湿浸法制备活性组分非均匀分布负载型催化剂过程的计算机模拟

对活性组分非均匀分布的负载型催化剂的湿浸法制备过程进行了计算机模拟,其模拟程度可适用于任意多个活性组分的浸渍。发现单组分浸渍时,通过控制浸渍时间可获得活性组分由薄到厚的蛋壳型分布和均匀分布,但通过预浸渍吸附至一定分布后,再在空白溶液中浸渍洗脱,控制洗脱条件也可获得蛋黄、蛋白型的分布;加入竞争吸附剂,进行双组分及多组分浸渍,通过控制浸渍溶液性质及浸渍时间可获得各种类型的活性组分分布,诸如蛋壳型、蛋白型、蛋黄型和均匀型。通过对制备过程参数(如竞争吸附剂的选择、各组分有效扩散系数、初始浓度、吸脱附速率常数等)与活性组分分布形式之间关系的分析,可实现对任一分布形式的催化剂的制备过程参数的优化。这对实际制备催化剂具有指导意义。     

Observer‐based H ∞ control for networked systems with bounded random delays and consecutive packet dropouts

This paper is concerned with the H _∞ control problem for a class of systems with bounded random delays and consecutive packet dropouts that exist in both sensor‐to‐controller channel and controller‐to‐actuator channel during data transmission. A new model is developed to describe possible random delays and packet dropouts by two groups of Bernoulli distributed stochastic variables. To avoid the state augmentation, a full‐order observer‐based feedback controller is designed via LMI approach. Based on the Lyapunov theory, a sufficient condition is provided to guarantee the closed‐loop networked system to be asymptotically mean‐square stable and achieve the prescribed H _∞ disturbance‐rejection‐attenuation level. The simulation examples illustrate the effectiveness of the proposed method. Copyright © 2013 John Wiley & Sons, Ltd.     

Preparation and characterization of a series of polyamides with long alkylene segments: Nylons 12 20, 10 20,s 20,6 20, 4 20 and 2 20

Summary A series of nylons with long alkylene segments between amide groups were newly prepared by step-heating melt-polycondensation of 1,lS-octadecanedicarboxylic acid with various diamines. The prepared polyamides were characterized carefully. The results show that many properties of the prepared nylons change regularly with the length of methylene segments in diamines. In addition, nylon 2 20 has a relatively low molecular weight and much different melting and thermal decomposition behaviors in comparison with other nylons. Received: 21 June 2OO2/Revised version: 18 September 2002/ Accepted: 18 September 2002 Correspondence to Deyue Yan E-mail: dyyan@mail.sjtu.edu.cn Tel: 0086-21-54742863 Fax: 0086-21-54741297     

一种通过USB接口的可靠固件升级技术

本文提出一种可靠固件升级的技术。该技术采用外部主晶振,工作异常时自动切换到校准后的内部晶振,还使用了DFU检测序列、看门狗等方法。相对于传统的固件升级技术,该技术具有抗干扰能力强、可靠、易于使用等优点。     

Interbay物料自动搬运系统性能分析

Interbay物料自动搬运系统的运行效率对于晶圆制造系统影响较大,研究Interbay物料自动搬运系统的绩效具有较大的意义[1]。该文以带有捷径的单闭环背脊式布局的物料自动搬运系统为研究对象,通过问题描述,简化、假设将实际问题抽象为导引运输模型。然后,建立数学模型,采用Dijkstra算法确定工件搬运的最短路径。最后,利用Arena仿真软件建立含有导引运输设备的模型,采用控制变量法探究小车数量小车占用轨道的方式、调度规则等因素对于产出的影响,发现对于本文中的模型,其它条件相同时,搬运系统采用Release-at-end的控制方式,系统最大搬运量越大。     

Spartan6芯片μC/OS-Ⅱ的可抢占式嵌套中断控制方法

介绍了Spartan6芯片搭载MicroBlaze软核的硬件平台,以及集成了μC/OS-Ⅱ操作系统的软件平台;给出了在此软硬件平台上的可抢占、可嵌套的中断机制的实现方法;灵活地运用面向底层硬件代码与操作系统代码之间的参数传递,协调了中断处理与任务调度之间的关系。阐述了方案的原理,给出了程序流程图;通过试验,验证了可抢占、可嵌套的中断机制的正确性与可行性。     

多媒体技术在高校教学中的应用

多媒体技术运用在高校音乐教学课堂中,不仅能为高校学生们营造一个生动的学习环境,吸引学生的兴趣,还能让学生直观地欣赏音乐,从而在在轻松的氛围中学习音乐知识,提高自己的音乐鉴赏水平。本文主要研究多媒体技术在高校音乐教学中的作用以及多媒体技术在高校音乐教学中的具体应用。     

特殊教育幼儿园中的导视系统设计分析简

随着我国越来越重视对特殊需要儿童的教育,特殊儿童幼儿园的人性化设计也成为了近几年热门的设计方向。导视系统的设计在特殊儿童幼儿园中起着非常重要的作用,完善的导视系统设计能够创造人性化的特殊教育幼儿园环境、儿童主体意识的确立和强化、对特殊儿童意愿需求的尊重和理解。同时,也能够让特殊教育儿童在使用中感到非常方便、自然。本文旨在构建功能合理的、具有人情味的、准确体现环境意象的导视系统设计,并且通过优秀的导视系统设计提高儿童在空间内行动的便捷性和安全性,提高空间环境使用的品质。     

成核剂对不同特性粘数PET结晶性能的影响

研究了新型复合成核剂水滑石(HT)／离聚物(Surlyn8920)／聚乙二醇(PEG)对不同特性粘数聚对苯二甲酸乙二醇酯(PET)非等温结晶性能的影响。通过差示扫描量热仪测试了PET的结晶峰温度T_(mc)和熔融峰温度(T_m)。结果表明,复合成核剂各组分及PET的质量比为0.5:3.0:3.0:100.0时,各种PET的过冷度(T_m-T_(mc))均显著减少．半结晶时间(1gt_(1／2))也明显降低。而且,复合成核剂对不同特性粘数PET结晶性能的改善是一致的。     

Crystal lattice deformation and the mesophase in poly(ethylene terephthalate) uniaxially drawn by solid-state coextrusion

The development of crystalline and mesophase structure on drawing of poly(ethylene terephthalate) (PET) has been studied. The uniaxial drawing has been done by solid-state coextrusion from 50 to 90°C. The unit-cell parameters of stress-induced crystallites in extrudates have been determined as a function of extrusion draw ratio (EDR) up to 4.4 and at an extrusion temperature (ET) above T_g, at 70 and 90°C. The higher the EDR, the longer the c-axis chain direction, the shorter the a and b axes and the smaller the unit-cell volume. In comparison with the conventional lattice parameters obtained by Bunn and Fisher, the highest elongation of the c axis is near 10%. These features imply that the lattice of stress-induced crystallites is far from the closest packing. Coextrudates made below the T_g of PET differ markedly from those made above T_g. Wide-angle X-ray diffraction (WAXD) patterns of PET extruded at 50°C (below T_g) even at high draw ratio exhibit small and/or imperfect crystallites. They appear much as a mesophase. The distance between macromolecular chains ranges from 3.2 to 5.4 Å. The shortest value in the mesophase approaches the interplanar crystal distance of 3.4 Å for the (100) crystal face, on which the benzene rings lie. The crystalline peak separation of the PET, WAXD curve has been evaluated to obtain absolute crystallinities and the content of mesophase and amorphous phase.