Trace-metal concentrations in normal human liver: methods to cope with marked variability

Concentrations of trace elements in human tissues characteristically vary widely, and the distributions of most concentrations are skewed to the right. Examination of some of the factors which contribute to the marked variability and skewness of the concentrations revealed that: (1) distributions of concentrations are satisfactorily normal (Gaussian) after logarithmic transformation, (2) ash weight is the best frame of reference in which to report results, (3) the distributions of metal concentrations are not further normalized by adjustments which assume that tissue lipid or collagen contains a fixed fraction of the metal found in the parenchyma, and (4) the choice of sample site within the liver is of minimal significance.     

Job accessibility impacts of intensive and multiple land-use scenarios for the Netherlands’ Randstad Area

This paper examines job accessibility impacts of intensive and multiple land-use scenarios in the Netherlands’ Randstad Area for the period 1996–2030. The scenarios involve a heavy increase in the density and diversity of activities around railway stations. Accessibility impacts are examined using location-based accessibility measures and utility-based accessibility benefit measures within a high-resolution land-use/transport interaction modelling framework, taking into account the regional demand for economic activities and possible market responses. It is concluded that extreme concentrations of economic activities at central urban locations well served by public transport are not to be preferred over less heavy concentrations of economic activities at more locations. Heavy concentrations of new firms may firstly repel existing firms in the neighbourhood and secondly result in decreasing marginal returns of accessibility benefits for public transport users.     

Microanalysis of anionic surfactants in waste water by infrared spectroscopy

Infrared spectroscopy was applied to identify and determine microamounts of anionic surfactants contained in sewage or river waters. The surfactants tested were linear alkylbenzene sulfonate (LAS), branched alkylbenzene sulfonate (ABS), alpha olefine sulfonate (AOS), fatty alcohol sulfate (AS) and fatty alcohol ethoxy sulfate (AES).Anionic surfactants in waters were extracted by chloroform as methylene blue complexes and sulfate type surfactants, i.e. AS and AES were then removed by subsequent hydrolysis. Residual sulfonate type surfactants were first released from methylene blue complexes by ion exchange technique and then changed to sulfonyl chloride derivatives for infrared spectroscopy. Key bands for the identification of sulfonate type surfactants are 640, 618 and 524 cm⁻¹ for LAS, ABS and AOS, respectively. Sulfate type surfactants was calculated from the difference of methylene blue active substance contents before and after hydrolysis.     

Earthquake analysis of isotropic asymmetric multistory buildings

Isotropic multistory buildings are the ones characterized by the property: all load‐resisting planar frames have proportional lateral stiffness matrices. In the present paper it is proved that the modal analysis of an N‐story isotropic asymmetric, torsionally coupled, building (a problem of order 3N) can be separated into two independent sub‐problems: (a) a sub‐problem that corresponds to a single‐story asymmetric, torsionally coupled, building (a problem of order 3); and (b) a sub‐problem that corresponds to an N‐story, torsionally uncoupled, planar frame (a problem of order N). It is also demonstrated that the orientation of peak modal seismic forces of the building is independent of the orientation of seismic excitation, which affects only their size. The separation provides a better insight into the structural behavior of asymmetric multistory buildings under earthquake ground motion. Copyright © 2006 John Wiley & Sons, Ltd.     

Buckling of tube-stiffened prolate domes under external water pressure

The paper describes experimental tests carried out on three tube-stiffened prolate hemi-ellipsoidal domes under external water pressure.The tubes were stuck to the internal surfaces of these three domes, in their flanks, and the experimental tests showed that the tubes increased the buckling pressures of these domes, especially in one case, when the tube was subjected to an initial internal pressure.All three domes failed by lobar buckling, in their flanks, and showed buckling resistances much larger than similar unstiffened domes.     

Prediction of the effectiveness of rolling dynamic compaction using artificial neural networks and cone penetration test data

Rolling Dynamic Compaction(RDC),which is a ground improvement technique involving non-circular modules drawn behind a tractor,has provided the construction industry with an improved ground compaction capability,especially with respect to a greater influence depth and a higher speed of compaction,resulting in increased productivity. However,to date,there is no reliable method to predict the effectiveness of RDC in a range of ground conditions. This paper presents a new and unique predictive tool developed by means of artificial neural networks(ANNs) that permits a priori prediction of density improvement resulting from a range of ground improvement projects that employed 4-sided RDC modules;commercially known as"impact rollers". The strong coefficient of correlation(i.e. R0.86) and the parametric behavior achieved in this study indicate that the model is successful in providing reliable predictions of the effectiveness of RDC in various ground conditions.     

Lead contamination in tap water of households with children in Lower Saxony, Germany

Lead has numerous acute and chronic adverse effects on human beings. This is especially true for infants and children. The main path of lead ingestion in children can be different according to housing and living situation. The intake of lead through drinking water is commonly due to metal corrosion. The users plumbing can be an important factor. In recent years, many lead pipes in Germany have been replaced by pipes made of an alternative material. The aim of this study is to assess the present state of drinking water contamination and the resulting exposure of infants to lead. For this purpose mothers of new-born babies were offered a free examination of their drinking water. After a written declaration of consent had been obtained and after the infant in question had reached an age of 3 months, a stagnation sample of cold tap-water after overnight stagnation together with a random daytime sample was obtained from the family. The collected samples were analysed by atomic absorption spectrometry for their lead concentration. In total, 1485 samples from households were collected. Of the 1434 stagnation samples, 3.1% had lead concentrations greater than 0.01 mg/l (recommended limit of the WHO) and 0.6% had concentrations above the limit of the German drinking water regulation (0.04 mg/l). The values for the 1474 random daytime samples were 2.1% above 0.01 mg/l and 0.2% greater than 0.04 mg/l, respectively. By region, the areas Bovenden, Friedland, Duderstadt, Northeim and Rosdorf were particularly affected. The highest measured concentrations of lead in the stagnation samples were 0.11 mg/l and 0.15 mg/l in the random daytime samples, respectively.     

Energy and environmental comparison of three variants of a family house during its whole life span

The aim of this study is to analyse and compare three variants of a family house in order to evaluate the total environmental impacts produced during the whole building life cycle. The first variant corresponds to the standard in force in Switzerland, the second alternative to the requirements of a quality control label for houses with low energy consumption and the third case is a very low energy consumption building. The three variants have the same architectural aspect but different insulation thicknesses and types, different energy production systems and the use of different renewable energies. The calculation of the environmental impacts is carried out by means of a life cycle analysis, which includes not only the impact related to the energy consumption during the occupancy stage, but also the materials manufacture, transport, replacement and elimination at the end of the building lifetime. The results are expressed with the Swiss and the UCTE (Union for the Co-ordination of Transmission of Electricity) electricity mix to analyse how they influence the building impact.     

Interaction of bacteriophage R17 and reovirus type III with the clay mineral allophane

A study has been made of the adsorption of bacteriophage R17 and reovirus type 3 by the amorphous aluminosilicate clay mineral allophane. In agreement with previous studies of virus adsorption to other minerals such as montmorillonite and aluminium hydroxide, the principal factors influencing adsorption were found to be mixing time, pH and the concentrations and isoelectric points of both the virus and the absorbent. However, allophane was found to be a much better adsorbent for reovirus and R17 over the pH range 5–7, the natural pH range of many fresh waters.By using highly purified radioactive reovirus it was possible to follow both the distribution of radioactive virus in a clay suspension and the specific infectivity of the virus. This study revealed that when adsorbed virus was eluted by neutral phosphate solutions it retained its physical integrity but was of a lower specific infectivity.