The direct measurement of ppm levels of uranium in soils using high-resolution Ge(Li) gamma-ray spectroscopy

The direct determination of ²³⁸U in various soil samples was done by measuring the 63.3-keV transition from the decay of the first daughter ²³⁴Th. Potential errors resulting from the chemical non-equilibrium of ²³⁸U with its daughters are thus avoided. The method sensitivity is 1 ppm compared to the 35 ppm obtainable by employing the 1001-keV gamma ray. A Ge(Li) gamma-ray spectrometer is the only analytical tool required. Examples are offered that demonstrate the usefulness of the technique for routine, inexpensive environmental monitoring of uranium. The technique also has the capability of providing information on the ²³⁸U/²³⁵U isotopic ratio.     

Dynamic modelling and control applications in water quality maintenance

The purpose of this paper is to develop and illustrate a unified, systematic approach to problems of water quality management. In order to achieve this a water quality system is defined as the following group of component features: the abstraction, purification, and supply of potable water from a river: consumer effluent, rainfall-runoff from an urban land surface, and the sewer network; the wastewater treatment plant: the river itself. A systems analysis approach to the study of the dynamic and control aspects of the system is discussed, with particular reference to the practical limitations of instrumentation and technology. In an attempt to blend the theory with the practice recent studies on the dynamic modelling and control of parts of the water quality system are reviewed. Special attention is paid to the practical application of techniques of system identification and parameter estimation. Finally, piecing together several individual results, it is possible to give a good indication of the manner in which control studies should be directed in the near future.     

Contamination bacterienne d'une zone balneaire liee a sa frequentation

The bacterial contamination from bathers in the water and sand at a beach was investigated. Measurements were made of the composition of the cutaneous bacterial flora released by two bathers as well as the sensitivity of the main contaminants to solar radiation. The variations in bacterial concentration of the sea water and sand were determined at the sea shore over three complete day cycles. Broadly speaking, the concentration of some bacteria increases with the frequency with which the beach is used. Nevertheless, short-period variations seem to be masked by the opposing effects of solar radiation and bathers.     

Effects of adding organic materials to an acid sulfate soil on the growth of cocoa (Theobroma cacao L.) seedlings

Acid sulfate soils having a pH of less than 3.5 are widespread in Malaysia. Some of these soils are planted to cocoa, but the yield is reported to be low due to soil infertility related to Al toxicity. Cocoa growth is sensitive to the presence of Al in the soil. To a certain extent, Al toxicity in soils can be reduced by organic matter application and to a greater extent in iron-poor acid sulfate soil. A study was conducted to determine the efficacy of various types of organic materials easily available in the country to ameliorate acid sulfate soil infertility for growing cocoa seedlings. The treatments were control (nil), lime (3 t/ha), peat (10% w/w), peat plus green manure (10% w/w), peat plus rice straw (10% w/w), peat plus chicken dung (10% w/w) and peat plus POMS (Palm oil mill sludge) (10% w/w). The growth of cocoa seedlings was affected significantly by the presence of Al in the cocoa tissues. As the amount of Al in the leaves increased, the relative top dry weight of cocoa seedlings decreased. Likewise, the relative plant height was negatively correlated with Al in the leaves. Peat as well as peat in combination with green manure, rice straw, chicken dung or palm oil mill sludge was able to reduce Al toxicity in acid sulfate soil; the highest top dry weight of cocoa seedlings were obtained in the peat plus green manure treatment. The best cocoa seedlings root growth was found for the peat treatment alone. The relative top dry weight of cocoa seedlings was negatively correlated with Al(3+) as well as Al(3+)+Al(OH)(2+)+Al(OH)(2)(+) activity in the soil solution. The critical values for Al(3+) and the combination of Al(3+)+Al(OH)(2+)+Al(OH)(2)(+) activity in the soil solution were 10 microM and 15 microM, respectively.     

Noise impact caused by electrical energy substations in the city of Curitiba, Brazil

This survey is intended to characterize the noise impact due to electrical energy substations in the city of Curitiba over the population living in their vicinity. This impact has been studied with the aid of a computational tool capable of mapping the acoustical field of substations and their vicinity. Several factors have been considered in this survey: (1) sound power of the transformers; (2) vehicle flow on the surrounding roads; (3) positioning of the firewalls, buildings and walls; and (4) terrain topography. Four substations have been analyzed, and an acoustical map has been traced for each of them. With these maps it was possible to visualize what was the incident noise level on the building facades. The predicted noise levels have been compared to the environmental legislation of the noise emissions in effect in the city.     

The collapse of welded aluminium plate girders—an experimental study

Twenty-two tests conducted to study the collapse behaviour of welded aluminium girders are described. The girders are of varying proportions, have transverse or longitudinal web stiffeners and are subjected to different combinations of shear and bending loads. It is observed that, although shear sway mechanisms similar to those for steel girders do develop, the webs of aluminium girders may fracture in the heat affected zones adjacent to the perimeter welds. These fractures develop at some stage during the formation of the collapse mechanism and are the consequence, rather than the cause, of failure. It is shown that the tension field theory, originally developed for steel girders, may overestimate the shear-carrying capacity of aluminium girders and it is concluded that the theory requires some modification before it can be applied with confidence to aluminium girders.     

Endogenising demand for information in road transport

In this paper, the impact of endogenous information provision to drivers in road transport is investigated. A static economic equilibrium model is used, which allows potential road users to buy information on the prevailing (stochastic) traffic situation. It takes for granted that an individual will try to acquire proper information when the private benefits of doing so exceed the private costs. By using an information model for road users, the interesting result is found that the provision of endogenous information leads to a strict Pareto improvement. Furthermore, the model shows that — depending on the price of information — it can be efficiency improving to subsidise or tax the motorist information to the user. Finally, there is a relationship between fine congestion pricing and subsidising motorist information. It turns out that the social welfare maximising subsidy under first-best congestion pricing is equal to zero. However, subsidising information may be an attractive policy instrument when a flat congestion pricing scheme is preferred.Participates in the VSB-fonds sponsored research project Transport and Environment     

Central place theory and intercommunity input-output analysis

This paper explores trade hierarchies and interindustry relationships, first in theory, then in the empirical context of a western United States timber economy facing a large reduction in its timber harvest. Principles of central place theory guide construction of a hybrid intercommunity input-output model. A nonsurvey technique for estimating central place trade is developed, and is compared with MRIO methods. The effect of central place dominance on intercommunity multipliers is examined theoretically, as is the nature of feedback linkages in a central place hierarchy. The empirical magnitude of feedback effects is small, and although effects vary in magnitude from community to community, neglect of central place considerations can understate intercommunity sawmill multipliers by as much as 36 percent.     

Sulfolane biodegradation potential in aquifer sediments at sour natural gas plant sites

Sulfolane is used in the treatment of sour natural gas. It is a highly water soluble compound that has been introduced into soils and groundwaters at a number of sour gas processing plant sites. Aquifer sediments from contaminated locations at three sites in western Canada were assessed for microbial activity and their ability to degrade sulfolane under aerobic and five anaerobic (nitrate-, Mn(IV)-, Fe(III)-, sulfate- and CO₂-reducing) conditions. The microcosms were supplemented with 200 mg/L sulfolane and adequate supplies of N, P, and the appropriate terminal electron acceptor. Microcosms containing contaminated aquifer sediments from each of the three sites were able to degrade sulfolane aerobically at 8°C and 28°C, and the biodegradation followed zero-order kinetics. The lag times before the onset of sulfolane biodegradation were shorter when sulfolane-contaminated sediments were used as inocula than when uncontaminated soils were used. No anaerobic sulfolane biodegradation was observed at 28°C, nor was sulfolane biodegradation observed at 8°C under Fe(III)-, sulfate- and CO₂-reducing conditions. At 8°C, anaerobic degradation of sulfolane coupled to Mn(IV) reduction was observed in microcosms from two sites, and degradation coupled to nitrate reduction was seen in a microcosm from one of the contaminated sites.