Various factors affecting heavy metal ion sorption from aqueous media by sorbent containing cellulose

The specific adsorption of heavy metal ions on hydrophilic monodentate biosorbent sites was studied. The solvation and coordination mechanism of cation distribution in heterophase system was suggested. Bivalent metal cation desorption mechanism affected by monovalent metal salts (NaCl) was represented in the form of cation-cation resolvation on monodentate sorbent sites, involving ion pairs of hydrated cations and counter ions (anions). The metal ion degree of extraction was found to decrease by 20%, when the solution/sorbent module increased from 75 to 1000. Heavy metal ion sorption by polysaccharide sorbent was identified as exothermic process. The estimated values of ΔH and ΔS enabled to consider sorption of metal cations on polysaccharide sorbent as specific reversible adsorption.     

Modeling of microstructure effects on the mechanical behavior of ultrafine-grained nickels processed by hot isostatic pressing

Bulk ultrafine-grained nickel specimens having grain sizes in the range of 0.25-5 μm were consolidated by hot isostatic pressing technique. The resulting microstructures were characterized by transmission electron microscopy and X-ray diffraction analysis. Compression tests were carried out at room temperature and at strain rate of 1.6×10⁻⁴ s⁻¹. It was found that the measured yield strength does not follow the Hall-Petch law as a consequence of the presence of oxide phase. Therefore, the use of micromechanics based model, which takes into account only the Hall-Petch relationship at grain level for predicting the grain sized effects on mechanical behavior of this kind of materials, is not accurate yet. In this study, a modification made to the generalized self-consistent model was proposed for studying both grain size and oxide phase dependence of ultrafine-grained materials behavior. Because of the novel modification, an optimization procedure with two steps was required to identify the parameters of micromechanical model. An acceptable agreement between experimental and numerical results was achieved. Moreover, the influence of texture on the yield strength and the application of the proposed model to the spark plasma sintering processed materials were also discussed.     

Creep behaviour of a new air-hardenable intermetallic Ti–46Al–8Ta alloy

Creep behaviour of a new cast air-hardenable intermetallic Ti–46Al–8Ta (at.%) alloy was investigated. Constant load tensile creep tests were performed at initial applied stresses ranging from 200 to 400 MPa in the temperature range from 973 to 1073 K. The minimum creep rate is found to depend strongly on the applied stress and temperature. The power law stress exponent of the minimum creep rate is n = 5.8 and the apparent activation energy for creep is calculated to be Q_a = (382.9 ± 14.5) kJ/mol. The kinetics of creep deformation of the specimens tested to a minimum creep rate (creep deformation about 2%) is suggested to be controlled by non-conservative motion of dislocations in the γ(TiAl) matrix. Besides dislocation mechanisms, deformation twinning contributes significantly to overall measured strains in the specimens tested to fracture. The initial γ(TiAl) + α₂(Ti₃Al) microstructure of the creep specimens is unstable and transforms to the γ + α₂ + τ type during creep. The particles of the τ phase are preferentially formed along the grain and lamellar colony boundaries.     

Bulk amorphous Al85Fe15 alloy and Al85Fe15-B composites with amorphous or nanocrystalline-matrix produced by consolidation of mechanically alloyed powders

An Al80Fe14B6 powder mixture was subjected to mechanical alloying. Presence of an amorphous structure in the milling product was revealed by XRD investigations. The calorimetric study showed that the amorphous phase crystallised above 370 °C. The milled Al₈₀Fe₁₄B₆ powder was consolidated under a pressure of 7.7 GPa in different conditions: at 350 °C and at 1000 °C. Besides, the mechanically alloyed amorphous Al₈₅Fe₁₅ powder was consolidated at 360 °C. The amorphous structure was retained after consolidation applied at 350 °C and 360 °C. Compaction at 1000 °C caused crystallisation of the amorphous phase and appearance of metastable nanocrystalline phases. Structural investigations revealed that both bulk Al₈₀Fe₁₄B₆ samples are composites with boron particles embedded in amorphous or nanocrystalline matrix. The hardness of the nanocrystalline-matrix composite and of the amorphous-matrix one is equal to 707 HV1 and 641 HV1 respectively, whereas that of bulk amorphous Al₈₅Fe₁₅ alloy is 504 HV1. The specific yield strength of amorphous-matrix and nanocrystalline-matrix composites, estimated using the Tabor relationship, is 625 and 650 kNm/kg respectively, while that of amorphous Al₈₅Fe₁₅ alloy is 492 kNm/kg. We also suppose that application of high pressure affected crystallisation of amorphous phase, influencing the phase composition of the products of this process.     

Plastic limit of clayey soils and its subjective determination

The subjectiveness of technicians who determine the plastic limit of clayey soils of different grain-size distribution is evaluated. It is demonstrated that subjective determination of characteristics may lead to erroneous classification of soils with respect to type and consistency.     

Mechanical behaviour of fired clay materials subjected to freeze–thaw cycles

The aim of this paper is to study the frost durability of fired clay materials. The behaviour of five fired clay materials with different physical and mechanical properties (porosity, permeability, mechanical strengths and elasticity modulus) subjected to freeze–thaw cycles is analysed. The strains of specimens and the evolution of the main properties with the number of cycles are assessed. The analysis shows that the pore distribution is not the only important parameter but that the tensile strength is also significant. A complete data bank is thus built up to study the effects of the physical and mechanical parameters on frost resistance and to determine how these parameters are affected by frost cycles. It will be possible to use these data to improve the modelling of coupled thermo-hydro-mechanical phenomena involved during the freezing and thawing process in porous media.     

Neural Network–Based Intelligent Compaction Analyzer for Estimating Compaction Quality of Hot Asphalt Mixes

Continuous real-time estimating of compaction quality during the construction of a hot mix asphalt (HMA) pavement is addressed in this paper. The densification of asphalt pavements during construction usually is accomplished by using vibratory compactors. During compaction, the compactor and the asphalt mat form a coupled system whose dynamics are influenced by the changing stiffness of the mat. The measured vibrations of the compactor along with process parameters such as lift thickness, mix type, mix temperature, and compaction pressure can be used to predict the asphalt mat density. Contrary to existing techniques in the literature in which a model is developed to fit experimental data and to predict mat density, a neural network-based approach is adopted that is model-free and uses pattern-recognition techniques to estimate density. The neural network is designed to read the entire frequency spectrum of roller vibrations and to classify these vibrations into different levels. The intelligent asphalt compaction analyzer (IACA) is then trained to convert these vibration levels into a “number” indicative of the asphalt mat density at a given location. This two-step process eliminates the need for regression analysis and produces more accurate density measurements than those reported elsewhere in the literature. Compaction studies of HMA mixes on a stiff subgrade indicate that the changes in the vibration characteristics of the roller are attributable to an increased compaction of the HMA base. The results also show that, with the neural network working as a classifier, the IACA can estimate the density continuously, and in real time, with accuracy levels adequate for quality control in the field.