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21.
本文在[1]的基础上,详尽地得到了Boussinesq方程和KdV方程的孤立波解,并对波高和波形进行了细致的分析。为了更好地比较,本文还给出了高阶摄动的孤立波解。 相似文献
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A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution 1H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry 相似文献
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以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点. 相似文献
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大直径近水平长钻孔瓦斯抽采全液压坑道钻机的研制 总被引:1,自引:0,他引:1
用大直径长钻孔进行瓦斯抽采是近几年一直受到广泛关注的技术,我国大部分煤矿矿井巷道条件一般、地层条件较复杂,以大扭矩孔口回转钻进方式为主的瓦斯钻机仍会是大直径长钻孔瓦斯抽采钻机的主导机型。文章介绍了大直径长钻孔施工常用的几种全液压坑道钻机的结构和性能特点。以期为我国煤矿推广应用大直径长钻孔瓦斯抽采提供技术保障,同时促进我国煤矿坑道钻探水平的进步。 相似文献
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Dielectric anisotropy phenomenon of coal was detectable by many dielectric measurements. The paper presented that it was attributed to coal interior moisture distribution. A new model describing interior moisture distribution was developed basing on microstructure observation of coal. In the model, coal interior moisture distribution was analyzed and simulated numerically, the relationship between interior moisture distribution and coal dielectric property was constructed, the character of the permittivity varying with moisture content had also been studied and coal dielectric anisotropy was deduced. Corresponding experiment results were well satisfied with the model analysis, demonstrating that the interior moisture content could cause coal dielectric anisotropy. 相似文献
28.
Xin Song Xiaoyu Qi Bin Hao Yinbo Qu 《European Journal of Lipid Science and Technology》2008,110(12):1095-1101
Although lipases are widely applied in a wide variety of reactions, available information on the factors that are responsible for the substrate specificities of lipases from different sources is scarce. In this paper, nine lipase‐producing microorganism strains were isolated from oil‐containing samples. The properties of these enzymes, including pH optima, temperature optima, thermal stability, and pH stability, vary significantly with the different sources from which these lipases were isolated. The substrate specificities of the nine lipases, including fatty acid and positional specificities, were also studied. The fatty acid specificities of the nine lipases were observably different toward 15 substrates with different carbon chain lengths, different saturation degrees and different side chains. The lipases from S3 Penicillium citrinum (PCL), MJ1 Aspergillus niger (ANL), MJ2 Aspergillus oryzae (AOL), YM Bacillus coughing (BCL), S9 Geotrichum candidum (GCL), and S11 Candida lypolytica (CLL) showed the strongest specificities to short‐chain esters, and the other lipases showed strong selectivity for medium‐ or long‐chain and branched esters. The positional specificities were examined by analyzing the hydrolytic products of triolein catalyzed by the nine lipases, using TLC. The lipases can be mainly classified into two groups by their specificities for the ester bond at position 2 of triglycerides; one group can selectively hydrolyze the ester bond at position 2 of the triglycerides, the other group cannot. All these nine lipases were divided into four groups by hierarchical clustering analysis on the basis of the results of fatty acid and positional specificities. 相似文献
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