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91.
We previously reported that a copolymer consisting of N-isopropylacrylamide (NIPAM) and benzophenone (BP) units, behaves as a photosensitizer showing temperature-controlled oxygenation activity in water (J. Am. Chem. Soc.2006, 128, 8751). This polymer shows a heat-induced oxygenation enhancement at low temperature region (5-20 °C), while showing a heat-induced oxygenation suppression at high temperature region (20-60 °C), resulting in an off-on-off activity profile against the temperature window. This is driven by a heat-induced phase transition of the polymer from coil to micelle and then to globule states. In the present work, effects of adding an amine component (N-[3-(dimethylamino)propyl]acrylamide: DMAPAM) to the polymer on the sensitization activity were studied, where the relationship between the phase transition behavior and the activity was clarified by several spectroscopic analyses. The polymers, poly(NIPAMx-co-BPy-co-DMAPAMz), show activity controlled by temperature and pH. The off-on-off activity profile shifts to higher temperature with a pH decrease. This is because protonation of the DMAPAM units leads to an increase in the polymer polarity and, hence, the polymer aggregates at higher temperature. In addition, increase in the DMAPAM content of the polymer leads to further shift of the activity profile. In contrast, at pH < 8, no activity enhancement is observed because complete protonation of the DMAPAM units suppresses polymer aggregation. 相似文献
92.
Enhanced Light Storage of SrAl2O4 Glass‐Ceramics Controlled by Selective Europium Reduction
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Takayuki Nakanishi Kazune Watanabe Jumpei Ueda Koji Fushimi Setsuhisa Tanabe Yasuchika Hasegawa 《Journal of the American Ceramic Society》2015,98(2):423-429
A luminescent Eu, Dy: SrAl2O4 glass‐ceramics with high transparency in the visible region was successfully synthesized using the frozen sorbet technique with the control of O2 partial pressure () for the oxidation of Eu2+ ions. The glass‐ceramics include Eu2+, Eu3+, and Dy3+ ions, and thus exhibits three characteristic types of emission bands, 4f–5d at around 520 nm (Eu2+ ions), 4f–4f at 610 nm (Eu3+ ions), and 480 nm (Dy3+ ions). The Eu, Dy: SrAl2O4 glass‐ceramics provide remarkable long‐persistent luminescence under dark condition. The glass‐ceramics also exhibits color‐changing luminescence in the visible region based on their remarkable light storage properties. The luminescent Eu, Dy: SrAl2O4 glass‐ceramics using the frozen sorbet technique with control of are promising materials for application in novel photonic and light storage materials. 相似文献
93.
统一强度理论的发展及其在土木水利等工程中的应用和经济意义 总被引:10,自引:5,他引:10
统一强度理论是在中国本土原创产生和发展起来的关于材料强度和结构强度的系统新理论。它从连续统力学最基本的单元体力学模型开始,到数学建模方法,理论公式的表述,以及一系列新的理论公式都不同于以往的各种理论。它将以往各种适合于某一类材料的单一强度理论推进为可以适合于多种材料的统一强度理论。经过40多年的发展,它不仅自己形成了系统的理论,而且将很多著名的理论包容其中,形成了范围更宽广、功能更强大的理论体系。由于它具有一个统一的力学模型,清晰的物理意义,简单的线性数学表述式,能反映材料的基本特性,即sD效应(不同的抗拉强度和抗压强度)、静水应力效应、正应力效应、中间主应力效应和中间主剪应力效应,以及结构强度分析的破坏准则效应,并且与现有的实验数据相吻合,能容易地适合许多新情况;此外,统一强度理论既容易用来取得解析解,也容易用于计算机程序取得数值解。统一强度理论已被推广应用于很多领域。在连续介质和工程应用的框架下对统一强度理论的发展及其在土木工程中的应用和经济意义进行较为系统的小结。 相似文献
94.
Watanabe Masahito Sato Fumiya Abe Raiki Ueda Kyosuke Matsuwaka Daisuke Kudo Fumiaki Narushima Takayuki 《Metallurgical and Materials Transactions B》2019,50(4):1553-1558
Metallurgical and Materials Transactions B - A two-step plasma arc melting process, comprising a first step under Ar-30 pct H2 gas flow and the second step under Ar gas flow, has been... 相似文献
95.
R.W. Callis J.L. Doane H.J. Grunloh K. Kajiwara A. Kasugai C.P. Moeller Y. Oda R.A. Olstad K. Sakamoto K. Takahashi 《Fusion Engineering and Design》2009,84(2-6):526-529
Initial testing on the Japan Atomic Energy Agency Gyrotron Test Stand of ITER-relevant TL components, has shown reasonable efficiencies, but identified that trapped modes between closely located miter bends, as well as mode conversion at miter bends can lead to excessive heating of the connecting waveguides. General Atomics has designed, built, and will test components to address this issue as well as ITER relevant components that have not been tested at the levels of 1 MW, 170 GHz, for extended pulse lengths. Some of the components that will be tested are ultra low loss miter bends, dc breaks, polarizers, power monitors, bellows, waveguide switches, waveguide cooling clamps, etc. Details of the components and test results will be presented. 相似文献
96.
Corrosion characteristics of reduced activation ferritic steel, JLF-1 (8.92Cr–2W) in molten salts Flibe and Flinak 总被引:1,自引:0,他引:1
Masatoshi Kondo Takuya Nagasaka Qi Xu Takeo Muroga Akio Sagara Nobuaki Noda Daisuke Ninomiya Masaru Nagura Akihiro Suzuki Takayuki Terai Naoki Fujii 《Fusion Engineering and Design》2009,84(7-11):1081-1085
Static corrosion tests were performed in molten salts, LiF–BeF2 (Flibe) and LiF–NaF–KF (Flinak), at 500 °C and 600 °C for 1000 h. The purpose is to investigate the corrosion characteristics of reduced activation ferritic steels, JLF-1 (8.92Cr–2W) in the fluids. The concentration of hydrogen fluoride (HF) in the fluids was measured by slurry pH titration method before and after the exposure. The HF concentration determined the fluoridation potential. The corrosion was mainly caused by dissolution of Fe and Cr into the fluids due to fluoridation and/or electrochemical corrosion. Carbon on the surface might be dissolved into the fluids due to the corrosion, and this resulted to the decrease of carbide on the surface. The corrosion depth of the JLF-1 specimen, which was obtained from the weight losses, was 0.637 μm in Flibe at 600 °C and 6.73 μm in Flinak at 600 °C. 相似文献
97.
The n-6/n-3 fatty acid (FA) ratio has increased in the Western-style diet to ~10–15:1 during the last century, which may have
contributed to the rise in cardiovascular disease (CVD). Prior studies have evaluated the effects on CVD risk factors of manipulating
the levels of n-6 and n-3 FA using food and supplements or investigated the metabolic fate of linoleic acid (LNA) and α-linolenic
acid (ALA) by varying the n-6/n-3 ratios. However, no previous studies have investigated the potential interaction between
diet ratios and supplementation with eicosapentaenoic acid (EPA, 20:5n-3) and docosahexaenoic acid (DHA, 22:6n-3). We used
a factorial design approach with adults (n = 24) in a controlled feeding trial to compare the accretion of EPA and DHA into red blood cell membranes (RBC) by adding
a direct source (algal oil supplement) of EPA and DHA in a diet with a 10:1 versus 2:1 ratio of n-6/n-3 FA. Subjects were
randomized into 8-week crossover diet sequences and each subject consumed three of four diets [10:1, 10:1 plus supplement
(10:1 + S), 2:1 and 2:1 + S]. LNA and ALA intakes were 9.4 and 7.7%, and 1.0 and 3.0% during the low and high ALA diets, respectively.
Compared to the Western-style 10:1 diet, the 2:1 diet increased EPA by 60% (P < 0.0001) in RBC membranes without the direct EPA source and a 34% increase (P = 0.027) was observed with the 10:1 + S diet; however, DHA levels increased in both diet ratios only with a direct DHA source.
Shifting towards a 2:1 diet is a valid alternative to taking EPA-containing supplements. 相似文献
98.
K. Kainosho M. Ohta M. Uchida M. Nakamura O. Oda 《Journal of Electronic Materials》1996,25(3):353-356
Recently, it was found that undoped semi-insulating InP can be obtained by highpressure annealing of high purity materials.
The reproducibility and the uniformity was, however, not satisfactory. In the present work, we found that not only Fe concentrations
but also Cr and Ni concentrations in annealed wafers were slightly increased during annealing. Since it seems that the origin
of the contamination was due to the vapor source of red phosphorus, conductive InP with a trace amount of Fe was annealed
under low phosphorus vapor pressure in order to reduce the contamination. By preventing the contamination of Cr and Ni, preparation
of semi-insulating InP became highly reproducible. The minimum Fe concentration for realizing semi-insulating InP was found
to be 1 x 1015cm−3. It was also found that the better resistivity uniformity can be obtained at higher annealing temperatures. 相似文献
99.
Takayuki Sasaki Takayuki Koukami Taishi Kobayashi Akira Kirishima Hiroaki Murakami Yuki Amano 《Journal of Nuclear Science and Technology》2017,54(3):373-381
At two underground research laboratories situated at Horonobe and Mizunami, Japan, trace amounts of natural thorium and uranium dissolved in deep groundwater were investigated with the help of chemical pre-concentration method. The groundwater was sampled from underground boreholes under the geochemical condition of no atmospheric exposure, and the colloid contribution was checked by in situ two size-fractionated ultrafiltration systems. A rough decrease by half in the concentration after in situ filtration suggested the presence of natural colloids and suspended matter that were carriers of a portion of the elements. The Th and U concentrations in groundwater after 10 kDa filtration was evaluated as dissolved species, and was identified thermodynamically using existing hydrogeological and geochemical data, such as the mineral components in the groundwater at a given pH, ionic strength, concentration of co-existing ions, redox potential, and a hypothetical solubility-limiting solid phase. The crystalline solid phase of tetravalent thorium and uranium dioxides made the solubility very low compared with that of the amorphous phase. 相似文献
100.
Manabu Nishijima Irina D. Gocheva Shigeto Okada Takayuki Doi Jun-ichi Yamaki Tetsuaki Nishida 《Journal of power sources》2009,190(2):558-562
Fluorine compounds have high discharge voltage due to its highly ionic metal-ligand bonds. In them, perovskite-type metal trifluorides with corner sharing matrix have large bottlenecks of diffusion pathways for intercalants. Iron trifluoride composites (FeF3-C) prepared by planetary ball milling with carbon showed reversible charge/discharge behavior not only for Li, but also for Na anodes. X-ray diffraction and 57Fe Mössbauer spectroscopy were applied to characterize the electrochemical properties of FeF3 vs. Li and Na anodes. The cathode performances of the other commercially available transition metal trifluorides such as MF3 (M = Ti, V, Mn, Co) have been also investigated. 相似文献