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121.
Daisuke Tashima Eri Yamamoto Nanami Kai Daisuke Fujikawa Go Sakai Masahisa Otsubo Tsuyoshi Kijima 《Carbon》2011,(14):4848-4857
Micro-mesoporous bimodal carbon nanospheres with high surface areas were synthesized by a combined use of surfactant templating technique and BaO2 chemical activation one. Starting spherical nanopolymer/surfactant composites were prepared by the NaOH-catalyzed reaction of resorcinol (R) and formaldehyde (F) in the presence of cetyltrimethylammonium bromide (CTAB) as a core template and 1,3,5-trimethylbenzene (TMB) and tert-butanol (t-BuOH) as cosurfactants. After pretreatment with hydrochloric acid, the composite materials were calcined at 1000 °C in N2 coexistent with varying weight ratios of BaO2 to RF polymer ranging from 0 to 11. It produced micro-mesoporous bimodal carbon nanospheres of 124–143 nm diameter, with specific surface areas as high as 1884 m2 g−1 or up to 3301 m2 g−1, in contrast to microporous ones with smaller surface areas obtained at low BaO2-loadings. The electrochemical double layer capacitance of the resulting nanocarbons in 0.5 M H2SO4 showed a marked increase with specific surface areas, up to as high as 219 F g−1 for the highest surface area carbon material. 相似文献
122.
Vujisić LV Makarov SE Curčić BP Ilić BS Tešević VV Gođevac DM Vučković IM Curčić SB Mitić BM 《Journal of chemical ecology》2011,37(12):1358-1364
Three European julid species, Cylindroiulus boleti, Leptoiulus trilineatus, and Megaphyllum bosniense, secrete mixtures of up to 12 different quinones. The major components in these species are 2-methoxy-3-methyl-1,4-benzoquinone
and 2-methyl-1,4-benzoquinone. 2-Methoxy-5-methylhydroquinone is detected for the first time in the Class Diplopoda. 2-Hydroxy-3-methyl-1,4-benzoquinone,
2,3-dimethoxyhydroquinone, 2-methyl-3,4-methylendioxyphenol, and 2,3-dimethoxy-5-methylhydroquinone are registered for the
first time in representatives of the family Julidae. The similar chemical composition of defense secretions in all analyzed
European julids and Pacific spirobolids supports the idea of the chemical consistency of defensive compounds in juliform millipedes. 相似文献
123.
Nan Xia Yongliang Wang Ping Zheng Go Sakaguchi Kenji Saijo Hirokazu Hasegawa 《Polymer》2011,52(8):1772-1780
In the present work, we report our work concerning the synthesis of heteropolymers of poly(?-caprolactone)-polyoxomolybdate-poly(?-caprolactone) using ring-opening polymerization (ROP) of ?-caprolactone monomer initiated by two hydroxyl groups attached on the two sides of a polyoxomolybdate cluster which was organically modified using pentaerythritols. Since the hydroxyl groups on polyoxomolybdate macroinitiator are less reactive, ring-opening polymerization were finally carried out by using 4,4′-(dimethylamino) pyridine to activate ?-caprolactone monomer. The polyoxomolybdate-containing heteropolymers were confirmed in detail by 1H NMR, FT-IR, GPC, TGA and XPS methods. Although the size of polyoxomolybdate cluster is extremely small compared to PCL chains, it was also found that POM played an important role in crystallization process. Self-assembly of such heteropolymers in mixed solvents were investigated and the analysis of formed spherical aggregates with multiple concaves on the surface was supported by TEM results and 3D electron tomography. 相似文献
124.
125.
A Unique Approach to Characterization of Sol‐Gel‐Derived Rare‐Earth‐Doped Oxyfluoride Glass‐Ceramics
Go Kawamura Ryota Yoshimura Kazunari Ota Song‐Yul Oh Norio Hakiri Hiroyuki Muto Tomokatsu Hayakawa Atsunori Matsuda 《Journal of the American Ceramic Society》2013,96(2):476-480
Using the sol‐gel route Nd3+‐doped oxyfluoride glass‐ceramics were prepared. LiYF4 and YF3 crystals were deposited in the glass‐ceramics and their size, distribution, and amount ratio were varied by changing the compositions and heating temperatures. The incorporation of Nd3+ ions into both the fluoride crystals was confirmed by the high‐resolution elemental mapping of the glass‐ceramics. The incorporated Nd3+ ions showed up and down conversion photoluminescence whose properties were obviously different among the samples. The preliminary site analysis for Nd3+ ions was carried out using a unique approach associated with the Prony series approximation. Finally, the approach was found to be useful for the analysis of materials that are structurally complicating. 相似文献
126.
Sanghee Won Seunghee Go Wonhee Lee Kyunghoon Jeong Hyunsuk Jung Chongmu Lee Eungu Lee Jaegab Lee 《Metals and Materials International》2008,14(6):759-765
Thin TiO2 layers grown at 130°C on SiO2-coated Si substrates by atomic layer deposition (ALD) using TTIP and H2O as precursors were annealed, and the effects of the annealing temperature on the resulting electrical properties of TiO2 and the interface properties between a Pt electrode and TiO2 were examined using transmission line model (TLM) structures. The as-deposited TiO2 thin film had an amorphous structure with OH groups and a high resistivity of 6×103Ω-cm. Vacuum annealing at 700 °C transformed the amorphous film into an anatase structure and reduced its resistivity to 0.04Ω-cm.
In addition, the vacuum-annealing of the TiO2/SiO2 structure at 700°C produced free silicon at the TiO2-SiO2 interface as a result of the reaction between the Ti interstitials and SiO2. The SiO2 formed on the TiO2 surface caused a Schottky contact, which was characterized by the TLM method. The use of the TLM method enabled the accurate
measurement of the resistivity of the vacuum-annealed TiO2 films and the characterization of the Schottky contacts of the metal electrode to the TiO2. 相似文献
127.
Go Hitoki Tsuyosi Takata Shigeru Ikeda Michikazu Hara Junko N. Kondo Masato Kakihana Kazunari Domen 《Catalysis Today》2000,63(2-4):175-181
Simple transition metal oxides such as NiO, Co3O4, Fe3O4 and Cu2O were found to catalytically decompose water into H2 and O2 by mechanical energy. The reaction is regarded as “mechano-catalytic” overall water splitting” and is a quite novel catalytic reaction. In this paper, some general aspects on the mechano-catalytic overall water splitting are reviewed on simple oxides. In addition, recent results on the mechano-catalytic activity of a groups of mixed oxides, wolramite-type oxides with a formula of ABO4 (A=Fe, Co, Ni and Cu, etc., B=W, Mo), are shown. AWO4 (A=Fe, Co, Ni and Cu) decomposed water into H2 and O2 under the supply of mechanical energy, indicating that mechano-catalytic overall water splitting proceeded on wolframite-type compounds containing 3d-transition metals. AMoO4 (A=Fe, Co, Ni) also decomposed water into H2 and O2 under supply of mechanical energy. The reaction properties on wolframite-type oxides are discussed. 相似文献
128.
Masaru Namura Yoshinori Sato Go Yamamoto Hisamichi Kimura Kenichi Motomiya Balachandran Jeyadevan 《Materials Letters》2009,63(15):1307-1310
LaC2@CNC/LaB6 nanocomposites were prepared using a spark plasma sintering system, and their mechanical properties and the intensity of characteristic La X-rays from the composites were characterized for application as X-ray target material. Using LaB6 as a binder, we succeeded in producing LaC2@CNC/LaB6 nanocomposites with a bulk density (2.91 g/cm3) and specific electric resistance (3.12 × 10− 4 Ω cm) through solidification at 2123 K. The fracture bending strength of LaC2@CNC/LaB6 nanocomposites (224 MPa) was 1.5 times larger than that observed for graphite/LaB6 composites. The most emitted characteristic La Lα X-ray from LaC2@CNC/LaB6 nanocomposites was 7743 counts/mm2/s in comparison with 6372 counts/mm2/s for graphite/LaB6 composites. 相似文献
129.
Functional properties of heat-induced gels prepared from microbial transglutaminase (TG)-treated porcine myofibrillar protein (MP) containing sodium caseinate with or without konjac flour (KF) under various salt concentrations (0.1, 0.3 and 0.6 M NaCl) were evaluated. The mixed MP gels with KF exhibited improved cooking yields at all salt concentrations. TG treatment greatly enhanced gel strength and elasticity (storage modulus, G′) at 0.6 M NaCl, but not at lower salt concentrations. The combination of KF and TG improved the gel strength at 0.1 and 0.3 M NaCl and G′ at all salt concentrations, when compared with non-TG controls. Incubation of MP suspensions (sols) with TG promoted the disappearance of myosin heavy chain and the production of polymers. The TG-treated MP mixed gels had a compact structure, compared to those without TG, and the KF incorporation modified the gel matrix and increased its water-holding capacity. Results from differential scanning calorimetry suggested possible interactions of MP with KF, which may explain the changes in the microstructure of the heat-induced gels. 相似文献
130.
Antioxidant (polyphenols and carotenoids) and nonantioxidant (phytosterols) bioactive compounds and dietary fiber may have a significant role in health. The intake of these compounds is strongly linked with the high consumption of fruits, vegetables, and unrefined cereals. A whole-diet approach to these food constituents is intended to render the current definition of Mediterranean diet based on food consumption more comprehensive. The Mediterranean dietary pattern can be characterized by the following four essential dietary indicators: 1) Monounsaturated to saturated fatty acid ratio (range: 1.6 to 2.0); 2) Intake of dietary fiber (41 to 62 g/person/day); 3) Antioxidant capacity of the whole diet (3500 to 5300 trolox equivalent/person/day); 4) Phytosterols intake (370 to 555 mg/person/day). The contribution of foods and beverages to these parameters is described. Spanish National Food Consumption Data for the years 2000 and 1964 were used to quantify the lowest and highest range values. The occurrence of these indicators in the Mediterranean diet has specific characteristics and there is sufficient scientific evidence to support the beneficial health effects. 相似文献