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91.
Lida T Nakamori R Yabuta R Yada S Takagi Y Mano N Ikegawa S Goto J Nambara T 《Lipids》2002,37(1):101-110
A facile and efficient synthesis of the carboxyl-linked glucosides of bile acids is described. Direct esterification of unprotected
bile acids with 2,3,4,6-tetra-O-benzyl-d-glucopyranose in pyridine in the presence of 2-chloro-1,3,5-trinitrobenzene as a coupling agent afforded a mixture of the
α- and β-anomers (ca. 1∶3) of the 1-O-acyl-d-glucoside benzyl ethers of bile acids, which was separated effectively on a C18 reversedphase chromatography column (isolated yields of α- and β-anomers are 4–9% and 12–19%, respectively). Subsequent hydrogenolysis
of the α- and β-acyl glucoside benzyl ethers on a 10% Pd−C catalyst in acetic acid/methanol/EtOAc (1∶2∶2, by vol) at 35°C
under atmospheric pressure gave the corresponding free esters in good yields (79–89%). Chemical specificities such as facile
hydrolysis and transesterification of the acyl glucosides in various solvents were also discussed. 相似文献
92.
Simultaneous surface modification by 3‐chloropropyl and methyl groups on the same Si atoms resulted in hydrophobic and highly
ordered mesoporous silica with a very high surface area. 13C and 29Si MAS NMR spectra indicate homogeneous grafting of chloropropyl and methyl groups in the silica matrix and this organically
modified Ti‐MCM‐41 shows outstanding catalytic performance in the epoxidation of cyclododecene using tert‐butyl hydroperoxide
as oxidant.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
93.
Hakoshima Toshio; Tanaka Masahiro; Itoh Takeshi; Tomita Ken-khi; Amisaki Takashi; Nishikawa Satoshi; Morioka Hiroshi; Uesugi Sei-ichi; Ohtsuka Eiko; Ikehara Morio 《Protein engineering, design & selection : PEDS》1991,4(7):793-799
Hydrophobic effects on binding of ribonuclease Tl to guaninebases of several ribonucleotides have been proved by mutatinga hydrophobic residue at the recognition site and by measuringthe effect on binding. Mutation of a hydrophobic surface residueto a more hydrophobic residue (Tyr45 Trp) enhances thebinding to ribonucleotides, including mononucleotide inhibitorand product, and a synthetic substrate-analog trinudeotide aswell as the binding to dinucleotide substrates and RNA. Enhancementson binding to non-substrate ribonucleotides by the mutationhave been observed with free energy changes ranging from 2.2 to 3 .9 kJ/mol. These changes are in good agreementwith that of substrate binding, 2.3 kJ/mol, which iscalculated from Michaelis constants obtained from kinetic studies.It is shown, by comparing the observed and calculated changesin binding free energy with differences in the observed transferfree energy changes of the amino acid side chains from organicsolvents to water, that the enhancement observed on guaninebinding comes from the difference in the hydrophobic effectsof the side chains of tyrosine and tryptophan. Furthermore,a linear relationship between nucleolytic activities and hydrophobicityof the residues (Ala, Phe, Tyr, Trp) at position 45 is observed.The mutation could not change substantially the base specificityof RNase Tl, which exhibits a prime requirement for guaninebases of substrates. 相似文献
94.
Takashi Kojima Wataru Sakamoto Toshinobu Yogo Takashi Fujii Shin-ichi Hirano 《Journal of the American Ceramic Society》2002,85(9):2212-2216
An in situ composite composed of ceria-stabilized tetragonal zirconia polycrystals (Ce-TZP) and La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 was synthesized from a powder mixture of Ce-TZP, La(Fe0.9 Al0.1 )O3 , Fe2 O3 , Al2 O3 , and CoO. The dense Ce-TZP dispersed with platelike La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 crystals as a second phase were formed after sintering from 1250° to 1350°C. The saturation magnetization of the in situ composite Ce-TZP/La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 was proportional to the mass fraction of the hexaferrite second phase in Ce-TZP. The coercivity of the composite with a 20 mass% of second phase decreased from 9.14 to 2.52 kOe (from 728 to 201 kA/m) after the pulverization of the composite. The susceptibility (χ) increased by 15%–25% under uniaxial stress on the composite. The change of the susceptibility (Δχ/χ) value increased with decreasing the mass fraction of the second phase in the composite. The Δχ was found to increase linearly with applied stress and abruptly change on cracking, which is expected for the application in fracture sensing of the composite. 相似文献
95.
Tatsuya Kodama Ken-ichi Tominaga Masahiro Tabata Takashi Yoshida Yutaka Tamaura 《Journal of the American Ceramic Society》1992,75(5):1287-1289
Active wustite (FeδO, with a δ value of 0.98) was prepared by keeping normal wustite (δ value of 0.94) in a N2 atmosphere at 300°C for 10 min. This reaction is given by (4δ2 –3)Feδ1 O→(4δ1 –3)Feδ2 O + (δ2 –δ1 )Fe3 O4 where δ1 = 0.94 and δ2 = 0.98. The equation indicates that the normal wustite undergoes eutectoid decomposition into active wustite and stoichiometric magnetite (Fe3 O4 ). Carbon dioxide (1.013 × 105 Pa) was almost completely (100%) decomposed into carbon (zero valence) by the active wustite at the low temperature of 300°C, which was associated with the transformation of the active wustite into the stoichiometric magnetite. The internal pressure of the reaction cell eventually became a vacuum. 相似文献
96.
Autoxidation of ethyl eicosapentaenoate and docosahexaenoate 总被引:2,自引:0,他引:2
Soon-Yeong Cho Kazuo Miyashita Teruo Miyazawa Kenshiro Fujimoto Takashi Kaneda 《Journal of the American Oil Chemists' Society》1987,64(6):876-879
The extent of oxidation of ethyl esters of eicosapentaenoic (EPA) and docosahexaenoic acids (DHA) was compared quantitatively
with that of ethyl linoleate (Lo) and ethyl linolenate (Ln) by oxygen uptake and formation of conjugated diene, hydroperoxide
and secondary oxidation products. EPA and DHA esters were oxidized rapidly even at 5 C in the dark after an induction period
of 3–4 days, while the induction periods of Ln and Lo esters were 20 days and more than 60 days, respectively. Oxygen uptake
of EPA and DHA esters after the induction period was 5.2 and 8.5 times faster than that of ethyl Ln, respectively. Hydroperoxides
of EPA and DHA esters are much less stable than those of ethyl Lo. The peroxide value is not necessarily a good indication
of oxidation in these polyenoic acids because a considerable amount of secondary products is formed at the early stage of
oxidation. Polymers were found to be major secondary products in these polyenoic esters. 相似文献
97.
Pervaporation membranes for the ethanol–water mixture were prepared by plasma polymerization of tetrafluoroethylene, perfluoropropane, and perfluoropropylene onto porous substrates. The influence of the monomers on the elemental ratio (F/C) of the polymer depositions by X-ray photoelectron spectroscopy was rather small compared with that of the W/FM parameter (W = wattage for plasma excitation, FM = mass flow rate of a monomer). The optical emission spectroscopy indicated the similarity of gaseous species formed in the plasmas. The membranes were found ethanol-permselective, showing separation coefficients (αEtOH) around 4–7 and a wide range of permeation rates (J), 10–10?2 kg/m2 h, for the 4.8 wt % ethanol solution at 40°C. The αEtOH of the membranes with thicker depositions could be correlated to the F/C ratios as a measure of membrane hydrophobicity. It was thought that, by making a plot αEtOH against J values for the perfluorocarbon membranes, they could be classified into three groups on thickness of deposition. The ethanol-separation mechanisms for each group, which may contain four kinds of mass transfer schemes, i.e., distillation through larger pores, flow of sorption layer at the liquid–membrane interface, and diffusions through deposition or substrate, were also discussed. 相似文献
98.
Takashi Inoue 《Carbon》2007,45(11):2164-2170
Iron-based nanoparticles, centrifugally classified by size, with variation of subnanometer order, have been used for the growth of diameter-controlled carbon nanotubes (CNTs) for the first time via catalytic chemical vapor deposition. The centrifugal classification of nanoparticles is facilitated by fractional precipitations through the sequential addition of ethanol to a hexane solution containing the nanoparticles. Three different nanoparticle sizes were obtained, which have average diameters and standard deviations of 3.9 ± 0.8 nm, 3.3 ± 0.6 nm, and 2.8 ± 0.4 nm. By the classification process of nanoparticles, the standard deviation of the average diameter of the fractionated nanoparticles decreased by around one half of that of the as-synthesized nanoparticles. In addition, we demonstrate a technique for estimating the average diameter of each classified nanoparticle using conventional low-angle X-ray diffraction, without the need for time-consuming TEM observation and analysis. From the three classified nanoparticle sizes, with average diameters of 2.8, 3.3, and 3.9 nm, CNTs with average diameters of 3.1, 3.6, and 4.5 nm were obtained by changing growth temperatures, respectively. Therefore, centrifugally classified nanoparticles are one of the most promising ‘seeds’ for use in the diameter-selective growth of CNTs. 相似文献
99.
Tsunehiro Aki Kazutaka Hachida Megumi Yoshinaga Yuko Katai Takashi Yamasaki Seiji Kawamoto Toshihide Kakizono Takashi Maoka Seiko Shigeta Osamu Suzuki Kazuhisa Ono 《Journal of the American Oil Chemists' Society》2003,80(8):789-794
Thraustochytrids, marine protists whose dominant genera are Thraustochytrium and Schizochytrium, belong to the kingdom Chromista and are known as an industrial source of DHA. We describe here that thraustochytrid strain
KH105, isolated as a DHA producer, also accumulates significant levels of β-carotene and xanthophylls including canthaxanthin
and astaxanthin. A4-d cultivation using a medium composed of 10% glucose and less than 0.3% of nitrogen sources in a half-concentration
of seawater gave an astaxanthin production up to 6.1 mg/L, and canthaxanthin content reached more than 10 mg/L under conditions
where a higher concentration of nitrogen sources (6%) was employed. It might be advantageous in mass production systems for
these carotenoids to be extracted readily by simply suspending the cells with organic solvents such as acetone and chloroform.
Analyses on the morphological and life history features of the KH105 strain revealed that it belongs to the genus Schizochytrium. This particular species of thraustochytrids is thus considered to be a promising source of xanthophylls as well as DHA for
use in the food industry. 相似文献
100.
Yasushi Endo Riichiro Usuki Takashi Kaneda 《Journal of the American Oil Chemists' Society》1985,62(9):1387-1390
To understand the mechanism of the antioxidant effect of chlorophyll on the autoxidation of oils in the dark, antioxidant
activities of several derivatives of chlorophyll were compared. Antioxidant activities were observed in chlorophyll derivatives
such as protopor-phyrin methyl ester and its magnesium chelated compound. Porphyrin seems to be an essential chemical structure
for the antioxidant activity of chlorophyll. Chlorophyll did not decompose the hydroperoxides, but reduced free radicals such
as 1,1-diphenyl-2-picrylhydrazyl. Electron spin resonance spectrum of the π-cation radical was recorded during the oxidation
of chlorophyll in methyl linoleate solution. These observations suggest that chlorophyll may act as a hydrogen donor to break
the chain reaction. 相似文献