Progress in deep-UV photoresists

Higher resolution can be achieved in lithography by decreasing the wavelength of the exposure source. However, resist material and their processing are also important when we move to a shorter wavelength lithography technology. This paper reviews the recent development and challenges of deep-UV photoresists and their processing technology.     

Application of Strong Arcs in m-Polar Fuzzy Graphs

Neural Processing Letters - Recently, m-polar fuzzy graph (mPF graph) becomes a growing research topic as the generalization of fuzzy graph. In this paper, at first mPF path, mPF cycle in an mPF...     

Preparation of thermal resistant gas barrier chitosan nanobiocomposites

Nanobiocomposites of chitosan/clay were prepared by solution method using CuSO₄/glycine chelate complex as the catalyst with variable percentage of clay loading. The chemical interaction of chitosan and clay was studied by Fourier transform infrared spectroscopy. The structure of chitosan and clay nanobiocomposites was investigated by X‐ray diffraction and high resolution transmission electron microscopy. From thermogravimetric analysis, it was found that chitosan/clay nanobiocomposites were more thermally stable as compared to pure chitosan. A substantial reduction in oxygen permeability was obtained from the gas permeameter with increase in clay concentrations by which the synthesized nanocomposites materials may be used for packaging applications. POLYM. COMPOS., 35:2324–2328, 2014. © 2014 Society of Plastics Engineers     

A facile synthesis of a novel three‐phase nanocomposite: Single‐wall carbon nanotube/silver nanohybrid fibers embedded in sulfonated polyaniline

A three‐phase water‐soluble nanocomposite of single wall carbon nanotube/silver nanoparticle hybrid fibers embedded in sulfonated polyaniline has been synthesized by a simple chemical solution mixing process. The nanocomposite has been characterized by high resolution electron microscopy, X‐ray diffractometry, FTIR spectroscopy, Raman spectroscopy, and thermogravimetric analysis. Optical and electrical characteristics of the nanocomposite have been determined by UV–vis absorption spectroscopy, photoluminescence spectroscopy, and four‐probe electrical conductivity measurement. A surface plasmon absorption band obtained around 460 nm indicates the presence of silver nanoparticles in the composite. The optical band gap calculation for sulfonated polyaniline vis‐a‐vis the nanocomposite supported the conductivity measurement. Over 1300 times increase in DC electrical conductivity has been observed for the three‐phase nanocomposite, with a filler loading of 20 wt %, at 306 K. This observation could be explained by Mott's variable range hopping model considering a three‐dimensional conduction. Such a nanocomposite has immense potential for use as a cathode material in lithium‐ion batteries and supercapacitors. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41692.     

Carbon nanohorn‐graphene nanoplate hybrid: An excellent electrode material for supercapacitor application

This study describes the capacitor behavior of carbon nanohorn (CNH)/graphene nanoplate (GNP) hybrid (CNGN). The well‐CNH‐decorated GNP‐plate electrode materials show high capacitance value (≈677 F/g) and can be extensively used in new generation for energy storage. In the hybrid (CNGN), two nanofillers jointly affect the capacitance behavior and increase the capacitance value of the CNGN hybrid. Homogeneous coating of CNH over the GNP plate plays an effective role to enhance the capacitance behavior of the composite. Field emission scanning electron microscopy and high‐resolution transmission electron microscopy analysis of the composite confirmed the CNH coating on the GNP plate. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42118.     

Industrial scale synthesis of few-layer graphene nanosheets (FLGNSs): an exploration of electrochemical exfoliation approach

Journal of Applied Electrochemistry - Industrial scale manufacturing with tunable properties of graphene nano-sheets has been a practical concern in many applications. This study focuses on, a...     

Direct Numerical Simulation of pulsed jets-in-crossflow

Direct Numerical Simulations of a jet with a passive scalar injected vertically into a crossflow (velocity ratio = 6) is performed at a jet Reynolds number of 5000. The role of sinusoidal forcing of the jet on the dynamics of the flow structures, and on the jet trajectory and jet spreading is examined. Sinusoidal excitations selected are at non-dimensional frequencies of 0.2, 0.4, and 0.6. For the unforced jet, shear-layer vortices on the leading edge of the jet have a preferred mode frequency of around 0.35. With forcing, the dominant frequency in the near field of the jet is the forcing frequency, but further downstream, vortex interactions/mergings lead to the growth of the subharmonic modes. For a forcing frequency of 0.2, the jet bifurcates in the vertical plane; at a forcing frequency of 0.4, the jet trifurcates into three jet-streams in the vertical plane; and, at a forcing frequency of 0.6, the jet bifurcates in the horizontal plane. The largest vertical penetration is at a forcing frequency of 0.4, while the largest horizontal spreading occurs at a non-dimensional forcing frequency of 0.6. Wake vortices, with a U-loop structure, are seen for all cases except at a forcing frequency of 0.6, where they are completely suppressed. The U-loop structure is asymmetric for the unforced and 0.2 forcing frequency case, and is consistent with the earlier experimental observations for unpulsed jets-in-crossflow. Through particle visualizations, a mechanism for the development of the wake vortices is presented in the paper. Mean statistics on isosurface contours are also presented, and asymmetry in the mean counter-rotating kidney pair vortex structures are also seen for the unforced and 0.2 forcing cases. The results of this study indicate the potential of using external forcing as a potential control strategy for controlling the jet penetration and mixing with the crossflow in either the vertical plane or the horizontal plane.     

Separation of hematite from banded hematite jasper (BHJ) by magnetic coating

The separation of iron oxide from banded hematite jasper(BHJ) assaying 47.8% Fe, 25.6% Si O2 and 2.30%Al2O3 using selective magnetic coating was studied. Characterization studies of the low grade ore indicate that besides hematite and goethite,jasper, a microcrystalline form of quartzite, is the major impurity associated with this ore. Beneficiation by conventional magnetic separation technique could yield a magnetic concentrate containing 60.8% Fe with 51% Fe recovery. In order to enhance the recovery of the iron oxide minerals, fine magnetite, colloidal magnetite and oleate colloidal magnetite were used as the coating material. When subjected to magnetic separation, the coated ore produces an iron concentrate containing 60.2% Fe with an enhanced recovery of56%. The AFM studies indicate that the coagulation of hematite particles with the oleate colloidal magnetite facilitates the higher recovery of iron particles from the low grade BHJ iron ore under appropriate conditions.     

Synthesis and characterization of chitosan/cloisite 30B film for controlled release of ofloxacin

In this research program, chitosan film was prepared by blending chitosan with Cloisite 30 B at different concentrations 0 wt %, 1 wt %, and 2.5 wt %. The blends were characterized by Fourier transmission infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X‐ray diffraction (XRD) analysis. From the FTIR spectra the various groups present in chitosan/C 30 B blend were monitored. The homogeneity, morphology, and crystallinity of the blends were ascertained from SEM and XRD data, respectively. The most suitable form of blend was taken and used as a carrier for the controlled release of ofloxacin. The swelling studies have been carried out at different drug loading. Drug release kinetics was analyzed by plotting the cumulative release data versus time by fitting to an exponential equation which indicated the occurrence of non‐Fickian type of kinetics. The drug release was investigated at different pH medium and it was found that the drug release depends upon the pH medium as well as the nature of matrix. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012