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991.
Sohn JI Joo HJ Kim KS Yang HW Jang AR Ahn D Lee HH Cha S Kang DJ Kim JM EWelland M 《Nanotechnology》2012,23(20):205707
We demonstrate that surface stresses in epitaxially grown VO? nanowires (NWs) have a strong effect on the appearance and stability of intermediate insulating M? phases, as well as the spatial distribution of insulating and metallic domains during structural phase transitions. During the transition from an insulating M1 phase to a metallic R phase, the coexistence of insulating M? and M? phases with the absence of a metallic R phase was observed at atmospheric pressure. In addition, we show that, for a VO? NW without the presence of an epitaxial interface, surface stresses dominantly lead to spatially inhomogeneous phase transitions between insulating and metallic phases. In contrast, for a VO? NW with the presence of an epitaxial interface, the strong epitaxial interface interaction leads to additional stresses resulting in uniformly alternating insulating and metallic domains along the NW length. 相似文献
992.
Yeh TW Lin YT Stewart LS Dapkus PD Sarkissian R O'Brien JD Ahn B Nutt SR 《Nano letters》2012,12(6):3257-3262
Uniform GaN nanorod arrays are grown vertically by selective area growth on (left angle bracket 0001 right angle bracket) substrates. The GaN nanorods present six nonpolar {1?100} facets, which serve as growth surfaces for InGaN-based light-emitting diode quantum well active regions. Compared to growth on the polar {0001} plane, the piezoelectric fields in the multiple quantum wells (MQWs) can be eliminated when they are grown on nonpolar planes. The capability of growing ordered GaN nanorod arrays with different rod densities is demonstrated. Light emission from InGaN/GaN MQWs grown on the nonpolar facets is investigated by photoluminescence. Local emission from MQWs grown on different regions of GaN nanorods is studied by cathodoluminescence (CL). The core-shell structure of MQWs grown on GaN nanorods is investigated by cross-sectional transmission electron microscopy in both axial and radial directions. The results show that the active MQWs are predominantly grown on nonpolar planes of GaN nanorods, consistent with the observations from CL. The results suggest that GaN nanorod arrays are suitable growth templates for efficient light-emitting diodes. 相似文献
993.
Aradhya SV Meisner JS Krikorian M Ahn S Parameswaran R Steigerwald ML Nuckolls C Venkataraman L 《Nano letters》2012,12(3):1643-1647
Electronic factors in molecules such as quantum interference and cross-conjugation can lead to dramatic modulation and suppression of conductance in single-molecule junctions. Probing such effects at the single-molecule level requires simultaneous measurements of independent junction properties, as conductance alone cannot provide conclusive evidence of junction formation for molecules with low conductivity. Here, we compare the mechanics of the conducting para-terminated 4,4'-di(methylthio)stilbene and moderately conducting 1,2-bis(4-(methylthio)phenyl)ethane to that of insulating meta-terminated 3,3'-di(methylthio)stilbene single-molecule junctions. We simultaneously measure force and conductance across single-molecule junctions and use force signatures to obtain independent evidence of junction formation and rupture in the meta-linked cross-conjugated molecule even when no clear low-bias conductance is measured. By separately quantifying conductance and mechanics, we identify the formation of atypical 3,3'-di(methylthio)stilbene molecular junctions that are mechanically stable but electronically decoupled. While theoretical studies have envisaged many plausible systems where quantum interference might be observed, our experiments provide the first direct quantitative study of the interplay between contact mechanics and the distinctively quantum mechanical nature of electronic transport in single-molecule junctions. 相似文献
994.
B- and N-doped carbon nanotubes (CNTs) with controlled workfunctions were successfully employed as charge trap materials for solution processable, mechanically flexible, multilevel switching resistive memory. B- and N-doping systematically controlled the charge trap level and dispersibility of CNTs in polystyrene matrix. Consequently, doped CNT device demonstrated greatly enhanced nonvolatile memory performance (ON-OFF ratio >10(2), endurance cycle >10(2), retention time >10(5)) compared to undoped CNT device. More significantly, the device employing both B- and N-doped CNTs with different charge trap levels exhibited multilevel resistive switching with a discrete and stable intermediate state. Charge trapping materials with different energy levels offer a novel design scheme for solution processable multilevel memory. 相似文献
995.
Back SY Song CH Yu S Lee HJ Kim BS Yang NY Jeong SH Ahn H 《Journal of nanoscience and nanotechnology》2012,12(1):446-450
Electrohydrodynamic (EHD) jet printing is a technique using electric fields to eject inks through nozzle apertures. EHD jet printing is very attractive due to its non-contacting nature and compatibility with diverse materials and substrates. In this research, we have fabricated micron-sized dot arrays and line patterns with carbon black ink on Si wafer substrates using EHD jet printing. The effect of operating conditions such as applied voltage, working distance and stage speed on the size and shape of the jetted patterns and jetting cycles is investigated by using optical microscope, high speed camera and atomic force microscopy (AFM). We have also demonstrated the drop-on-demand feature of the EHD jet printing system by patterning carbon black ink lines with various widths and dot arrays with desired diameters and spacing by controlling the operating conditions. 相似文献
996.
Park JS Kim DJ Park JW Ryu HS Kim KW Wang GX Ahn HJ 《Journal of nanoscience and nanotechnology》2012,12(7):5794-5798
An elemental sulfur and multi-walled carbon nanotube (S-MWNT) composite was synthesized by dissolving sulfur in ammonium sulfides and then precipitating on MWNT. Morphology observation by scanning electron microscopy (SEM) confirmed that S-MWNT product was successfully prepared by incorporating sulfur into MWNT network. Without additional conducting material, the S-MWNT composite cathodes were prepared for electrochemical tests. The properties measured in discharge-charge cycling test showed that the composite had the initial discharge capacity of 1024 mAh g(-1), which is about 61% sulfur utilization. However, in the subsequent cycling, the capacities faded. To determine the reason of rapid capacity drop, S-MWNT composite cathodes were compared in the cycling tests with varying three kinds of electrolytes and the cathode was subjected to physical force by rolling. The changes in the cycle performances proved that the deterioration of S-MWNT composite cathodes was not related to the electrolytes but to physical bonding that may not maintain the conducting path between sulfur and MWNT. 相似文献
997.
Park S Kim KS Roh JY Jang GB Ahn SH Lee CS 《Journal of nanoscience and nanotechnology》2012,12(4):3376-3379
High mechanical properties of a tungsten carbide micro-end-mill tool was achieved by extending its tool life by electroplating nano-sized SiC particles (< 100 nm) that had a hardness similar to diamond in a nickel-based material. The co-electroplating method on the surface of the micro-end-mill tool was applied using SiC particles and Ni particles. Organic additives (saccharin and ammonium chloride) were added in a Watts bath to improve the nickel matrix density in the electroplating bath and to smooth the surface of the co-electroplating. The morphology of the coated nano-sized SiC particles and the composition were measured using Scanning Electron Microscope and Energy Dispersive Spectrometer. As the Ni/SiC co-electroplating layer was applied, the hardness and friction coefficient improved by 50%. Nano-sized SiC particles with 7 wt% were deposited on the surface of the micro-end mill while the Ni matrix was smoothed by adding organic additives. The tool life of the Ni/SiC co-electroplating coating on the micro-end mill was at least 25% longer than that of the existing micro-end mills without Ni/SiC co-electroplating. Thus, nano-sized SiC/Ni coating by electroplating significantly improves the mechanical properties of tungsten carbide micro-end mills. 相似文献
998.
Kim YH Kim KS Lee JW Kim MS Choi JO Ahn SH Lee CS 《Journal of nanoscience and nanotechnology》2012,12(4):3478-3482
TiO2 layers were fabricated using a nano-particle deposition system (NPDS) on transparent conductive oxide (TCO) glass for dye sensitized solar cells (DSSCs). Conventionally, TiO2 paste for working electrodes has been fabricated using paste type methods. The fabricated paste composed of a mixture of nano-sized TiO2 powders, binders and solutions is then painted on TCO glass. After drying, the TiO2 layer on TCO glass is sintered to make a path for electron transfer. TiO2 layers formed by this paste type method require numerous steps, which can be time consuming. In this study, TiO2 powders were sprayed directly on TCO glass using NPDS in order to simplify the fabrication steps. To improve porosity and produce scattering layers, commercial nanocrystalline TiO, powders with different sizes were alternately deposited. Moreover, powders with different sizes were mixed and deposited on the TCO glass. The results indicate that the DSSCs with a TiO2 layer composed of different particle sizes had better cell performance than the cells assembled with single-sized TiO2 particles. Therefore, this study shows that a dry TiO2 coating process is possible for DSSC fabrication to improve its cell efficiencies, and this method can easily be applied on flexible substrates since NPDS is a room-temperature deposition process. 相似文献
999.
Shah AA Kang H Kohlstedt KL Ahn KH Glotzer SC Monroe CW Solomon MJ 《Small (Weinheim an der Bergstrasse, Germany)》2012,8(10):1551-1562
DC electric fields are used to produce colloidal assemblies with orientational and layered positional order from a dilute suspension of spheroidal particles. These 3D assemblies, which can be visualized in situ by confocal microscopy, are achieved in short time spans (t < 1 h) by the application of a constant voltage across the capacitor-like device. This method yields denser and more ordered assemblies than had been previously reported with other assembly methods. Structures with a high degree of orientational order as well as layered positional order normal to the electrode surface are observed. These colloidal structures are explained as a consequence of electrophoretic deposition and field-assisted assembly. The interplay between the deposition rate and the rotational Brownian motion is found to be critical for the optimal ordering, which occurs when these rates, as quantified by the Peclet number, are of order one. The results suggest that the mechanism leading to ordering is equilibrium self-assembly but with kinetics dramatically accelerated by the application of the DC electric field. Finally, the crystalline symmetry of the densest structure formed is determined and compared with previously studied spheroidal assemblies. 相似文献
1000.
Yoon SW Seo JH Chae KH Park JK Song JH Jayaram V Lee KB Seong TY Hoon-Kwon Ahn JP 《Journal of nanoscience and nanotechnology》2012,12(2):1476-1479
AIN/CrN multilayer hard coatings with various bilayer thicknesses were fabricated by a reactive sputtering process. The microstructural and mechanical characterizations of multilayer coatings were investigated through transmission electron microscope (TEM) observations and the hardness measurements by nano indentation. In particular, the variation of chemical bonding states of the bilayer nitrides was elucidated by near edge X-ray absorption fine structure (NEXAFS) spectroscopy. Many broken nitrogen bonds were formed by decreasing the bilayer thickness of AIN/CrN multilayer coatings. Existence of optimum AIN/CrN multilayer coatings thickness for maximum hardness could be explained by the competition of softening by the formation of broken nitrogen bonds and strengthening induced by decreasing bilayer thickness. 相似文献