Synthesis of polyethylene oxide end‐capped with perfluoroalkyl groups/polystyrene prototype brushes

Polystyrene (PS)/poly(ethylene oxide) (PEO) prototype brushes were prepared by alternating free‐radical copolymerization of methacryloyl‐terminated PS and α‐vinylbenzyl‐ω‐hydroxy or α‐vinylbenzyl‐ω‐perfluoroalkyl (R_f) PEO macromonomers with the addition of Lewis acid (SnCl₄). It was found from their dilute‐solution properties that PS/PEO end‐capped with R_f (PBR_f), and PS/PEO having OH groups at terminal ends (PBOH) prototype brushes formed a single molecule in benzene and aggregates in chloroform, respectively. However, the brush PBOH formed a single molecule in N,N‐dimethylformamide. Such aggregation behaviors seemed to be caused by the interaction between hydroxy groups of PEO chain ends. The brush PBOH was also converted into PBR_f‐type brush by chemical modification, using corresponding acid chloride. The substitution of R_f groups was ～70% due to slipping of terminal hydroxy groups into PEO internal domains. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 772–778, 2006     

New polylactide/layered silicate nanocomposites. 5. Designing of materials with desired properties

Understanding the structure/property relationship in polymer/layered silicate nanocomposites is of great importance in designing materials with desired properties. In order to understand these relations, a series of polylactide (PLA)/organically modified layered silicate (OMLS) nanocomposites have been prepared using a simple melt extrusion technique. Four different types of OMLS have been used for the preparation of nanocomposites, three were modified with functionalized ammonium salts while fourth one was a phosphonium salt modified OMLS. The structure of the nanocomposites in the nanometer scale was characterized by using wide-angle X-ray diffraction and transmission electron microscopic observations. Using four different types of layered silicates modified with four different types of surfactants, the effect of OMLS in nanocomposites was investigated by focusing on four major aspects: structural analysis, thermal properties and spherulite morphology, materials properties, and biodegradability. Finally, we draw conclusions about the structure/property relationship in the case of PLA/OMLS nanocomposites.     

Domain Adaptation for Structured Regression

Discriminative regression models have proved effective for many vision applications (here we focus on 3D full-body and head pose estimation from image and depth data). However, dataset bias is common and is able to significantly degrade the performance of a trained model on target test sets. As we show, covariate shift, a form of unsupervised domain adaptation (USDA), can be used to address certain biases in this setting, but is unable to deal with more severe structural biases in the data. We propose an effective and efficient semi-supervised domain adaptation (SSDA) approach for addressing such more severe biases in the data. Proposed SSDA is a generalization of USDA, that is able to effectively leverage labeled data in the target domain when available. Our method amounts to projecting input features into a higher dimensional space (by construction well suited for domain adaptation) and estimating weights for the training samples based on the ratio of test and train marginals in that space. The resulting augmented weighted samples can then be used to learn a model of choice, alleviating the problems of bias in the data; as an example, we introduce SSDA twin Gaussian process regression (SSDA-TGP) model. With this model we also address the issue of data sharing, where we are able to leverage samples from certain activities (e.g., walking, jogging) to improve predictive performance on very different activities (e.g., boxing). In addition, we analyze the relationship between domain similarity and effectiveness of proposed USDA versus SSDA methods. Moreover, we propose a computationally efficient alternative to TGP (Bo and Sminchisescu 2010), and it’s variants, called the direct TGP. We show that our model outperforms a number of baselines, on two public datasets: HumanEva and ETH Face Pose Range Image Dataset. We can also achieve 8–15 times speedup in computation time, over the traditional formulation of TGP, using the proposed direct formulation, with little to no loss in performance.     

Application of enzymatically gelled chitosan solutions to water‐resistant adhesives

An investigation was undertaken on the application of dilute chitosan solutions gelled by tyrosinase‐catalyzed reaction with 3,4‐dihydroxyphenethylamine (dopamine). The tyrosinase‐catalyzed reaction with dopamine conferred water‐resistant adhesive properties to the semidilute chitosan solutions. The viscosity of the chitosan solutions increased highly by the tyrosinase‐catalyzed reaction and the subsequent reactions between o‐quinone compounds and chitosan. These highly viscous, gel‐like modified chitosan materials were allowed to spread onto the surfaces of the glass slides, which were tightly lapped together and held them in water. Tensile shear adhesive strength of over 400 kPa was observed for the modified chitosan samples. The increase in the amino group concentration of the chitosan solutions and the molecular mass of the chitosan used effectively led to the increase in adhesive strength of the glass slides. In addition, in the case where the chitosan solution was gelled by the enzymatic reaction with dopamine in the presence of poly(ethylene glycol), adhesive strength sharply increased at shorter reaction times concomitantly with the increase in the viscosity of the chitosan solutions because the tyrosinase activity effectively was retained by poly(ethylene glycol). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1818–1827, 2007     

Desulphurization of coals and chars by treatment in various atmospheres between 400 and 600 °C

Desulphurization of fifteen US coals of rank ranging from anthracite to sub-bituminous B and five high-temperature chars by carbon monoxide and other gases and gas mixtures between 400 and 600 °C has been studied. The sulphur content of the parent coals ranged between 3.0 and 7.3% and that of the chars between 1.3 and 3.8% by weight. A comparison between air, nitrogen, carbon monoxide, and steam-carbon monoxide mixtures as desulphurizing gases shows the order of desulphurizing ability as

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FORCED CONVECTIVE MASS TRANSFER IN ANNULI

Mass transfer in annuli has been critically examined for various flow situations. The overall mass transfer rate depends on the hydrodynamic regions prevailing in the annular channel as well as on its dimensions. Theoretically consistent correlations are proposed and recommended for both developed and developing boundary layers under laminar and turbulent flow conditions.     

Development of three-electrode type micro-electrochemical reactor on anodized aluminum with photon rupture and electrochemistry

Photon rupture with a focused single pulse of pulsed YAG-laser irradiation was used to fabricate an aluminum electrochemical micro-reactor. Porous type anodic oxide film formed on aluminum specimens was irradiated in solutions with a pulsed Nd-YAG laser beam through a convex lens to fabricate micro-channels, micro-electrode, and through holes (for reference electrode, solution inlet, and outlet). During irradiation, specimens were moved by a computer controlled XYZ stage. After irradiation, the surface of the micro-channel and through hole were again treated to form anodic oxide film and the surface of the micro-electrode was treated electrochemically to provide an Au layer. The calculated volume of the micro-reactor including micro-channel and through holes is about 1.5 μl. The cyclic voltammogram of the micro-electrochemical cell was measured in K₃Fe(CN)₆/K₄Fe(CN)₆ with both static and flowing solution at different scanning rates. The anodic and cathodic peak currents were measured and the values depended on scanning rate and ion concentration when the solution was static. With the flowing solution, limiting currents were observed and the anodic limiting current was increased with the cubic root of the solution flow rate.     

Sesamin is a potent and specific inhibitor of Δ5 desaturase in polyunsaturated fatty acid biosynthesis

Incubation with sesame oil increases the mycelial dihomo-γ-linolenic acid content of an arachidonic acid-producing fungus,Mortierella alpina, but decreases its arachidonic acid content [Shimizu, S., K. Akimoto, H. Kawashima, Y. Shinmen and H. Yamada (1989)J. Am. Oil Chem. Soc. 66, 237–241]. The factor causing these effects was isolated and identified to be (+)-sesamin. The results obtained in experiments with both a cell-free extract of the fungus and with rat liver microsomes demonstrated that (+)-sesamin specifically inhibits Δ5 desaturase at low concentrations, but does not inhibit Δ6, Δ9 and Δ12 desaturases. Kinetic analysis showed that (+)-sesamin is a noncompetitive inhibitor (K_i for rat liver Δ5 desaturase, 155 μM). (+)-Sesamolin, (+)-sesaminol and (+)-episesamin, also inhibited only Δ5 desaturases of the fungus and liver. These results demonstrate that (+)-sesamin and related lignan compounds present in sesame seeds or its oil are specific inhibitors of Δ5 desaturase in polyunsaturated fatty acid biosynthesis in both microorganisms and animals. On leave from Suntory Ltd.     

Prediction of burning rate of coal in fluidized-bed combustion

A theory has been proposed to evaluate the burning rate of a single carbon particle in a continuously operated coal-fired fluidized bed. Experimental verification was carried out in a laboratory scale 200 mm × 200 mm combustor. The burning rate increases with the increase of the fluidization velocity and the size of the bed material. The predicted data on burning rate agree fairly well with the experimental values. The gas concentration in the bed and freeboard has also been measured and it is seen that the consumption of oxygen mostly takes place in the bed.     

Structure and properties of nanocomposites based on poly(butylene succinate) and organically modified montmorillonite

Poly(butylene succinate) and organically modified montmorillonite nanocomposites with there different compositions were prepared via melt blending in a twin‐screw extruder. The structure of the nanocomposites was studied with X‐ray diffraction and transmission electron microscopy, which revealed the formation of intercalated nanocomposites, regardless of the silicate loading. Dynamic mechanical analysis revealed a substantial increase in the storage modulus of the nanocomposites over the entire temperature range investigated. The tensile property measurements showed a relative increase in the stiffness with a simultaneous decrease in the yield strength in comparison with that of neat poly(butylene succinate). The oxygen gas barrier property of neat poly(butylene succinate) improved after nanocomposite preparation with organically modified montmorillonite. The effect of the layered‐silicate loading on the melt‐state linear viscoelastic behavior of the intercalated nanocomposites was also investigated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 777–785, 2006