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51.
This study aims to evaluate the performance of ozone treatment for removing N-nitrosamines from reverse osmosis (RO) concentrate in water recycling applications. In the absence of any N-nitrosamine precursors, the destruction efficiency of N-nitrosamines was dependent on their molecular weight or the length of the alkyl chain in their molecular structure. Experiments conducted with RO concentrate showed that ozonation could lead to the formation of N-nitrosodimethylamine (NDMA) and N-nitrosodiethylamine (NDEA), resulting in an increase in concentrations of these N-nitrosamines. Nevertheless, ozonation was effective for destruction of N-nitrosamines with molecular weight greater than that of NDEA (102 g/mol). 相似文献
52.
High‐temperature latent heat storage technology to utilize exergy of solar heat and industrial exhaust heat
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Latent heat storage (LHS) using phase change materials is quite attractive for utilization of the exergy of solar energy and industrial exhaust heat because of its high‐heat storage capacity, heat storage and supply at constant temperature, and repeatable utilization without degradation. In this article, general LHS technology is outlined, and then recent advances in the uses of LHS for high‐temperature applications (over 100 °C) are discussed, with respect to each type of phase change material (e.g., sugar alcohol, molten salt, and alloy). The prospects of future LHS systems are discussed from a principle of exergy recuperation. In addition, the technologies to minimize exergy loss in the future LHS system are discussed on the basis of the thermodynamic analysis by ‘thermodynamic compass’. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
53.
Akihito Sagara Takahiro NomuraMasakatsu Tsubota Noriyuki OkinakaTomohiro Akiyama 《Materials Chemistry and Physics》2014
This paper describes the control of the melting point and improvement of the thermal endurance of D-mannitol (melting point Tm = 440 K) as a phase-change material (PCM) by vacuum impregnation of the PCM into nanosized pores of porous SiO2 grains. First, we examined the effects of the average pore size (DP) of porous SiO2 on Tm and latent heat (L) of PCM/SiO2 composites. Second, we investigated the thermal endurance of the composites using constant temperature kinetics based on L of the PCM and composites. Third, we performed cyclic tests of melting and freezing on the composite to evaluate leakage of the PCM. Thermophysical properties of the samples were measured by differential scanning calorimetry, and the following results were obtained: (1) The impregnation ratio of the composites was 0.91–0.99; therefore, almost all pores were completely filled with the PCM. (2) Tm shifted to lower temperature with smaller DP, reaching 413 K in case of the PCM/SiO2 composite with a DP of 11.6 nm (3) Tm was derived as a function of DP from the Gibbs–Thomson equation taking into account the existence of a nonfreezing layer on the surface of the pore wall. (4) The duration of thermal degradation of the PCM/SiO2 composite with DP = 11.6 nm was three times longer than that of the pure PCM at a temperature that is 10 K more than each melting point. (5) The PCM/SiO2 composite with DP = 11.6 nm can use as a shape-stable PCM composite without leakage of PCM. 相似文献
54.
Takahiro Matsumoto Tetsuro Nose Yasuaki Nagata Katsuhiro Kawashima Tastuya Yamada Hidetoshi Nakano Satoshi Nagai 《Journal of the American Ceramic Society》2001,84(7):1521-1525
Young's modulus and Poisson's ratio of SiC ceramics at temperatures >1400°C were obtained using a laser ultrasonics method that included a Fabry-Pérot interferometer (LUFP). At temperatures <1000°C, Young's modulus and Poisson's ratio measured using the LUFP method agreed well with those measured using standard contact methods, such as the resonance method and the ultrasonic pulse method. These results showed that the LUFP method is a powerful tool for measuring high-temperature elastic properties of advanced ceramics in a noncontact manner. 相似文献
55.
56.
Back Cover: Tailored Synthesis of 162‐Residue S‐Monoglycosylated GM2‐Activator Protein (GM2AP) Analogues that Allows Facile Access to a Protein Library (ChemBioChem 20/2016)
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57.
Masuda Takahiro Fujimitsu Kazushige Sumikawa Kosei Kajita Takahiro Tang Yongpeng Hirosawa Shoichi Takizawa Yoichi Yumoto Manabu Otagiri Yoshiharu Horita Zenji 《Metallurgical and Materials Transactions A》2021,52(9):3860-3870
Metallurgical and Materials Transactions A - This study examines strain distribution occurring in the high-pressure sliding (HPS) processing for rods of pure Al and an AZ61 alloy. The strain... 相似文献
58.
Tae Oike Yoshihito Sekiguchi Yuya Yoshimoto Takahiro Oike Ken Ando Wenchao Gu Yasushi Sasaki Takashi Tokino Akira Iwase Tatsuya Ohno 《International journal of molecular sciences》2022,23(1)
Radiotherapy is a definitive treatment for early-stage cervical cancer; however, a subset of this disease recurs locally, necessitating establishment of predictive biomarkers and treatment strategies. To address this issue, we performed gene panel-based sequencing of 18 stage IB cervical cancers treated with definitive radiotherapy, including two cases of local recurrence, followed by in vitro and in silico analyses. Simultaneous mutations in KRAS and SMAD4 (KRASmt/SMAD4mt) were detected only in a local recurrence case, indicating potential association of this mutation signature with radioresistance. In isogenic cell-based experiments, a combination of activating KRAS mutation and SMAD4 deficiency led to X-ray resistance, whereas either of these factors alone did not. Analysis of genomic data from 55,308 cancers showed a significant trend toward co-occurrence of mutations in KRAS and SMAD4. Gene Set Enrichment Analysis of the Cancer Cell Line Encyclopedia dataset suggested upregulation of the pathways involved in epithelial mesenchymal transition and inflammatory responses in KRASmt/SMAD4mt cancer cells. Notably, irradiation with therapeutic carbon ions led to robust killing of X-ray-resistant KRASmt/SMAD4mt cancer cells. These data indicate that the KRASmt/SMAD4mt signature is a potential predictor of radioresistance, and that carbon ion radiotherapy is a potential option to treat early-stage cervical cancers with the KRASmt/SMAD4mt signature. 相似文献
59.
Meng Guo Masakoto Kanezashi Hiroki Nagasawa Liang Yu Kazuki Yamamoto Takahiro Gunji Toshinori Tsuru 《American Institute of Chemical Engineers》2020,66(4):e16850
Fine-tuned, molecular-composite, organosilica membranes were fabricated via the co-condensation of organosilica precursors bis(triethoxysilyl)acetylene (BTESA) and bis(triethoxysilyl)benzene (BTESB). Fourier transform infrared and UV–vis spectra confirmed the co-condensation behaviors of BTESA and BTESB. The evolution of the network structure indicated that the incorporated BTESB decreased the membrane pore size, which was determined by a modified gas translation model according to the steric effect of the phenyl groups. The incorporation of BTESB to BTESA finely tuned the membrane structure and endowed the resultant composite membrane with improved separation properties. The BTESAB 9:1 membrane (molar ratio of BTESA/BTESB was 9:1) exhibited high C3H6 permeance at 4.5 × 10−8 mol m−2 s−1 Pa−1 and a C3H6/C3H8 permeance ratio of 33 at 50°C. One of the most important developments of this study involved clearly defining the relationship between membrane pore size and C3H6/C3H8 separation performance for organosilica membranes in single and binary separation systems. 相似文献
60.
Tohru Morii Toshio Tanimoto Hiroyuki Hamada Zen-Ichiro Maekawa Takahiro Hirano Kenji Kiyosumi 《Polymer Composites》1994,15(3):206-216
This study deals with the fracture process and acoustic emission (AE) characteristics of a randomly oriented E-glass fiber mat reinforcement with a crosslinked polyester. These panels were evaluated after they were immersed in hot water. The fiber volume content of the panel was 19%. Glass fiber reinforced plastics (GFRP) panels wer immersed in water at 81°C. Bending and AE monitoring tests were Performed and after bending, the cross-section of the specimen was observed by an optical microscope and SEM. The influence of degradation, due to water immersion, on the changes of fracture process of GFRP is discussed. The dominant fracture mode of the virgin specimen was matrix cracks, whereas that of the immersed specimen was debondings at the fiber bundle/matrix and fiber/matrix interfaces. This change was caused by reduction of the bonding strength at the interface. The scale of fracture can be estimated by both AE amplitude and AE energy and this estimation method was used to estimate the fracture mode changes of GFRP panels immersed in hot water. 相似文献