Improving the transfer of near infrared prediction models by orthogonal methods

Eight calibration transfer methods based on the removal of orthogonal signal were compared for the standardization of whole soybean protein and oil models. Dynamic orthogonal projection (DOP), transfer by orthogonal projection (TOP), error removal by orthogonal subtraction (EROS), orthogonal signal correction (OSC), and orthogonal projections to latent structures (O-PLS) as well as the modification and extension of some of these methods were compared in the transfer of models in intra and inter-brand situations using two Foss Infratecs and two Bruins OmegAnalyzerGs. For each brand, a master was designated and its models transferred onto the second unit of its network and the two units of the second brand. Calibration models were transferable from brand to brand with similar or better precision than when each instrument was calibrated on its own calibration set (for Infratec 1229, the relative predictive determinant (RPD) increased in intra and inter-brand calibration transfer situations from 10.42 to 11.45 and 10.57, with DOP and EROS respectively). Performance of each method was different across parameters, instruments, and validation sets. DOP modifications on the determination of the difference matrix showed promising results while TOP and EROS extensions to include variability specifically present in certain crop years did not bring any beneficial effects.     

Gas environment effect on cavitation damage in stretched polyvinylidene fluoride

The influence of gas sorption on damage nucleation of a semicrystalline polymer during coupled diffuso‐mechanical monotonic loading in tension was investigated for the first time. Alpha‐poly(vinylidene fluoride) was mechanically strained under the presence of two chemically different gases, hydrogen and carbon dioxide, at a temperature of 30°C and a pressure up to 120 bar. The cavitation damage at the microstructure scale after gas decompression was assessed from a careful SEM and TEM micrographs analysis. Compared with SEM, TEM allowed quantifying the smallest cavities (ten‐nanometer size). If decompression in hydrogen appeared to have only a slight effect on cavitation however, carbon dioxide showed a detrimental effect on damage nucleation with the exhibition of a significant population of small cavities. On the other hand, tension under gas pressure is more sensitive to hydrogen than to carbon dioxide. Once interaction with gaseous carbon dioxide takes place the plasticizing effect is in competition with damage by cavitation. POLYM. ENG. SCI., 54:2139–2146, 2014. © 2013 Society of Plastics Engineers     

Influence of H2/NH3 mixtures on the composition of SiCNYO and SiCNAl(O) nanopowders

We performed pyrolysis of SiCNAlH and SiCNYOH nanopowder precursors under a reactive atmosphere (Ar/NH₃/H₂) with various compositions of ammonia (NH₃) and dihydrogen (H₂) to diminish C content, which is deleterious for thermal stability and sintering of the powders. This paper continues a previous work on the fabrication of an Si₃N₄/SiC composite without free C by studying the effect of H₂ on the C/N atomic ratio of the powder. We studied the influence of the nature of the gaseous mixture (Ar/NH₃/H₂) on the powder composition. Elemental analysis showed that the introduction of H₂ in the pyrolysis atmosphere limited the decomposition of NH₃ and allowed for control of the C/N ratio. This behaviour can be explained by the structural evolution observed by ²⁹Si NMR spectrometry but also by Fourier transform infrared and Raman spectroscopy. An Si₃N₄/SiC composite, with traces of free C, was obtained after post-pyrolysis heat treatment of the powders synthesized with 10 wt.% of H₂ and 25 wt.% NH₃.     

Antibacterial activity of peptides extracted from tryptic hydrolyzate of whey protein by nanofiltration

Ultrafiltration permeate of whey protein tryptic hydrolyzate was processed by nanofiltration (NF) to obtain retentate (NFR) and permeate (NFP) that were then tested as inhibitors of Listeria, Staphylococcus aureus and Escherichia coli. NFR at 20 mg mL^?1 was most effective as an inhibitor (P < 0.001); whereas E. coli was relatively resistant, the effect on Listeria and S. aureus was greater at 20 mg mL^?1 than at 10 mg mL^?1 (P < 0.01). Peptide analysis revealed that NFR was rich in anionic peptides over eight amino acid residues in length. The antibacterial activity of two anionic peptides (84–91 and 125–135) and a cationic peptide (36–42) derived from β-lactoglobulin was tested. Peptide 125–135 was more inhibitory (P < 0.05) than peptide 84–91 against Listeria monocytogenes and S. aureus; peptide 36–42 was not inhibitory. NFR appears to have potential as a natural bio-preservative.     

Proliferative effects of synthetic peptides from β-lactoglobulin and α-lactalbumin on murine splenocytes

Eleven peptides, selected on the basis of physicochemical characteristics and their theoretical release from β-lactoglobulin (β-Lg) and α-lactalbumin (α-La) by trypsin or chymotrypsin, were chemically synthesised to evaluate their immunomodulating properties. Murine splenocyte proliferation in the absence and presence of mitogen and different peptide concentrations were measured after 72–96 h incubations. β-Lg f78–83 had no effect on proliferation; β-Lg f15–20, f55–60, f84–91, f92–105, f139–148, f142–148 and α-La f10–16 stimulated proliferation to different extents; β-Lg f1–8, f102–105 and α-La f104–108 showed a cytotoxic effect. Regression analysis revealed the relationship of positive charge, hydrophobicity and length to the stimulatory proliferative effect. β-Lg f15–20, f55–60 and f139–148 also induced various inhibiting and/or stimulating effects on cytokine secretion. The results confirm that peptides releasable by digestive enzymes from α-La and β-Lg have the potential to influence the specific immune response through the modulation of splenocyte proliferation and cytokine secretion.     

PEM: The small company-dedicated software process quality evaluation method combining CMMISM and ISO/IEC 14598

Many small software organizations have recognized the need to improve their software product. Evaluating the software product alone seems insufficient since it is known that its quality is largely dependant on the process that is used to create it. Thus, small organizations are asking for evaluation of their software processes and products. The ISO/IEC 14598-5 standard is already used as a methodology basis for evaluating software products. This article explores how it can be combined with the CMMI to produce a methodology that can be tailored for process evaluation in order to improve their software processes. ^SM: CMMI is a service mark of Carnegie-Mellon University. Sylvie Trudel has over 20 years of experience in software. She worked for more than 10 years in development and implementation of management information systems and embedded real-time systems. Since 1996, she works as a process improvement specialist, implementing best practices into organizations processes from CMM and CMMI models. She performed several CMM and CMMI assessments and participated in many other CMM assessments such as CBA IPI, SCE, and other proprietary methods. She obtained a bachelors degree in computer science in 1986 from Laval University in Québec City and a Masters degree in Software Engineering at école de Technologie Supérieure (éTS) in Montréal. Sylvie is currently working as a software engineering advisor at the Centre de Recherche Informatique de Montréal (CRIM). Jean-Marc Lavoie has been working in software development for over 10 years. He performed and published a comparative study between the guide to the SWEBOK and the CMMI in 2003. Jean-Marc obtained a bachelor degree in Electrical Engineering. He is pursuing a Masters degree in Software Engineering at école de Technologie Supérieure (éTS) in Montréal while working as a software architect at Trisotech. Marie-Claude Pare has been working in software development for 7 years. Marie-Claude obtained a bachelor degree in Software Engineering from école Polytechnique in Montréal. She is pursuing a Masters degree in Software Engineering at école de Technologie Supérieure (éTS) in Montréal while working as a software engineer at Motorola GSG Canada. Dr Witold Suryn is a Professor at the école de technologie supérieure, Montreal, Canada (engineering school of the Université du Québec network of institutions) where he teaches graduate and undergraduate software engineering courses and conducts research in the domain of software quality engineering, software engineering body of knowledge and software engineering fundamental principles. Dr Suryn is also the principal researcher and the director of GELOG : IQUAL, the Software Quality Engineering Research Group at école de technologie supérieure. From October 2003 Dr. Suryn holds the position of the International Secretary of ISO/IEC SC7 – System and Software Engineering.