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51.
Thermosensitive networks based on hydroxypropyl cellulose and N‐isopropylacrylamide crosslinked with N,N‐methylene bisacrylamide were synthesized by a simultaneous gamma radiation technique. The network yield was optimized by the variation of reaction parameters such as the total radiation dose, concentration of crosslinker and monomer, and amount of water. The hydrogels had a biphasic structure and good mechanical strength, even in the fully swollen state, and could be synthesized in any shape and size. Volume transitions as a function of time and temperature were studied for these hydrogels in water, and the effects on swelling in different media such as 0.5N NaOH, 0.5N HCl, and 5% NaCl at the optimum time and temperature were also studied. The response of the hydrogels to these diverse changes in the swelling media was observed, and the volume transitions due to environmental changes in the hydrogels were not sharp and discontinuous as a maximum volume collapse occurred at a temperature higher than the reported lower critical solution temperature of 32.5°C for N‐isopropylacrylamide. These hydrogels were environmentally sensitive and responded to changes in their thermal and ionic environment and have potential applications in diverse fields such as drug delivery, enzyme technology, and environmental management. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 479–488, 2004 相似文献
52.
Average self-diffusion coefficients of hydrated protons in sulfonated poly (ether sulfone) (SPES), Interpolymer and Nafion 117 membranes are measured by impedance spectroscopy and pulsed field gradient nuclear magnetic resonance (PFG NMR). Self-diffusion coefficient measured by impedance spectroscopy shows two patterns, one is at the low hydration states, i.e. λ = 2–4 and another at the high hydration states (starting from λ = 4). At lower hydration states the diffusion values increases slowly while steep increment is found at higher hydration level. PFG NMR shows similar trend throughout the measurements. The diffusion coefficients at higher temperatures are higher than at lower temperatures as a function of λ for SPES membrane. At the same value of λ, hydrated proton self-diffusion coefficient is found to be increased by 18% from 295.5 to 303 K. The thermo-mechanical properties of the membranes characterised by the means of DSC, TGA and DMA analysis show SPES, stable up to 450 °C and can be used for the high-temperature applications. 相似文献
53.
Surface ultrastructure of gills in relation to the feeding ecology of an angler catfish Chaca chaca (Siluriformes,Chacidae) 下载免费PDF全文
Arup Mistri Neeraj Verma Usha Kumari Swati Mittal Ajay Kumar Mittal 《Microscopy research and technique》2016,79(10):973-981
Surface ultrastructure of the gills of the angler catfish Chaca chaca was investigated to unravel the adaptive modifications associated with the feeding ecology of the fish. The fish is often found in mud or in soft substrates where they remain buried both for protection and to feed. Gill rakers present on the gill arch in most fish species are absent in this fish. The absence of gill rakers are associated with the feeding habit of the fish and is considered to facilitate the swallowing of captured prey smoothly without any hindrance. Highly corrugated surface of the gill arch and gill filaments could be associated to retain water/mucus to prevent dessicassion of the fish. Papillae like epithelial protuberances each bearing a taste bud at its summit toward the pharyngeal side of the gill arch is associated with the sorting of the food. Large number of mucous goblet cells on the gill arch epithelium are considered to secret copious mucus to lubricate the prey for easy swallowing. In C. chaca the gill septa between gill filaments are reduced. This could enhance the flexibility and permit the free movement of the gill filaments. Extensive secondary lamellae and infrequent mucous goblet cells on secondary lamellae are associated to increase the surface area to enhance efficiency of gaseous exchange. 相似文献
54.
A. Das N. Banerjee S. Sen B. Neogi S. Simlandi N. Barman 《Transactions of the Indian Institute of Metals》2012,65(6):815-820
In the present work, a study on the double diffusive convection and the macro-segregation during solidification of an Al-alloy (A356) is considered based on the macro?Cmicro model. The model considers a volume average single-domain approach to represent all the variables and properties as continuum in the entire domain where the transport phenomena during solidification are represented by mass, momentum, energy and species conservation equations. The evolution of solid during solidification, in the model, is predicted based on the microscopic phenomena, i.e. considering the nucleation and the growth of the nuclei. A semi-implicit finite volume method is adopted to discretize the governing equations and the discretized linear simultaneous equations are solved based on the SIMPLER and the TDMA algorithms. The simulation involves prediction of temperature, velocity and species in the computation domain during solidification of the alloy. A parametric study is also considered. 相似文献
55.
Abhay Kumar Singh Mukesh K. Mahato Babita Neogi K. K. Singh 《Mine Water and the Environment》2010,29(4):248-262
In a qualitative assessment of mine water from the Raniganj coalfield, 77 mine water samples were analyzed to assess water
quality and suitability for domestic, industrial, and irrigation uses. The pH of the mine water ranged from 6.5 to 8.8. Total
dissolved solids (TDS) ranged from 171 to 1,626 mg L−1; spatial differences between the TDS values reflect variations in lithology, activities, and prevailing hydrological regime.
The anion chemistry was dominated by HCO3
− and SO4
2−. On average, Cl− contributes 10 and 19% of the total anionic balance, respectively, in the Barakar and Raniganj Formation mine water. F− and NO3
− contribute <2% to the total anions. The cation chemistry is dominated by Mg2+ and Ca2+ in the mine water of the Barakar Formation and Na+ in the Raniganj Formation mines. Much of the mine water, especially of the Barakar Formation area, has high TDS, total hardness,
and SO4 concentrations. Concentrations of some trace metals (i.e. Fe, Cr, Ni) were found to be above the levels recommended for drinking
water. However, the mine water can be used for irrigation, except at some sites, especially in the Raniganj Formation area,
where high salinity, sodium adsorption ratio, %Na, residual sodium carbonate, and excess Mg restrict its suitability for agricultural
uses. 相似文献
56.
Debapriya Mohanty Rajashree Jena Ritesh Pattnaik Swati Mohapatra Manish Ranjan Saini 《International Journal of Food Properties》2016,19(4):837-846
In recent decades, bioactive peptides have attracted increasing interest as health promoting functional foods. A variety of naturally formed bioactive peptides have been found in fermented dairy products such as yogurt, sour milk, and cheese. Initially these peptides are inactive within the sequence of the parent protein molecule and can be generated by gastrointestinal digestion of milk, fermentation of milk with proteolytic starter cultures, and/or hydrolysis by proteolytic enzymes. Milk derived peptides exert a number of health beneficial activities, even upon oral administration. Bioactive peptides have a great impact on major body systems including the digestive, nervous, endocrine, cardiovascular, diabetes type II, obesity, and immune systems. Antimicrobial peptides are also an important ingredient of innate immunity, especially at mucosal surfaces such as lungs and small intestine that are constantly exposed to a range of potential pathogens. Therefore, it plays an important role in boosting natural immune protection by reducing the risk of chronic diseases. Bioactive peptides are considered as potent drugs with well-defined pharmacological residues and also used to formulate health-enhancing nutraceuticals. 相似文献
57.
Llopis A. Jie Lin Jianyou Li Pereira S. Neogi A. 《IEEE journal of selected topics in quantum electronics》2009,15(5):1400-1405
The emission and recombination characteristics of UV or blue light emission from InGaN/GaN quantum well (QW) structures influenced by V-shaped pits have been investigated by near-field and time-resolved photoluminescence measurements. Localization of charge carriers due to the potential barriers caused by the V-shaped pit formation is observed to be modified by thermal excitation. Temperature dependence of recombination dynamics shows evidence of a more complex potential barrier produced by the inverted hexagonal pits embedded within the multiple QWs. The emission from the narrow V-shaped pit QWs shows anomalous temperature dependence behavior that is significantly different from the emission from c-plane QWs. The carrier recombination process in c-plane QWs is significantly longer ~ 5 ns compared to the ~ 1.5 ns in V-shaped pit QWs at low temperatures due to the larger piezoelectric fields in wider wells. At room temperature, the recombination lifetimes are comparable due to increased carrier separation and delocalization within the V-shaped pit QWs. 相似文献
58.
Schiavo S Ebbel E Sharma S Matson W Kristal BS Hersch S Vouros P 《Analytical chemistry》2008,80(15):5912-5923
A novel approach to the parallel coupling of normal-bore high-performance liquid chromatography (LC) with electrochemical-array detection (EC-array) and nanoelectrospray mass spectrometry (MS), based on the use of a nanosplitting interface, is described where both detectors are utilized at their optimal detection mode for parallel configuration. The dual detection platform was shown to maintain full chromatographic integrity with retention times and peak widths at half-height between the EC-array and MS displaying high reproducibility with relative standard deviations of <2%. Detection compatibility between the two detectors at the part per billion level injected on-column was demonstrated using selected metabolites representative of the diversity typically encountered in physiological systems. Metabolites were detected with equal efficiency whether neat or in serum, demonstrating the system's ability to handle biological samples with limited sample cleanup and reduced concern for biological matrix effects. Direct quantification of known analytes from the EC-array signal using Faraday's law can eliminate the need for isotopically labeled internal standards. The system was successfully applied to the detection and characterization of metabolites of phenylbutyrate from serum samples of Huntington's disease patients in an example that illustrates the complementarity of the dual detection nanoelectrospray LC-EC-array-MS system. 相似文献
59.
Vinamrita Singh Swati Arora P. K. Bhatnagar Manoj Arora R. P. Tandon 《Journal of Polymer Research》2012,19(6):1-6
We have investigated the degradation of P3HT:PCBM (poly(3-hexylthiophene):6,6-phenylC61 butyric acid methyl ester) solar cell beyond 150?h of fabrication in continuation to our earlier reported work up to 150?h of fabrication. The current- voltage characteristics of degraded Indium tin oxide/poly(3,4-ethylenedioxythiopene):poly(styrenesulfonate)/poly(3-hexylthiophene):6,6-phenylC61 butyric acid methyl ester/Aluminum (ITO/PEDOT:PSS/P3HT:PCBM/Al) solar cell can be explained by considering the tunneling current through electrode interfaces, increase in both the interface states density and the thickness of interface with time for150-200?h. Beyond 200?h of fabrication, a significant reduction in the occupation probability at the electrode interfaces explains the experimental results up to 300?h fairly well. Calculations based on realistic parameters and activity at both the electrode interfaces (ITO/PEDOT:PSS and P3HT:PCBM/Al) confirm that degradation at P3HT:PCBM/Al interface is more prominent than that at ITO/PEDOT:PSS interface. 相似文献
60.
M. Swati O. P. Karthikeyan Kurian Joseph C. Visvanathan R. Nagendran 《Canadian Metallurgical Quarterly》2011,15(4):321-330
Four pilot-scale lysimeters were used to study the benefits of landfill operation with and without leachate recirculation in tropical weather conditions. Young and old landfills were simulated by filling lysimeters with a segregated fraction of fresh municipal solid waste (MSW) and MSW mined from an open dump site, respectively, and periodically monitoring leachate quantity and quality and biogas quality. For each substrate, one lysimeter was operated as a bioreactor with leachate recirculation and another lysimeter was operated as a controlled dump, for a period of 10 months. Densities between 652 and 825??kg/m3 could be achieved with fresh and mined MSW. Despite such compaction during waste placement, bioreactor technology helps in leachate management, especially in the case of the young landfill lysimeter operated in tropical weather. The benefits of leachate recirculation in the young landfill lysimeter were evident from the significant decrease in chemical oxygen demand (COD) (86%), biochemical oxygen demand (BOD) (82%), dissolved organic carbon (DOC) (85%), and volatile solids (75%) in leachates. However, ammonia nitrogen (amm-N) and chlorides in the leachates accumulated in bioreactor landfills. Operating an old landfill lysimeter as a bioreactor seemed to have no exceptional advantage in the context of leachate management, although leachate recirculation enhanced the methane potential of both fresh and mined MSW. 相似文献