die visuelle Exploration der Daten, integriert werden. Neben den Anforderungen der individuellen Behandlung ergeben sich weitere Herausforderungen für die Datenauswertung aus den Bedürfnissen der klinischen Forschung, der ?ffentlichen Gesundheitsvorsorge und der Epidemiologie. Die Rolle des Benutzers ist hier die eines Forschers, der Daten untersucht und dabei z. B. potenzielle Korrelationen zwischen Risikofaktoren und der Entstehung von Erkrankungen analysiert. Die visuelle Exploration, bei der oft mehrere koordinierte Ansichten genutzt werden, und statistische Analysen müssen dazu geeignet integriert werden. Oft sind dabei die r?umliche (geografische) Verteilung der Patienten und die zeitliche Entwicklung von Erkrankungsf?llen wesentlich. Daher müssen die medizinischen Daten in ihrem r?umlichen und zeitlichen Bezug repr?sentiert werden, sodass eine enge Verbindung zwischen geografischen Informationssystemen und der Datenvisualisierung entsteht.