全文获取类型
收费全文 | 74619篇 |
免费 | 16904篇 |
国内免费 | 1264篇 |
专业分类
电工技术 | 2200篇 |
技术理论 | 6篇 |
综合类 | 1954篇 |
化学工业 | 23950篇 |
金属工艺 | 2469篇 |
机械仪表 | 3005篇 |
建筑科学 | 4051篇 |
矿业工程 | 790篇 |
能源动力 | 2100篇 |
轻工业 | 9106篇 |
水利工程 | 795篇 |
石油天然气 | 1983篇 |
武器工业 | 160篇 |
无线电 | 11339篇 |
一般工业技术 | 16446篇 |
冶金工业 | 2837篇 |
原子能技术 | 455篇 |
自动化技术 | 9141篇 |
出版年
2024年 | 93篇 |
2023年 | 540篇 |
2022年 | 933篇 |
2021年 | 1501篇 |
2020年 | 2294篇 |
2019年 | 3861篇 |
2018年 | 3953篇 |
2017年 | 4325篇 |
2016年 | 4811篇 |
2015年 | 5034篇 |
2014年 | 5463篇 |
2013年 | 7030篇 |
2012年 | 4904篇 |
2011年 | 4925篇 |
2010年 | 4806篇 |
2009年 | 4670篇 |
2008年 | 4106篇 |
2007年 | 3710篇 |
2006年 | 3446篇 |
2005年 | 2962篇 |
2004年 | 2564篇 |
2003年 | 2602篇 |
2002年 | 2550篇 |
2001年 | 2300篇 |
2000年 | 2026篇 |
1999年 | 1500篇 |
1998年 | 1135篇 |
1997年 | 831篇 |
1996年 | 708篇 |
1995年 | 549篇 |
1994年 | 520篇 |
1993年 | 361篇 |
1992年 | 303篇 |
1991年 | 240篇 |
1990年 | 188篇 |
1989年 | 178篇 |
1988年 | 138篇 |
1987年 | 109篇 |
1986年 | 104篇 |
1985年 | 57篇 |
1984年 | 71篇 |
1983年 | 63篇 |
1982年 | 34篇 |
1981年 | 43篇 |
1980年 | 29篇 |
1979年 | 22篇 |
1978年 | 22篇 |
1977年 | 31篇 |
1976年 | 58篇 |
1975年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
For this study, we first prepared a fluorocarbon polymer and its hybrid materials. We found that fluorocarbon copolymers can produce hydrogen bonds with SiO2 to form hybrid materials. We also used thermogravimetric analyzer and tested the thermostabilities of the four products, which were ranked as follows: fluorocarbon copolymer/SiO2 hybrid material > fluorocarbon polymer/SiO2 hybrid material > fluorocarbon copolymer > fluorocarbon polymer. In addition, we found that, due to the inorganic SiO2 used, the number of pores and the specific surface areas of the hybrid materials both increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1140–1145, 2007 相似文献
992.
The O-methylation of phenol with dimethyl carbonate proceeds selectively in the vapor phase over alkali ion exchanged X-zeolites. Thus, a 76% yield of anisole was obtained with a 93% selectivity over NaX at 553 K. The participation of basic sites in the O-methylation is suggested. 相似文献
993.
The purpose of this investigation was to study the origin of the differences in paper‐to‐paper friction of linerboards based on old corrugated containers (OCC). The sheets were subjected to two extraction stages and analyzed with respect to, surface roughness, and their content of low‐molecular‐mass lipophilic compounds (LLC). Friction was measured using a friction tester based on the horizontal plane principle. The surface roughness was measured using a Perthometer profiler and the low molecular mass lipophilic constituent of the paper sheets was determined by gas chromatography‐mass spectroscopy. The sheets were imaged using environmental scanning electron microscopy (ESEM), and the relative compositions of inorganic ions on the paper surfaces were determined by energy dispersive X‐ray spectroscopy (EDS). The results showed that a high amount of LLC in the sheets lead to low friction, due to lubrication. It was also observed that large CaCO3 particles on the surface had a friction‐increasing effect, and that there was no relationship between the surface roughness and the friction. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1511–1520, 2002 相似文献
994.
The relative viscosity (RV) of polyvinylpyrrolidone (PVP) with different molecular weights was measured with a glass capillary viscometer and with a differential dual‐capillary viscometer in water at different concentrations. For the differential dual‐capillary viscometer, RV increases with a decreasing flow rate, especially for high molecular weight PVP at a 1% concentration. A good agreement in the RV between the two methods can be obtained for PVP with different molecular weights and at various concentrations if an appropriate flow rate is selected for the differential dual‐capillary viscometer. Special precaution is needed when using the differential dual‐capillary viscometer to measure the viscosity of a pure solvent. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1312–1315, 2002 相似文献
995.
Yuan‐Hsiang Yu Chien‐Chih Jen Hsiu‐Ying Huang Pei‐Chi Wu Chao‐Cheng Huang Jui‐Ming Yeh 《应用聚合物科学杂志》2004,91(6):3438-3446
A series of heterocyclically conjugated polymer–clay nanocomposite (PCN) materials that consisted of organic poly(3‐hexylthiophene) (P3HT) and inorganic montmorillonite (MMT) clay platelets were prepared by in situ oxidative polymerization with FeCl3 as an oxidant. The as‐synthesized PCN materials were characterized by Fourier transform infrared (FTIR) spectroscopy, wide‐angle powder X‐ray diffraction (WAXRD), and transmission electron microscopy (TEM). The effects of the material composition on the anticorrosion, gas barrier, thermal stability, flammability, mechanical strength, and electrical conductivity properties of the P3HT and PCN materials were studied by electrochemical corrosion measurements, gas‐permeability analysis (GPA), thermogrametric analysis (TGA), limiting oxygen index (LOI) measurements, dynamic mechanical analysis (DMA), and a four‐point probe technique, respectively. The molecular weights of extracted and bulk P3HT were determined by gel permeation chromatography (GPC) with THF as an eluant. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3438–3446, 2004 相似文献
996.
Jun-Bin Ko Sung Wook Lee Dong Eun Kim Young Un Kim Gang Li Seung Goo Lee Tae-Sun Chang Dojin Kim Yong Lak Joo 《Journal of Porous Materials》2006,13(3):325-330
(1 − x)SiO2-(x)ZrO2 (x = 0.1, 0.2) composite fiber mats were prepared by electrospinning their sol-gel precursors of zirconium acetate and tetraethyl
orthosilicate (TEOS) without using a polymer binder. The electrospun composite fibers were characterized by powder X-ray diffraction
(XRD), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FT-IR) and mercury porosimetry. The composite
fibers having a tetragonal crystalline ZrO2 were obtained by calcining the electrospun composite fibers at high temperatures. The results show that the structure and
crystallization of ZrO2 in the composite fibers can be controlled by sintering temperature, while the porosity and morphology of the fiber mats did
not depend on the sintering temperature. 相似文献
997.
A good way of achieving compatibility in polymer blends of poly(styrene‐co‐acrylonitrile) (S/AN) and bisphenol A polycarbonate (PC) is the chemical modification of S/AN in the melt. A catalyzed reaction of the nitrile groups with a substituted 2‐amino alcohol or 2‐amino phenol resulted in a conversion of nitrile groups of 55–75% in 60 min. The introduced heterocyclic structures were ethyl hydroxymethyl oxazoline (EHMOXA) and benzoxazole (BenzOXA), respectively. The use of dibutyltin oxide as a catalyst led to the highest efficiency. The modified polymer was characterized by Fourier transform infrared and NMR spectroscopy, elemental analysis, and reactions with organic acids and anhydrides. The modified S/AN showed good technical compatibility (single glass‐transition temperature) with PC in blends made from solution and from the melt. All blends were characterized with oscillating rheometry and differential scanning calorimetry. Rheological measurements showed that EHMOXA–S/AN reacted with PC and had crosslinked structures, whereas BenzOXA–S/AN showed compatibilization without any (crosslinking) reaction. The melt blends of BenzOXA–S/AN and PC showed a downward shift in the complex viscosity due to the influence of the BenzOXA group. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2322–2332, 2003 相似文献
998.
Mahmoud A.‐Halim Abdel‐Goad 《应用聚合物科学杂志》2004,91(4):2543-2547
In efforts to contribute to community development, particularly in the context of Egyptian communities, waste plastics materials were successfully recycled without the difficult task of separation and reused to economically produce new structural material. Recycling was performed by mixing molten waste plastics with sand to produce these new materials. Samples with different percentages of plastics and different particle sizes of sand were used in the process. Materials showed acceptable density and high compressive strength, which was shown to be at a maximum with contents of about 30–40% waste plastic. Furthermore, certain types of sand having different colors were used to produce attractive materials, suitable for decorative uses. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2543–2547, 2004 相似文献
999.
1000.
Polypropylene/poly(methyl acrylate)‐grafted glass wool (PMA‐g‐GW) mixes were prepared. The polymerization process was carried out using potassium persulfate (PPS) and PPS/acetone sodium bisulfite (ASBS) as a redox‐pair initiation system at 60 and 70°C. The effect of using PPS or PPS/ASBS on the grafting percent and conversion percent reveals that the conversion percent values on using PPS as an initiator are higher than those of PPS/ASBS, while in the case of grafting, the inverse is true, that is, using PPS as an initiator gives grafting percent values lower than those that can be obtained using PPS/ASBS. The dielectric properties, thermal diffusivity, specific heat capacity, and thermal conductivity of PP loaded with modified glass wool as a function of different types and concentrations of initiators—used in the grafting polymerization process, namely, PPS and the redox initiating system—were also studied. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 723–732, 2003 相似文献