Hollow Pd/MOF Nanosphere with Double Shells as Multifunctional Catalyst for Hydrogenation Reaction

A new type of hollow nanostructure featured double metal‐organic frameworks shells with metal nanoparticles (MNPs) is designed and fabricated by the methods of ship in a bottle and bottle around the ship. The nanostructure material, hereinafter denoted as Void@HKUST‐1/Pd@ZIF‐8, is confirmed by the analyses of photograph, transmission electron microscopy, scanning electron microscopy, powder X‐ray diffraction, inductively coupled plasma, and N₂ sorption. It possesses various multifunctionally structural characteristics such as hollow cavity which can improve mass transfer, the adjacent of the inner HKUST‐1 shell to the void which enables the matrix of the shell to host and well disperse MNPs, and an outer ZIF‐8 shell which acts as protective layer against the leaching of MNPs and a sieve to guarantee molecular‐size selectivity. This makes the material eligible candidates for the heterogeneous catalyst. As a proof of concept, the liquid‐phase hydrogenation of olefins with different molecular sizes as a model reaction is employed. It demonstrates the efficient catalytic activity and size‐selectivity of Void@HKUST‐1/Pd@ZIF‐8.     

基于Fluent的圆柱齿轮流量计的密封性仿真分析

通过对圆柱齿轮流量计进行二维简化建模,用Fluent仿真软件的ICEM CFD模块进行网格划分,利用Fluent仿真软件对圆柱齿轮流量计进行了计算和密封性的仿真分析,得出了其速度矢量分布图,并且给出了各泄漏量的计算公式和每种泄漏所占泄漏总量的百分比,即为以后的整个流量计的设计提供理论依据。,提高流量计的寿命具有重要意义。同时还省去了大量的人工计算过程,极大地加快了计算速度。     

Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions

The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction.     

SFC编程方法在煤矿带式输送机监控系统中的应用

针对煤矿带式输送机监控系统中的PLC程序因采用经验法设计而存在编写周期长、可读性差、程序维护困难等问题,提出了一种采用SFC编程方法设计煤矿带式输送机监控系统梯形图的方案。实践表明,该方案具有设计方便、可读性好、维护简单等特点。     

Approximate dynamic programming solutions with a single network adaptive critic for a class of nonlinear systems

Approximate dynamic programming (ADP) formulation implemented with an adaptive critic (AC)-based neural network (NN) structure has evolved as a powerful technique for solving the Hamilton-Jacobi-Bellman (HJB) equations. As interest in ADP and the AC solutions are escalating with time, there is a dire need to consider possible enabling factors for their implementations. A typical AC structure consists of two interacting NNs, which is computationally expensive. In this paper, a new architecture, called the ‘cost-function-based single network adaptive critic (J-SNAC)’ is presented, which eliminates one of the networks in a typical AC structure. This approach is applicable to a wide class of nonlinear systems in engineering. In order to demonstrate the benefits and the control synthesis with the J-SNAC, two problems have been solved with the AC and the J-SNAC approaches. Results are presented, which show savings of about 50% of the computational costs by J-SNAC while having the same accuracy levels of the dual network structure in solving for optimal control. Furthermore, convergence of the J-SNAC iterations, which reduces to a least-squares problem, is discussed; for linear systems, the iterative process is shown to reduce to solving the familiar algebraic Ricatti equation.     

Adaptive control for a class of nonlinear systems with time-varying delays in state and input

This paper is concerned with the adaptive stabilization problem of uncertain input delayed systems.A solution to this problem is given for a class of uncertain nonlinear systems with time-varying delays in both state and input.An adaptive asymptotically stabilizing controller,which can guarantee the stability of the closed-loop system and the convergence of the original system state,is designed by means of the Lyapunov-Krasovskii functional stability theory combined with linear matrix inequalities (LMIs) an...     

WCDMA直放站数字下变频的FPGA实现

数字下变频器（Digital Down Converter,DDC）是WCDMA直放站的重要组成部分,它将高速采样的数字中频信号下变频到基带,然后进行抽取,低通滤波。重点研究了数字下变频器的数控振荡器NCO和半带滤波器的原理和硬件设计仿真,通过FPGA芯片Virtex-6 XC6VLX75T设计实现了适用于WCDMA直放站的数字下变频器,并对其进行硬件仿真与验证。