Investigation of Scale Formation in Heat Exchangers of Phosphoric Acid Evaporator Plants

The primary problem in concentrating phosphoric acid is due to fouling on the tube‐side of the heat exchangers of the evaporator units. Scaling on the heat transfer surfaces occurs because of high supersaturation of phosphoric acid liquor with respect to calcium sulphate. A review of the existing literature reveals that no information is available on heat transfer and on crystallization fouling of industrial phosphoric acid solutions. In this investigation, the solubility of different calcium sulphate types in phosphoric acid solution was studied and its dependency on acid concentration and temperature was investigated. A large number of fouling experiments were carried out in a side‐stream of a phosphoric acid plant at different flow velocities, surface temperatures and concentrations to determine the mechanisms, which control the deposition process. After identifying the effects of operational parameters on the deposition process, a model was developed for prediction of fouling resistances. The reaction of calcium sulphate crystallization followed a second order rate with respect to the supersaturation. The activation energy evaluated for the surface reaction of the deposit formation was found to be 57 kJ/mol. The predicted fouling resistances were compared with the experimental data. Quantitative and qualitative agreement between measured and predicted fouling rates is good.     

Preparation and characterization of polyurethane microcapsules containing n‐octadecane with styrene‐maleic anhydride as a surfactant by interfacial polycondensation

A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the T_m and T_c of microPCMs were in the range of 29.8–31.0^oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006     

ACCELERATION AMBIGUITY FUNCTION OF RADAR SIGNALS AND ITS APPLICATION

High acceleration of radar targets is analyzed using Acceleration Ambiguity Function(AAF). The acceleration resolution based on AAF is defined. The AAF and acceleration resolution of rectangle pulse signal are derivated and the conclusion that its acceleration resolution is in inverse proportion with the square of its duration is drawn. In the end, these conclusions are applied to the parameter designing and performance evaluation for a certain type of pulse Doppler radar.     

A One‐Kilobit PQR‐CMOS Smart Pixel Array

The photonic quantum ring (PQR) laser is a three dimensional whispering gallery (WG) mode laser and has anomalous quantum wire properties, such as microampere to nanoampere range threshold currents and √T‐dependent thermal red shifts. We observed uniform bottom emissions from a 1‐kb smart pixel chip of a 32×32 InGaAs PQR laser array flip‐chip bonded to a 0.35 µm CMOS‐based PQR laser driver. The PQR‐CMOS smart pixel array, now operating at 30 MHz, will be improved to the GHz frequency range through device and circuit optimization.     

Ubiquitous Information Services with JAIN Platform

To provide responsive information services in a ubiquitous computing environment, service software and system development are indispensable. A component-based ubiquitous information system with a JAIN (Java APIs for Integrated Networks) platform to achieve seamless transmissions and reach-everywhere communications was designed in our research. In this development, numerous ubiquitous service modules were identified: location management, roaming, mobile IP and WAP networking. These component-based network modules were constructed using a component composition language with component specification and interface definition, running on top of a distributed service architecture using a JAIN platform to distribute the ubiquitous information services to mobile users. Two applications, Wireless-Application-Protocol (WAP) Mail and Video-on-Demand (VoD) services, show that the JAIN-like platform with the developed networking components effectively fills the gap for application developers between mobile appliances and various kinds of ubiquitous information services.     

拳王阿里

该片根据拳王阿里的故事改编而成。编导在影片中不但在努力塑造这位世界三大拳击组织的金腰带获得者，而且还塑造成了一个另类英雄。从更深的层面上看，正是因为阿里的传奇经历早已超越了一个体育明星的影响力。作为社会活动家与慈善大使，对发展中国家进行人道主义救援成为了这位拳王生活中极为重要的内容。他对他这一代人以及后来的几代人的影响为世人所公认。