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31.
Wax esters were isolated from commercial orange roughy (Hoplostethus atlanticus) oil by column chromatography and fractionated by argentation thin layer chromatography. Following transesterification, the
resultant fatty acid methyl esters and fatty alcohols were analyzed by gas chromatography. both acyl- and alkyl-moieties were
mainly of the monoene structure within the 16∶1–22∶1 range. After derivatization, the positions of the double bonds of even
numbered fatty acid and fatty alcohol isomers were located by chromatography-mass spectrometry and compared.
Results of these positional analyses indicate that the primary desaturation reactions takes place in the Δ9 position of pre-existing
(C14 to C24) acyl chains. It is proposed that acyl components from 18∶1 are subjected to chain elongation to form a mixture of 24∶1 isomers
as the final product. Apart from the 24∶1 acyl moiety of the wax esters, in which the double bond was almost exclusively in
the Δ15 position, de novo biosynthetic reactions on acids and alcohols appear to yield related acyl- and alkyl-moieties of
resynthesized wax esters. 相似文献
32.
The effects of a forming atmosphere on the stability, the sintering and the dielectric properties of Ba5Nb4O15, BaNb2O6, ZnNb2O6 and Zn3Nb2O8 ceramics were investigated, because of the primary importance of the sintering atmosphere in relation to copper sintering. These Nb-based materials were sintered in air and in Ar/H210%. Zn-containing samples are very sensitive to the reductive atmosphere. ZnO volatilises at 800–850 °C and the resulting compound does not exhibit the expected properties. BaNb2O6 and Ba5Nb4O15 are more stable in term of relative weight loss. Nevertheless, the phase analysis reveals a modification of the BaNb2O6 phase, what induces the degradation of the dielectric property stability versus temperature. The properties of Ba5Nb4O15 are not modified by a sintering in reductive atmosphere. A relative permittivity of 38.8, a permittivity temperature coefficient of −150 ppm °C−1 and an insulating resistivity of 1010.9 Ω cm were obtained for this latter. 相似文献
33.
Makoto Kanazawa Gregory M. Kobele Jens Michaelis Sylvain Salvati Ryo Yoshinaka 《Theory of Computing Systems》2014,55(1):250-278
Seki et al. (Theor. Comput. Sci. 88(2):191–229, 1991) showed that every m-multiple context-free language L is weakly 2m-iterative in the sense that either L is finite or L contains a subset of the form \(\{ u_{0} w_{1}^{i} u_{1} \cdots w_{2m}^{i} u_{2m} \mid i \in \mathbb {N}\}\) , where w 1?w 2n ≠ε. Whether every m-multiple context-free language L is 2m-iterative, that is to say, whether all but finitely many elements z of L can be written as z=u 0 w 1 u 1?w 2m u 2m with w 1?w 2m ≠ε and \(\{ u_{0} w_{1}^{i} u_{1} \cdots w_{2m}^{i} u_{2m} \mid i \in \mathbb {N}\} \subseteq L\) , has been open. We show that there is a 3-multiple context-free language that is not k-iterative for any k. 相似文献
34.
Arkadev Chattopadhyay Ricard Gavaldà Kristoffer Arnsfelt Hansen Denis Thérien 《Theory of Computing Systems》2014,55(2):404-420
Boolean functions that have constant degree polynomial representation over a fixed finite ring form a natural and strict subclass of the complexity class ACC0. They are also precisely the functions computable efficiently by programs over fixed and finite nilpotent groups. This class is not known to be learnable in any reasonable learning model. In this paper, we provide a deterministic polynomial time algorithm for learning Boolean functions represented by polynomials of constant degree over arbitrary finite rings from membership queries, with the additional constraint that each variable in the target polynomial appears in a constant number of monomials. Our algorithm extends to superconstant but low degree polynomials and still runs in quasipolynomial time. 相似文献
35.
The transport of gellan gum microbeads as potential cell carriers was investigated in horizontal columns packed with different grain size classes of gravel (2–16 mm) and sand (0.25–2 mm). A suspension of microbeads was pulsed into each column for 6 h, followed by injection of water for 42 h. In general, the total amount of microbeads travelling across a given section of the column increased with injection time but decreased towards the column outlet, varying as a direct function of grain size. The results of this study demonstrate the feasibility of the transport of gellan gum microbeads through medium sand to medium gravel across distances up to 110 cm. 相似文献
36.
Vapor-liquid equilibrium compositions have been measured for the argon-methane system at 115.2°, 123.4° and 137.1°K, by means of a forced-recirculation apparatus. A modified Redlich-Kwong equation of state with the incorporation of a binary interaction constant has been successfully employed to represent the data. Liquid activity coefficients have been evaluated and correlated. 相似文献
37.
Electrochemical characterization of 8-hydroxyquinoline-5-sulphonate/aluminium(III) aqueous solutions
Denis Badocco Annalisa Dean Valerio Di Marco Paolo Pastore 《Electrochimica acta》2007,52(28):7920-7926
8-Hydroxyquinoline-5-sulphonate/Al(III) aqueous solutions were studied both by potentiometric titrations and voltammetric measurements, in order to obtain the number, the stoichiometry and the stability constants of the complexes formed at equilibrium, and to evaluate the redox and (electro)kinetic properties of the free ligand and of the metal/ligand complexes. The complexes formed in 0.2 m (Na)Cl aqueous solution (stability log beta values ± standard deviation) are AlL+ (8.95 ± 0.05), AlL2− (17.43 ± 0.03) and AlL33− (24.58 ± 0.05), where “L” denotes the free ligand in the completely deprotonated form (L2−, pKa1 = 3.910 ± 0.008, pKa2 = 8.319 ± 0.004). AlL33− is the predominant Al(III) species in a very wide range of pH, metal and ligand concentrations and metal-to-ligand ratios. The free ligand shows an oxidation wave at 0.62 V versus SCE. The proposed oxidation mechanism includes a first reversible one-electron oxidation of the ligand, followed by a coupling reaction and by a second reversible one-electron oxidation, and finally by a decomposition reaction. The addition of Al(III) lowers the intensity of the oxidation wave due to the formation of the redox-inactive complex AlL33−. A residual low signal was attributed to the free ligand produced by the complex dissociation, AlL33− = AlL2− + L2−. All the kinetic parameters involved in the ligand oxidation and in the complex disruption were calculated on the basis of the agreement between experimental and simulated linear sweep and cyclic voltammetries. Correctness of the mechanisms proposed was further confirmed “a posteriori” by the agreement between potentiometric and linear sweep voltammetric results. The low residual signal observed in the presence of fully formed complex was attributed to the free ligand produced by the complex dissociation, having a kinetic constant estimated 0.2 s−1. 相似文献
38.
An efficient, reliable and easily programmed method for solving systems of equilibrium stage separation devices is described. The method is an extension of an algorithm developed by Ishii and Otto(9) for single columns. It solves all equations simultaneously, takes advantage of the basic tridiagonal matrix form form of the linearized steady state equations and can handle configurations which include distillation columns, absorbers and reboiled absorbers. The solution for a thermally coupled distillation system is presented. 相似文献
39.
Multimedia Tools and Applications - The exponential rise in the development of cloud computing environments in the healthcare field, the protection and confidentiality of the medical records become... 相似文献
40.
Tomaschek Fabian Arnold Denis Sering Konstantin Strauss Friedolin 《Language Resources and Evaluation》2021,55(4):1127-1140
Language Resources and Evaluation - This report presents a corpus of articulations recorded with Schlieren photography, a recording technique to visualize aeroflow dynamics for two purposes. First,... 相似文献