国产气相聚乙烯浆液催化剂的工业应用

本文简要阐述了北化院BCS01和上海院SLC-S两种国产气相聚乙烯浆液催化剂的性能、催化剂结构,在Unipol聚乙烯工业装置上应用结果,以及和进口同类催化剂UCAT-J的性能比较。     

Effect of catalysts in the quality of syngas and by-products obtained by co-gasification of coal and wastes. 1. Tars and nitrogen compounds abatement

The aim of this work is to analyse the possibility of using co-gasification technology to process coal mixed with wastes to take profit of its energy content and at the same time to minimize the environmental impact associated with the use of wastes and to diminish the costs of flue gas treatment. The addition to coal of different types of materials, like: pine based waste, petcoke and polyethylene (PE), was not found to give rise to any operational problems, regarding both the feeding system and gasification process and led to higher energy conversions, however, the gas presented higher tars and hydrocarbons content. Several catalysts were tested, such as, dolomite, olivine, nickel and magnesium oxides, zinc oxides and cobalt and molybdenum oxides. Catalyst action was analysed in tars release and also in ammonia compounds reduction. The presence of catalysts allowed increasing hydrogen release, whilst there was a decrease in hydrocarbons and tars contents. A nickel-magnesium oxide was the catalyst that led to the highest reduction in hydrocarbons and tars. This catalyst also led to the lowest NH₃ content in the fuel gas produced, due to the catalyst efficiency in NH₃ destruction.     

国产耐火材料在欧洲3 300t/d生产线上的整体配套

Fushe-Kruje水泥厂项目位于距阿尔巴尼亚首都地拉那市28公里处，是由黎巴嫩SEAMENT集团投资兴建的．是迄今阿尔巴尼亚最大的外商投资项目，设计能力为3300t/d新型干法水泥熟料生产线，是全套生产线由我公司设计、制造成套、施工、安装、调试及试生产的总承包项目。     

Catalytic properties of aluminated sepiolite in ethanol conversion

The aluminated sepiolite, obtained by alkaline treatment with KAlO₂, as well as the silver-exchanged aluminated sepiolite were tested in ethanol conversion. The reactions were performed at 280°C and with 50 Torr of ethanol in He. After the alumination through KA1O₂, ethanol dehydrogenation and ethanol dehydration resulted from the Lewis acidity. The dispersion of silver led to a bifunctional catalytic system and the overall catalytic activity and the selectivity towards the acetaldehyde production increased. As a result of the Prins reaction, a significant yield in butadiene was observed.     

炭黑填充硬聚氯乙烯的改性

为使聚氯乙烯具有抗静电性能,采用加入具有导电性填料的方法,但加入大量的填料,会使硬聚氯乙烯的冲击性能降低,加工性能变差。本文是在以炭黑为填料的基础上,研究不同的改性剂和加工助剂改进硬聚氯乙烯的效果,结果表明,加入冲击改性剂和加工助剂后,大大增加了硬聚氯乙烯的冲击强度,且加工性能也得到改善,同时由于炭黑具有补强效果,其拉伸强度和弯曲强度在加入改性剂后也能满足使用要求。     

Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

金属间化合物的研究现状及其最新发展趋势

主要介绍了金属间化合物的概念、发展历程、研究现状及几种常用金属间化合物的发展状况，并提出了该类材料的最新发展趋势。     

用模糊规划证明期望放出体的合理性

文章采用模糊规划的方法证明了期望放出体在放矿中的合理性,从而使放矿这个复杂的过程能方便地采用数学手段来处理。同时说明了如何在崩落法矿山利用期望体来解决实际生产中的放矿问题。     

Two possible emission mechanisms involved in the arc discharge method of carbon nanotube preparation

By investigating the morphologies and microstructures of the cathode deposits prepared by self-sustained arc discharge between graphite rods, we consider that there are two electron emission mechanisms occurring on the cathode: field emission and thermionic emission. The former occurs mainly on the edge of the growing surface, by which we can explain the formation of the outer hard shell of the cathode deposit; while the latter occurs mainly on the growing surface except for the edge area and it is the main cause for the growth of carbon nanotubes.