Anchoring of Chiral Manganese(III) Salen Complex onto Organo Clay and Porous Clay Heterostructure and Catalytic Activity in Alkene Epoxidation

The chiral Mn(III) salen complex (C1) was immobilised onto a natural clay (BEN) and a porous clay heterostructure (PCH) functionalised with 3-aminopropyltriethoxysilane (APTES). FTIR, XPS and Mn chemical analysis confirm the C1 anchorage in both materials, but with higher efficiency in BEN_APTES clay. The catalytic activity of C1@BEN_APTES and C1@PCH_APTES, was assessed in the epoxidation of styrene (sty) and ∝-methylstyrene (∝-Mesty) using NaOCl and m-chloroperoxybenzoic acid (m-CPBA)/N-methylmorpholine-N-oxide (NMO). Both materials behave as moderate catalysts, show high epoxide selectivity but low enantiomeric excesses. In the case of sty epoxidation with m-CBPA/NMO the C1@PCH_APTES catalyst showed the highest catalytic activity, whereas in ∝-Mesty epoxidation, the C1@PCH_APTES catalyst, although leading to lower substrate conversion than the BEN analogue, presented the lowest complex leaching. In all cases, the oxidant NaOCl had some destructive effect in the hybrid catalysts, highlighting the importance of a careful choice of catalyst and oxidant system.     

Reprocessing of spent nuclear waste using ionic liquids

Nuclear power has once again attracted from all over the world due to many factors including the rise in oil process and environmental concerns on greenhouse gas emission resulting in global warming. However, spent fuel from nuclear power reactors is an enormous problem both from radiation hazard and economical point of view. Therefore, this review presents an overview of application of ionic liquids (ILs) in spent fuel reprocessing, particularly in the extraction of high-level radioactive aqueous waste from the processing of nuclear fuel.     

Fabrication of Multiscale Gradient Polymer Patterns by Direct Molding and Spatially Controlled Reflow

Size variations of pattern spacing as well as gradient control of the as‐formed polymeric pattern via a spatially controlled reflow process are presented. Micro‐ and nanopatterns of polymethyl methacrylate (PMMA) in the form of line‐and‐space strips are first generated by capillary force lithography (CFL), and the residual layers are removed by ashing process. Subsequently, the exposed PMMA strips underwent a controlled reflow process above the glass transition temperature (T_g) while heating single or both sides of the substrate either in parallel to the line pattern (parallel reflow) or perpendicular to the line pattern (perpendicular reflow). As a result of this controlled reflow, a linear or a parabolic profile of pattern spacing is achieved depending on the heating mode. Furthermore, multiscale gradient patterns are formed with the spacing ranging from 98 nm to 4.23 μm (a difference of two orders of magnitude) in a single patterned layer using the original micropattern of 16 μm width and 8 μm spacing. In order to explain reflow behaviors, a simple theoretical model relating the normalized pattern width to the polymer viscosity is derived based on a leveling kinetics of polymer melt. Also, gradient PMMA channels are fabricated and bonded to a glass substrate, which are used to flow a liquid inside the channels by capillarity‐driven flow.     

Rate-Adaptive MAC Protocol for Wireless Multicast Over OFDMA-Based MANETs

Unlike in unicast transmissions, a feedback channel has not been implemented for multicast transmission over Mobile ad hoc networks (MANET), due to the increase in the overhead with increasing group member size. As a result, rate-adaptation for wireless multicast has not been considered either. In this paper, a novel rate-adaptive Medium Access Control protocol is proposed to allow dynamic rate-adaptation for wireless multicast transmission over MANETs by utilizing the orthogonality of the subcarriers in an Orthogonal Frequency-Division Multiplexing system. In the proposed rate-adaptation method, each member station is assigned a unique subcarrier and by using this subcarrier, its preferred data rate in the current channel condition is reported to the multicast source. Due to their orthogonality, the feedbacked packets simultaneously transmitted by the group members can be distinguished at the source. Therefore, the source chooses the most appropriate data rate for all member stations. By using this method, the data rate for wireless multicast is able to be adaptively changed, so that the overall network performance is improved.     

Effect of Solid Fat Content on Structure in Ice Creams Containing Palm Kernel Oil and High-Oleic Sunflower Oil

ABSTRACT: The development of a structural fat network in ice cream as influenced by the solid:liquid fat ratio at the time of freezing/whipping was investigated. The solid fat content was varied with blends of a hard fraction of palm kernel oil (PKO) and high-oleic sunflower oil ranging from 40% to 100% PKO. Fat globule size and adsorbed protein levels in mix and overrun, fat destabilization, meltdown resistance, and air bubble size in ice cream were measured. It was found that blends comprising 60% to 80% solid fat produced the highest rates of fat destabilization that could be described as partial coalescence (as opposed to coalescence), lowest rates of meltdown, and smallest air bubble sizes. Lower levels of solid fat produced fat destabilization that was better characterized as coalescence, leading to loss of structural integrity, whereas higher levels of solid fat led to lower levels of fat network formation and thus also to reduced structural integrity. Practical Application: Blends of highly saturated palm kernel oil and monounsaturated high-oleic sunflower oil were used to modify the solid:liquid ratio of fat blends used for ice cream manufacture. Blends that contained 60% to 80% solid fat at freezing/whipping temperatures produced optimal structures leading to low rates of meltdown. This provides a useful reference for manufacturers to help in the selection of appropriate fat blends for nondairy-fat ice cream.     

Comparison of constituents, antioxidant potency, and acetylcholinesterase inhibition in Lentinus edodes, Sparassis crispa, and Mycoleptodonoides aitchisonii

This study evaluates three edible mushrooms: Lentinus edodes, Sparassis crispa, and Mycoleptodonoides aitchisonii, in terms of acetylcholinesterase (AChE) inhibition, antioxidant potency and constituents free amino acids and mineral. The concentration of essential amino acids was found to be 34.10 mg/g in M. aitchisonii, 26.25 mg/g in S. crispa, 25.99 mg/g in L. edodes. S. crispa displayed the highest DPPH scavenging activity and phenolic contents. The best results for AChE inhibition were obtained from M. aitchisonii. These results suggest that M. aitchisonii has high potential for cognitive improvement by AChE inhibition and antioxidant potency.     

Adsorption backup following light-emitting diode-irradiated photocatalytic unit for control of low-degraded toxic gaseous compounds

Although several visible light-emitting diode (LED)-irradiated photocatalysts exhibited low photocatalytic decomposition efficiencies for toxic gaseous pollutants, activated carbon fiber (ACF) has rarely been used as a backup adsorption device for photocatalytic systems. Accordingly, this study accessed the applicability of a supplemental ACF following a visible LED-irradiated S-TiO₂ unit for the control of low-degraded benzene and toluene. The characteristics of the S-TiO₂ and ACF were determined using an XRD, a UV-Vis-NIR, and an FTIR spectrophotometer. For an LED/S-TiO₂ system, low degradation efficiencies regarding benzene and toluene (close to zero-7.2% and 7.1–64.4%, respectively) were found. In contrast, the mean degradation efficiencies of both compounds obtained from the photocatalytic-ACF hybrid system were all close to 100%. In addition, no peaks were observed in the gas chromatogram of air samples taken at the outlet of the hybrid system, whereas several trace peaks were observed in the standalone photocatalytic reactor results. The breakthrough of the ACF occurred at approximately 14 and 28 hours for benzene and toluene, respectively, and saturation occurred at approximately 28 and 42 hours, respectively. Consequently, this study newly found that the supplemental activated carbon fiber following a visible LED-irradiated S-TiO₂ unit could be applied effectively for the control of low-degraded toxic benzene and toluene.     

Effect of Amphipathic HIV Fusion Inhibitor Peptides on POPC and POPC/Cholesterol Membrane Properties: A Molecular Simulation Study

T-20 and T-1249 fusion inhibitor peptides were shown to interact with 1-palmitoyl-2-oleyl-phosphatidylcholine (POPC) (liquid disordered, ld) and POPC/cholesterol (1:1) (POPC/Chol) (liquid ordered, lo) bilayers, and they do so to different extents. Although they both possess a tryptophan-rich domain (TRD), T-20 lacks a pocket binding domain (PBD), which is present in T-1249. It has been postulated that the PBD domain enhances FI interaction with HIV gp41 protein and with model membranes. Interaction of these fusion inhibitor peptides with both the cell membrane and the viral envelope membrane is important for function, i.e., inhibition of the fusion process. We address this problem with a molecular dynamics approach focusing on lipid properties, trying to ascertain the consequences and the differences in the interaction of T-20 and T-1249 with ld and lo model membranes. T-20 and T-1249 interactions with model membranes are shown to have measurable and different effects on bilayer structural and dynamical parameters. T-1249’s adsorption to the membrane surface has generally a stronger influence in the measured parameters. The presence of both binding domains in T-1249 appears to be paramount to its stronger interaction, and is shown to have a definite importance in membrane properties upon peptide adsorption.     

SnO<Subscript>2</Subscript>-core/SiO<Subscript>x</Subscript>-shell coaxial whiskers with a needle-like morphology

Needle-shaped structures of tin oxide (SnO₂) were coated with a shell layer of SiO_x via a sputtering method. The diameters of the SiO_x-coated structures gradually became thinner, leading to the formation of sharp tips. The whiskers consisted of a crystalline SnO₂ core surrounded by an amorphous SiO_x shell. The photoluminescence (PL) spectrum with a Gaussian fitting exhibited yellow-green and orange light emission bands, and the overall shape and intensity of the PL spectrum were not changed by the SiO_xcoating. The results of this study suggest that sputtering can be employed to achieve the layered growth of shell layers on a variety of nanostructures.