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91.
Surface preparation of various metals and alloys before plating and other finishing applications 总被引:1,自引:0,他引:1
Stephen F. Rudy 《Metal Finishing》2007,105(10):147-162
92.
James E. Shaw 《Journal of the American Oil Chemists' Society》1984,61(8):1389-1394
Oil displacement tests in water wet Berea sandstone cores containing residual crude oil flooded with water have shown that
high tertiary oil recoveries can be obtained using the sodium salts of readily available carboxylic acids. Using a 10% pore
volume surfactant slug containing 3.0% sodium isostearate and 3.0% isopentyl alcohol followed by a polyacrylamide mobility
buffer resulted in a 92% tertiary oil recovery, which compares well with recoveries using petroleum solfonates. Oil recoveries
were highly dependent on pH and added base. Aliphatic C18 carboxylates gave higher recoveries at lower pH using sodium bicarbonate
as the added base (pH 8.5) rather than sodium hydroxide, sodium carbonate or sodium orthosilicate (pH 11–13). In contrast,
aromatic carboxylates e.g., sodium p-(1-pentylnonyl)benzoate, gave higher recoveries at higher pH using sodium carbonate rather
than sodium bicarbonate. Carboxylates with branched alkyl groups, e.g., isostearate, gave higher tertiary oil recoveries than
unbranched carboxylates, e.g., oleate or stearate. Low cost tall oils and tall-oil fatty acids, when neutralized with base,
gave oil recoveries of 60–80%. Carboxylates were found to give good oil recoveries even when significant amounts of calcium
ion were present. 相似文献
93.
Indentation-crack-length procedures were used to determine the critical fracture toughness (KIC ) and the sensitivity to environmentally enhanced crack growth in heavy-metal fluoride glasses of varying chemical composition. The data show that while KIC was more or less invariant with composition, some glasses were more susceptible to subcritical crack growth than others. The results are interpreted in terms of existing crack-growth models. A technique for predicting KIC from fundamental atomic bonding and crystal-structure data for these glasses is discussed. 相似文献
94.
The aziridinyl group has been introduced as a terminal substituent into a series of monoazo disperse dyes; the dyes absorb hypsochromically in comparison with their counterparts containing larger terminal ring systems. When applied from aqueous dyebaths the dyes exhibit higher wash fastness on nylon 6.6 and diacetate fibres than conventional dispersedyes of similar structure and relative molecular mass. On polyester and triacetate fibresthe aziridinyl dyes display similar wash fastness to conventional dyes. Dye polymerisation and/or covalent fixation may account for the observed high fastness of the dyes on diacetate and nylon fibres. With the exception of nylon 6.6, the aziridinyl dyes display lower light fastness than conventional disperse dyes on the fibres studied, this being attributable to the greater susceptibility of the aziridinyl dyes to oxidative rather than reductive photodegradation. 相似文献
95.
Philip E. Sonnet Thomas A. Foglia Stephen H. Feairheller 《Journal of the American Oil Chemists' Society》1993,70(4):387-391
The fatty acid selectivity of several commercial lipases was evaluated in the hydrolysis of high-erucic acid rapeseed oil
(HEARO). The lipase ofPseudomonas cepacia catalyzed virtually complete hydrolysis of the oil (94–97%), while that ofGeotrichum candidum discriminated strongly against erucic acid, especially in esterification. A two-step process is suggested for obtaining a
highly enriched erucic acid in which theG. candidum lipase is employed to selectively esterify the fatty acid residues of unsaturated C-18, and shorter chain acids, from a mixture
of HEARO fatty acids obtained from total hydrolysis of the oil withP. cepacia lipase. 相似文献
96.
Career visual searchers such as radiologists and airport security screeners strive to conduct accurate visual searches, but despite extensive training, errors still occur. A key difference between searches in radiology and airport security is the structure of the search task: Radiologists typically scan a certain number of medical images (fixed objective), and airport security screeners typically search X-rays for a specified time period (fixed duration). Might these structural differences affect accuracy? We compared performance on a search task administered either under constraints that approximated radiology or airport security. Some displays contained more than one target because the presence of multiple targets is an established source of errors for career searchers, and accuracy for additional targets tends to be especially sensitive to contextual conditions. Results indicate that participants searching within the fixed objective framework produced more multiple-target search errors; thus, adopting a fixed duration framework could improve accuracy for career searchers. 相似文献
97.
Fei Yan Josef Kittler David Windridge William Christmas Krystian Mikolajczyk Stephen Cox Qiang Huang 《Image and vision computing》2014
Fully automatic annotation of tennis game using broadcast video is a task with a great potential but with enormous challenges. In this paper we describe our approach to this task, which integrates computer vision, machine listening, and machine learning. At the low level processing, we improve upon our previously proposed state-of-the-art tennis ball tracking algorithm and employ audio signal processing techniques to detect key events and construct features for classifying the events. At high level analysis, we model event classification as a sequence labelling problem, and investigate four machine learning techniques using simulated event sequences. Finally, we evaluate our proposed approach on three real world tennis games, and discuss the interplay between audio, vision and learning. To the best of our knowledge, our system is the only one that can annotate tennis game at such a detailed level. 相似文献
98.
A series of polyurethane (PU) films was prepared from chain-extended hydroxypropyl lignins (CEHPL). In appearance, these films ranged from brittle and dark brown to rubbery and bronze. The thermal, mechanical, and network properties of these PUs were investigated by DMTA and DSC analysis. All films exhibited single Tg's which varied between ?53° and 101°C, depending on lignin content. From swelling experiments, molecular weight between crosslinks (M c) was determined and found to vary over 2.5 orders of magnitude. The M c's were related to the change in Tg that accompanied network formation. Stress–strain experiments showed a variation in Young's modulus between 7 and 1300 MPa. Most of the variation in material properties was related to lignin content and to a lesser extent to diisocyanate type, hexamethylene diisocyanate, or toluene diisocyanate. The source of the CEHPL had no effect on the observed properties. From these results it was concluded that the properties of PUs can be controlled and engineered for a wide variety of practical uses. 相似文献
99.
Stephen Q. Zhou Liming Wang Xiugao Liao Georges Manuel William P. Weber 《Journal of Inorganic and Organometallic Polymers and Materials》1991,1(2):199-210
High molecular weight poly(1,1-dimethyl-1-germa-cis-pent-3-ene), poly(1,1-diphenyl-1-germa-cis-pent-3-ene), poly(1,1-dimethyl-1-sila-cis-pent-3-ene), and poly(1-methyl-1-phenyl-1-sila-cis-pent-3-ene) have been prepared. The thermal stability of these polymers is found to increase with their molecular weight. 相似文献
100.
An elimination strategy for solving sparse linear systems in bordered triangular form is presented. This strategy is designed to exploit certain common structural properties of the borders of such a system. It may also be interpreted as a recursive application of block elimination. The technique is numerically efficient and provides significant reductions in fill-in compared to routine Gaussian elimination. It is applicable in the iterative solution of the large systems of nonlinear equations that arise in the equation-oriented approach to process simulation and design calculations, as well as in other problems of interest to the chemical engineer. 相似文献