Intercalation on Transition Metal Trichalcogenides via a Quasi-Amorphous Phase with 1D Order

Intercalation into 1D transition metal trichalcogenides (TMTs) in which fibers are bonded by a weak van der Waals force can be expected to create various intercalation compounds and develop unique physical properties according to the combination of the host materials and guest ions. However, structural changes via intercalation into 1D TMTs are not as simple as those in 2D transition metal dichalcogenides (TMDs) and are still not understood comprehensively. ZrTe₃: a typical compound with a 1D trigonal prismatic structure, belongs to TMTs. Herein, through the Ag introduction to ZrTe₃ via solid-state intercalation, a novel crystal phase with a 1D octahedral structure and a quasi-amorphous (QA) phase during the structural transition are discovered; the QA phase is a novel state of matter in which long-range order is lost while retaining 1D order. Based on the Ag concentration, the transport properties are flexibly modulated from superconductivity to semiconductivity. Density functional theory calculations indicate the attraction between Ag ions and the pair diffusion due to their attraction. Furthermore, judging the attraction or repulsion between guest ions predicts whether to induce a QA phase or simple lattice expansion like the intercalation into 2D TMDs.     

Friction dynamics of human hair treated with water or cationic surfactant aqueous solution

Cationic surfactants are adsorbed on the surface of human hair and exhibit a lubricating effect. Here, we evaluated the friction when the hair treated with water or 1 wt% cationic surfactant (cetyltrimethylammonium bromide) aqueous solution was rubbed by a contact probe equipped in a sinusoidal motion friction evaluation system. Because of the rough structure of the cuticle on the human hair surface, an oscillatory phenomenon with a frequency of 50–70 Hz was observed when untreated hair was rubbed with a contact probe. On the other hand, the oscillatory phenomenon was not observed when the hair contained a large amount of water because stick–slip phenomena were inhibited on the soft, swollen hair surface. Furthermore, the change in kinetic friction coefficient and delay time, which is a normalized value of the time difference between the reaction of the friction force to accelerated motion, from untreated hair, Δμ_k and Δδ, was almost zero. However, we found a large difference in Δμ_k and Δδ for the hair treated with cationic surfactant aqueous solution. The treatment with cationic surfactant reduced both friction parameters, Δμ_k and Δδ, indicating that the treatment induced not only the frictional force but also the profile at the beginning of frictional sliding. The significant lubrication is due to cationic surfactant adsorption on the hair surface. These data imply that the smoothness of hair treated with a cationic surfactant is related to a reduction in friction coefficient and delay time δ.     

Sediment penetration performance of a portable underwater robot for core sampling

As described in this paper, we investigate the sediment penetration performance of a portable underwater robot with a helical screw pipe using marine thrusters with limited force. First, we derive a mathematical model based on an empirical and simple method using the undrained shear strength of cohesive soil to provide a rough estimate of maximum penetration depths. Then, we perform numerical analysis for estimating the maximum depth of sediment penetration and for designing a sampling pipe. Additionally, we use experimentation to investigate the relation between the penetration depth of the helical screw pipe and the force of marine thrusters mounted on the portable underwater robot. After testing the penetration performance in a water tank, we conduct a field experiment at Lake Biwa and obtain results of the penetration depths. The maximum penetration into the lake sediment is at least 0.30 m. The results demonstrated the possibility of using the derived mathematical model to make a rough estimation of the maximum penetration depth for clay sediments. Additionally, we can use non-powerful thrusters equipped with small autonomous underwater vehicles (AUVs) and remotely operated vehicles (ROVs) for sediment sampling. The proposed method is also applicable for the installation of underwater sensors using small AUVs and ROVs.