White graphene based composite proton exchange membrane: Improved durability and proton conductivity

Boron nitride, which is also known as “white graphene” may be an attractive filler for composite proton exchange membrane. Application of polymer electrolyte membranes in fuel cell as an electrolyte is gaining attention due to the requirement of clean energy. However, despite its attractive features it requires more consideration for complete commercialization. Herein we demonstrate the preparation of novel functionalized WHITE GRAPHENE (hexagonal boron nitride) and sulfonated poly ether sulfone (SPES) based polymer electrolyte membranes (PEM). Composite membranes have been characterized through thermal, mechanical, structural analysis. Membranes have been subjected to measure methanol permeability and proton conductivity at different temperatures for its use in DMFC. Composite membranes exhibit good physicochemical properties as well as high methanol crossover resistance. 0.5 wt % of FBN (SP-FBN-05) membrane is found to be adequate to get the better performance in DMFC.     

Feature Selection for Recognition of Online Handwritten Bangla Characters

Feature selection through optimization techniques provides an interesting approach to minimize computational time with enhanced prediction capability, and     

Effect of heating and acidic pH on characteristics of wheat gluten suspension

The effects of different pH treatments with and without heating on the characteristics of wheat gluten suspension was investigated. At pH 1, maximum changes in colour were observed with a concurrent 65% decrease in protein free-thiol content compared to the control gluten. The SDS-Extractability of protein (SDS-EP) chromatogram eluted at lower retention time and the presence of bands at the top lane even during reducing conditions in SDS-PAGE gel suggested complex formation involving bonds other than disulphides. An increase in the free-amino group content and the presence of an additional peak at a higher retention time in the SDS-EP chromatogram was suggestive of hydrolysis. At pH 2 and 3, similar decreases in SDS-EPs and free-thiol content indicated formation of complexes. When heated, the free-thiol content of the dispersions increased compared to the non-heated dispersions indicating disruption of disulphide bonds with changes in gluten structure and size distribution.     

Periodically Fully Developed Heat and Fluid Flow Characteristics in a Furrowed Wavy Channel

Periodically fully developed two-dimensional (2D) flow in a furrowed wavy channel is investigated numerically at various Reynolds numbers (100–2123). For the laminar and transitional flow regime, the study is done for six geometrically different channels; corresponding to various nondimensional amplitude (0.05, 0.075, and 0.1) and wavelength (0.5 and 1). Critical Reynolds number—for the onset of periodic flow—decreases with increasing amplitude and wavelength. A flow regime map—demarcating steady and unsteady flow regime—is proposed. It is shown that the size of the vortex in streamlines and waviness in isotherms increase with increasing Reynolds number, amplitude and wavelength. The performance of wavy as compared to straight channel is studied with the help of ratio of Nusselt number, friction factor and area-goodness factor, and thermal-performance factor. With increasing Reynolds number, all these parameters remain almost constant in the steady regime and increase almost linearly in the unsteady regime. For the largest Reynolds number (close to 2000) studied here, the increase in the Nusselt number ratio—within the periodic flow regime—is 11.21% and 133% for the amplitude equal to 0.075 and 0.1, respectively, at a wavelength of 0.5; at a wavelength of 1.0, the increase is 101%, 134%, and 181% for the amplitude of 0.05, 0.075, and 0.1, respectively.     

Enhancement of properties of recycled coarse aggregate concrete using bacteria

Due to rapid construction, necessity for raw materials of concrete, especially coarse aggregate, tends to increase the danger of early exhaustion of the natural resources. An alternative source of raw materials would perhaps delay the advent of this early exhaustion. Recycled coarse aggregate (RCA) plays a great role as an alternative raw material that can replace the natural coarse aggregate (NCA) for concrete. Previous studies show that the properties of RCA concrete are inferior in quality compared to NCA concrete. This article attempts to study the improvement of properties of RCA concrete with the addition of bacteria named as Bacillus subtilis. The experimental investigation was carried out to evaluate the improvement of the compressive strength, capillary water absorption, and drying shrinkage of RCA concrete incorporating bacteria. The compressive strength of RCA concrete is found to be increased by about 20% when the cell concentration of B. subtilis is 10⁶ cells/ml. The capillary water absorption as well as drying shrinkage of RCA are reduced when bacteria is incorporated. The improvement of RCA concrete is confirmed to be due to the calcium carbonate precipitation as observed from the microstructure studies carried out on it such as EDX, SEM, and XRD.     

Ideas generated in conceptual design and their effects on creativity

Search of design spaces to generate solutions affects the design outcomes during conceptual design. This research aims to understand the different types of search that occurs during conceptual design and their effect on the design outcomes. Additionally, we study the effect of other factors, such as creativity, problem-solving style, and experience of designers, on the design outcomes. Two sets of design experiments, with experienced and novice designers, are used in this study. We find that designers employ twelve different types of searches during conceptual design for problem understanding, solution generation, and solution evaluation activities. Results also suggest that creativity is influenced positively by the type and amount of searches, duration of designing, and experience of designers.     

Autonomous bioremediation of a microbial protein (bioremediase) in Pozzolana cementitious composite

The self-bioremediation in cementitious composite material is one of the most interesting avenues relating to damage management and self-life of constructions, which needs to be cogitated. The self-bioremediation of a microbial protein-impregnated cementitious material has been explored in this work. The bioremediase protein was isolated from a hot spring bacterium (BKH1) and incorporated at three different concentrations into commercial Pozzolana cements that are widely used for mortar sample preparation. Artificial cracks were generated within the mortar samples by applying partial breaking load (50 %) and the samples were cured under water for different days. Image analysis by Crackscope and microstructure analysis by field emission scanning electron microscope ascertained the formation of irregular crystalline healing material within the cracks of the test samples. X-ray diffractometer and energy dispersive spectra analyses confirmed that the irregular crystalline structures were due to the deposition of new silicate phase (Gehlenite) within the cracks. Increase of ultrasonic pulse velocity and compressive strength, augmentation of sulphate resistance, decrease of chloride permeability and water absorption capacity revealed that there were overall improvement of mechanical properties and durability of the protein-incorporated mortar samples compared to the control (without protein incorporation) mortar samples. This cost effective and eco-friendly self-bioremediation phenomenon observed in mortar is evolved due to the biosilicification activity of bioremediase protein when amended in mortar samples. The exceptional potential of the microbial bioremediase protein for self-bioremediation attribute may add a new dimension in self-healing construction technology in near future.