The manual determination of ammonia in fresh waters using an ammonia-sensitive membrane-electrode

The use of a commercially-available ammonia-sensitive membrane-electrode for the manual determination of ammonia in discrete samples of fresh water has been investigated and the analytical procedure is described. The electrode is simple and convenient to use, and a sample can be analyzed in a few minutes. For normal routine analysis, the lower limit of determination is approximately 0·1 mg N 1⁻¹ though smaller concentrations can be measured. The relative standard deviation of analytical results varied from approximately 10 to 3 per cent as ammonia concentration increased from 0·1 to 4 mg N 1⁻¹. Results for samples of river water agreed well with those obtained by absorptiometric methods of analysis; the electrode responds to amines but otherwise appears to be essentially specific for ammonia. Use of the electrode will be advantageous in a number of applications, and it also has good potential for the on-line analysis of fresh waters.     

Evolution of pH, organic matter and (226)radium/calcium partitioning in U-mining debris following revegetation with pine trees

Natural attenuation processes resulting from the afforestation of some U-waste rock piles have the potential to limit the linkage of radioelements and other trace pollutants, thereby minimizing exposure risks. We determined the evolution of pH and organic matter and compared the (226)Ra and Ca extractability in pyrite-containing mining debris which was revegetated 35 years ago with Scots pine. Oxidation of sulphidic minerals remaining in the substrate appeared to dominate over acidification processes due to vegetation inputs and litter decomposition. The accumulation of organic matter in forest floor had a negligible effect on the (226)Ra upward recycling compared to the migration losses observed mainly from decarbonatation of the surface mining debris. (226)Ra was overall less soluble than Ca in the soil profile but NH(4)Ac-pH 5 had the capacity to extract a (226)Ra fraction of 31.1-41.5%, i.e. at least twice as much as for Ca. In deeper layers, a majority of both Ca and (226)Ra were extractable from the same non-specific adsorption pool, which mainly involved carbonate. In the upper acidified layer, the incorporation of organic matter had no effect on (226)Ra extractability. A further specific adsorption pool for (226)Ra was attributed to the formation of sparingly soluble Fe-Al oxyhydroxides. However, that specific (226)Ra-bearing phase was readily dissolved in NH(4)Ac-pH 5, indicating a relatively reversibility of the precipitation reaction of (226)Ra with amorphous oxide. Trees are effective at reducing hydrological release of many pollutants but in the mining debris studied, four decades of pine growth did not significantly promote (226)Ra remediation in the soil.     

Locating underground cavities by means of radio waves

Conclusions Experiments have shown that radio waves may be used with economical efficiency to find and outline ancient mine workings. The device developed at the Artem Dnepropetrovsk Mining Institute is highly interference-free, stable, and reliable. It has been shown that the use of this method in combination with other methods of exploration, such as drilling, permits us to increase appreciably the accuracy and reliability of geologic exploration.Dnepropetrovsk. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 2, pp. 14–16, March–April, 1973.     

Elastoplastic finite-element analysis of the bearing capacity of beds of reconstructed entities

A method is presented for determination of the coefficients that take into account the increase in angle of internal friction and specific cohesion of silty-clayey soils in predicting variation in the bearing capacity of beds after the long-term effect of the consolidating service-induced loads. __________ Translated From Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 2, Pp. 18–21, March–April, 2007.     

A novel application of TPAD-MBR system to the pilot treatment of chemical synthesis-based pharmaceutical wastewater

A pilot-scale test was conducted with a two-phase anaerobic digestion (TPAD) system and a subsequential membrane bioreactor (MBR) treating chemical synthesis-based pharmaceutical wastewater. The TPAD system comprised a continuous stirred tank reactor (CSTR) and an upflow anaerobic sludge blanket-anaerobic filter (UASBAF), working as the acidogenic and methanogenic phases, respectively. The wastewater was high in COD, varying daily between 5789 and 58,792 mg L(-1), with a wide range of pH from 4.3 to 7.2. The wastewater was pumped at a fixed flow rate of 1m(3)h(-1) through the CSTR, the UASBAF and the MBR in series, resulting in respective HRTs of 12, 55 and 5h. Almost all the COD was removed by the TPAD-MBR system, leaving a COD of around 40 mg L(-1) in the MBR effluent. The pH of the MBR effluent was found in a narrow range of 6.8-7.6, indicating that the MBR effluent can be directly discharged into natural waters. A model, built on the back propagation neural network (BPNN) theory and linear regression techniques, was developed for the simulation of TPAD-MBR system performance in the biodegradation of chemical synthesis-based pharmaceutical wastewater. The model well fitted the laboratory data, and was able to simulate the removal of COD.     

Stochastic Simulation of Construction Bidding and Project Management

Abstract: A stochastic simulation model of a project management game was developed to assist in training estimators in developing bidding strategies in construction. This paper discusses the development of the conceptual gaming model for bidding on construction projects and the implementation of the model on portable software. The model simulates the actual bidding in construction by creating projects, initiating random phenomena, and keeping track of the performance of the individual players of the game. Upon conclusion of the game the winner is selected as the player that maximizes his relative return on the original investment assigned to him by the game. The paper describes the underlying construction management concepts and the bidding process in general. The database management model is then detailed focusing on the requirements and strategy behind the development of the various databases. The paper also describes the various models utilized in simulating the involved random processes. Finally the operation of the program is introduced and its use in educating construction engineers and managers is highlighted.     

Structural reliability software at the University of California, Berkeley

The paper provides an overview of three software for structural reliability analysis developed at the University of California, Berkeley. These are CalREL, which is a general-purpose structural reliability code written in FORTRAN; FERUM, which is a collection of Matlab^® files that can be used for structural reliability analysis in conjunction with simple finite element models; and OpenSees, which is an object-oriented code for nonlinear structural response simulation with reliability capabilities. Reliability analysis methods featured by these software include FORM, SORM, Monte Carlo simulation, and various importance sampling methods. In addition, variable importance and sensitivity measures are provided.     

Environmental exposure to lead and its correlation with biochemical indices in children

Lead is a global concern because of its ubiquity in the environment and known to be associated with abnormal neurobehavioral and cognitive development of young children. There is no study from India to describe a composite profile of blood lead and its biochemical influences in children. The present study was aimed at determining the proportion of children with >10 mug/dL blood lead levels (BLLs), association between BLLs, and sociodemographic characteristics, if any, and alterations in biochemical indices in the blood as an underlying mechanism of lead intoxication. A total of 62 children (4--12 y) of Lucknow and nearby areas were recruited to determine BLLs, delta-amimolevulinic acid dehydratase (delta-ALAD) activity, catalase (CAT) activity, and malondialdehyde (MDA) and glutathione (GSH) levels in the blood. Mean level of blood lead was 7.47+/-3.06 microg/dL (2.78--15.0) and 29%-exceeded 10 microg/dL, CDC intervention level. The BLLs were found to be significantly influenced by social status, area of residence, source of water supply, maternal educational status (p<0.001), type of house, and proximity to traffic density (p<0.01). delta-ALAD was significantly lower in the group of children with BLLs 11.39+/-1.39 microg/dL when compared to children with BLLs 7.11+/-1.25 microg/dL and 3.93+/-0.61 microg/dL (p=0.0007, 0.0005, respectively). However, CAT activity was higher in the groups of children with higher blood levels than with lower BLLs (p=0.0159, 0.0001, respectively). There was an increase in MDA level with a concomitant decrease of GSH in children with BLLs 11.39+/-1.39 microg/dL compared with those of children with BLLs 7.11+/-1.25 microg/dL and 3.93+/-0.61 microg/dL (p=0.0001, 0.0002, and p=0.0001, respectively). There was statistically significant correlation of BLLs with delta-ALAD (r=-0.44, p=0.00035), MDA (r=0.46, p=0.00018), GSH (r=-0.62, p=0.00001), and CAT (r=0.44, p=0.00035). Significantly, CAT activity, MDA, and GSH levels were in turn, found to be correlated with delta-ALAD (r=-0.45, p=0.00024; r=-0.43, p=0.00053; r=0.43, p=0.00053, respectively). Results of the present study indicate a declining trend of BLLs in children when compared with those reported from metropolitan cities of India when leaded gasoline was in practice and that the BLLs were significantly associated with biochemical indices in the blood which have the potential to be used as biomarkers of lead intoxication.     

The characterisation of friction stir welding process effects on stiffened panel buckling performance

The introduction of advanced welding methods as an alternative joining process to riveting in the manufacture of primary aircraft structure has the potential to realise reductions in both manufacturing costs and structural weight. However, welding processes can introduce undesirable residual stresses and distortions in the final fabricated components, as well as localised loss of mechanical properties at the weld joints. The aim of this research is to determine and characterise the key process effects of friction stir welding assembly methods on stiffened panel static strength performance. Utilising experimentally validated finite element modelling methods, it is demonstrated that welding induced residual stresses have a significant influence, and that collapse behaviour is less sensitive to advanced process effects and process effect magnitudes than panel initial buckling behaviour.     

Haloacetic acids and trihalomethanes in finished drinking waters from heterogeneous sources

Trihalomethanes (THM) and haloacetic acids (HAA) are the most frequent chlorination by-products (CBP) in finished drinking waters. Traditionally, THM have been used as surrogates for CBP although the quantitative association between THM and other CBP is not well established. This problem is addressed in the present study from the analysis of THM and HAA in drinking water samples from four Spanish regions, representing areas with very different CBP composition, e.g. between 86 and 8.0 microg/l of THM and 50-3.0 microg/l of HAA.The resulting dataset exhibit a statistically significant correlation between total THM and HAA (Pearson's correlation coefficient, r(p)=0.815,p<0.0005). Furthermore, specific HAA are highly correlated with specific THM or their combinations. Accordingly, multivariate linear regression analysis of the concentrations observed show that the levels in total and specific HAA can be predicted from the THM content. These results are relevant for epidemiological studies on health effects from CBP exposure since they usually involve comparison of populations consuming waters of very distinct quality.