Development of blown film linear low-density polyethylene–clay nanocomposites: Part A: Manufacturing process and morphology

In this study, linear low-density polyethylene (LLDPE)/clay nanocomposites with different clay contents were prepared by melt intercalation using two different compatibilizers: maleic anhydride grafted styrene–ethylene–butylene–styrene and maleic anhydride grafted polyethylene (PE-g-MA). Melt intercalation was achieved by twin extrusion and nanocomposite films were produced by blown film extrusion. Effects of clay and compatibilizer fractions and type of compatibilizer on the structure, permeability, and the barrier properties of the nanocomposite films were investigated. PE-g-MA was shown to notably improve the dispersion of clay layers in the polyethylene matrix, and this was examined by atomic force microscopy and X-ray diffraction. The latter tests have also highlighted the importance of the screw configuration: the presence of mixing elements favors the dispersion and distribution of nanoclay. Moreover, differential scanning calorimetry results have shown no significant effect of the clay on the crystallinity of the composite while thermogravimetric analysis tests have demonstrated a decrease of onset and peak of decomposition temperatures. Finally, barrier properties toward water vapor transmission were measured. It was proven that not also clay, but the compatibilizer participated in decreasing the permeability of the film. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48589.     

Self-Propagating High-Temperature Synthesis of Ti3SiC2: Study of the Reaction Mechanisms by Time-Resolved X-Ray Diffraction and Infrared Thermography

Ti₃SiC₂ is synthesized by self-propagating high-temperature synthesis (SHS) of elemental titanium, silicon, and graphite powders. The reaction paths and structure evolution are studied in situ during the SHS of the 3Ti+Si+2C mixture by time-resolved X-ray diffraction coupled with infrared thermography. The proposed reaction mechanism suggests that Ti₃SiC₂ might be formed from Ti–Si liquid phase and solid TiC _x . Finally, the effect of the powders starting composition on the Ti₃SiC₂ synthesis is studied. For the investigated initial mixtures, TiC _x is always formed as a major impurity together with the Ti₃SiC₂ phase.     

A monotone nonlinear finite volume method for approximating diffusion operators on general meshes

The basic principles of the discrete duality and nonlinear monotone finite volume methods are combined in order to obtain a new monotone nonlinear finite volume method for the approximation of diffusion operators on general meshes. Numerical results highlight both the second‐order accuracy of this method on general meshes and its capability to deal with challenging anisotropic diffusion problems on various computational domains. Copyright © 2016 John Wiley & Sons, Ltd.     

Infrared Image Processing to Guide the Identification of Damage and Dissipative Mechanisms in 3D Layer-to-Layer Woven Composites

Applied Composite Materials - This article discusses techniques that aim at facilitating the identification of dissipative mechanisms activated in woven composites under cyclic loadings. The focus...     

Inverse identification of constitutive parameters from heat source fields: A local approach applied to hyperelasticity

In this paper, a new inverse identification method of constitutive parameters is developed from full kinematic and thermal field measurements. It consists in reconstructing the heat source field from two different approaches by using the heat diffusion equation. The first one requires the temperature field measurement and the value of the thermophysical parameters. The second one is based on the kinematic field measurement and the choice of a thermo-hyperelastic model that contains the parameters to be identified. The identification is carried out at the local scale, ie, at any point of the heat source field, without using the boundary conditions. In the present work, the method is applied to the challenging case of hyperelasticity from a heterogeneous test. Due to large deformations undergone by the rubber specimen tested, a motion compensation technique is developed to plot the kinematic and the thermal fields at the same points before reconstructing the heterogeneous heat source field. In the present case, the constitutive parameter of the Neo-Hookean model has been identified, and its distribution has been characterized with respect to the strain state at the surface of a cross-shaped specimen.     

Linear regression-based multifidelity surrogate for disturbance amplification in multiphase explosion

Structural and Multidisciplinary Optimization - When simulations are very expensive and many are required, as for optimization or uncertainty quantification, a way to reduce cost is using...     

Formula One’s new urban economies

The Formula One (F1) industry has become a true microcosm of the world economy, as new business opportunities surface in emerging countries. Until the beginning of the twenty-first century, this sport was mostly relevant to traditional western urban elites, but since then, the F1 calendar has been largely altered to the benefit of ‘dominant-emerging cities’ and to the detriment of more traditional destinations. This article focuses on this urban question through a historical analysis of the F1 circuit’s expansion phases as well as through a study of the current Grand Prix’s estimate sanction fee.     

Model falsification diagnosis and sensor placement for leak detection in pressurized pipe networks

Pressurized pipe networks used for fresh-water distribution can take advantage of recent advances in sensing technologies and data-interpretation to evaluate their performance. In this paper, a leak-detection and a sensor placement methodology are proposed based on leak-scenario falsification. The approach includes modeling and measurement uncertainties during the leak detection process. The performance of the methodology proposed is tested on a full-scale water distribution network using simulated data. Findings indicate that when monitoring the flow velocity for 14 pipes over the entire network (295 pipes) leaks are circumscribed within a few potential locations. The case-study shows that a good detectability is expected for leaks of 50 L/min or more. A study of measurement configurations shows that smaller leak levels could also be detected if additional pipes are instrumented.     

Experimental comparison of classical PID and model-free control: Position control of a shape memory alloy active spring

Shape memory alloys (SMA) are being more frequently integrated into engineering applications. These materials with their shape memory effect enable the simplification of mechanisms and the reduction in size of actuators. SMA parts can easily be activated by Joule effect but their modeling and consequently their control remains difficult. It is principally due to their non-linear hysteretic thermomechanical behavior. Most of successful control strategies applied to SMA actuators are not often suitable for industrial applications: they are particularly heavy and use the Preisach model or neural networks to model the hysteretic behavior of these materials; this kind of model is difficult to identify and to use in real time. This paper deals with an application of the new framework of model-free control (MFC) of an SMA-spring based actuator. This control strategy relies on new results for fast derivative estimation of noisy signals. Their main advantages are: its simplicity and its robustness. Experimental results and comparisons with PI control are presented that demonstrate the efficiency of this new control strategy.