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491.
Pressurized planar electrochromatography (PPEC) is the mode which offers much higher separation efficiency in comparison to conventional planar chromatography, including both higher performance and much higher speed of separation. In this paper, we present a new device for performing PPEC in which the whole area of the chromatographic plate is pressurized. Both electrodes (anode and cathode) are washed with the mobile phase during the experiment, which prevents gas bubbles from collection in the region of the electrodes. This device enables directly controlling the flow rate of the mobile phase during the electrochromatography process. Mobile phase control offers the possibility of researching the influence of various properties of the PPEC system on separation efficiency. One important relationship to investigate is plate height vs mobile phase flow rate. This relationship helps to choose the optimal value of the mobile phase flow rate during the separation process. Considerable difference in shape of this relationship is demonstrated for conventional planar chromatography plates and high performance planar chromatography plates. Examples of the influence of some properties of the separating system on flow rate of the mobile phase are demonstrated, such as the buffer concentration in the mobile phase, the pH value of the buffer solution of the mobile phase, the type of chromatographic plate, and the voltage applied to the electrodes. 相似文献
492.
Stern E Jay S Bertram J Boese B Kretzschmar I Turner-Evans D Dietz C LaVan DA Malinski T Fahmy T Reed MA 《Analytical chemistry》2006,78(18):6340-6346
A critical shortcoming of current surface functionalization schemes is their inability to selectively coat patterned substrates at micrometer and nanometer scales. This limitation prevents localized deposition of macromolecules at high densities, thereby restricting the versatility of the surface. A new approach for functionalizing lithographically patterned substrates that eliminates the need for alignment and, thus, is scalable to any dimension is reported. We show, for the first time, that electropolymerization of derivatized phenols can functionalize patterned surfaces with amine, aldehyde, and carboxylic acid groups and demonstrate that these derivatized groups can covalently bind molecular targets, including proteins and DNA. With this approach, electrically conducting and semiconducting materials in any lithographically realizable geometry can be selectively functionalized, allowing for the sequential deposition of a myriad of chemical or biochemical species of interest at high density to a surface with minimal cross-contamination. 相似文献
493.
On the Preparation of Isocyanatoderivatives of Aliphatic Diethers A method for the preparation of some isocyanates of aliphatic diethers of the general formula: CH3(NCO) O [CH2]n O CH(NCO)CH3 2a – e , where n = 1–5 has been reported. The syntheses conditions, properties, as well as the conversion of the obtained diisocyanates into the new urea derivatives were described. 相似文献
494.
Stepinski T 《IEEE transactions on ultrasonics, ferroelectrics, and frequency control》2007,54(7):1399-1408
A new implementation of a synthetic aperture focusing technique (SAFT) based on concepts used in synthetic aperture radar and sonar is presented in the paper. The algorithm, based on the convolution model of the imaging system developed in frequency domain, accounts for the beam pattern of the finite-sized transducer used in the synthetic aperture. The 2D fast Fourier transform (FFT) is used for the calculation of a 2D spectrum of the ultrasonic data. The spectrum is then interpolated to convert the polar coordinate system used for the acquisition of ultrasonic signals to the rectangular coordinates used for the presentation of imaging results. After compensating the transducer lobe amplitude profile using a Wiener filter, the transformed spectrum is subjected to the 2D inverse Fourier transform to get the time-domain image again. The algorithm is computationally attractive due to the use of 2D FFT. The performance of the proposed frequency-domain algorithm and the classical time-domain SAFT are compared in the paper using simulated and real ultrasonic data. 相似文献
495.
Tadeusz Banek 《Systems & Control Letters》1986,8(2)
Two filtering problems for Brownian motions with absorbing and reflecting barriers are examined and shown to reduce to two classical boundary value problems (BVPs). It turns out that the solution of the first one is basically the same as those obtained by Bene
[2] for the ‘3-dimensional’ Bessel process. The presence,of a reflecting barrier manifests itself via an appropriate boundary. condition and some additional term in the PDE. Two different formulas solving the second BVP are obtained. 相似文献
496.
Indices of relative crystallinity of starch samples after gamma irradiation in dry form or in potatoes have been determined by differential and integral methods and compared with those calculated for corresponding reference samples. In the case of dry samples, the diminution of relative crystallinity was observed after gamma ray irradiation. In the case of starch samples extracted from irradiated potatoes, the influence of drying conditions was additionally observed. The diminution of relative crystallinity seems to be accompanied by destruction of long-range ordering as observed by SAXS experiment. 相似文献
497.
498.
Tadeusz Balcerowski Burak Ozbek Ozge Akbulut Ahu Gümrah Dumanli 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(8):2205506
Structural color—a widespread phenomenon observed throughout nature is caused by light interference from ordered phases of matter. While state-of-the-art nanofabrication techniques can produce structural organization in small areas, cost-effective and scalable techniques are still lacking to generate tunable color at sub-micron length scales. In this work, structurally colored hydroxypropyl cellulose filaments are produced with a suppressed angular color response by 3D printing. The systematic study of the morphology of the filaments reveals the key stages in the induction of a two-degree hierarchical order through 3D printing. The first degree of order originated from the changing of the cholesteric pitch at a few hundred nm scale via chemical modification and tuning of the solid content of the lyotropic phase. Upon 3D printing, the secondary hierarchical order of periodic wrinkling is introduced through the Helfrich–Hurault deformation of the shear-aligned cholesteric phases. In single-layered filaments, four morphological zones with varying orders of wrinkles are identified. Detailed morphological characterization is carried out using SEM to shed light on the mechanism of the wrinkling behavior. Through this work, the possibility of modifying the wrinkling behavior is demonstrated and thus the angle dependence of the color response by changing the printing conditions. 相似文献
499.