全文获取类型
收费全文 | 1602篇 |
免费 | 50篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 80篇 |
化学工业 | 443篇 |
金属工艺 | 29篇 |
机械仪表 | 40篇 |
建筑科学 | 20篇 |
能源动力 | 76篇 |
轻工业 | 138篇 |
水利工程 | 5篇 |
石油天然气 | 2篇 |
无线电 | 98篇 |
一般工业技术 | 301篇 |
冶金工业 | 280篇 |
原子能技术 | 39篇 |
自动化技术 | 105篇 |
出版年
2024年 | 3篇 |
2023年 | 12篇 |
2022年 | 40篇 |
2021年 | 45篇 |
2020年 | 25篇 |
2019年 | 30篇 |
2018年 | 35篇 |
2017年 | 38篇 |
2016年 | 46篇 |
2015年 | 30篇 |
2014年 | 59篇 |
2013年 | 104篇 |
2012年 | 84篇 |
2011年 | 82篇 |
2010年 | 68篇 |
2009年 | 71篇 |
2008年 | 76篇 |
2007年 | 61篇 |
2006年 | 62篇 |
2005年 | 45篇 |
2004年 | 37篇 |
2003年 | 46篇 |
2002年 | 29篇 |
2001年 | 35篇 |
2000年 | 36篇 |
1999年 | 33篇 |
1998年 | 89篇 |
1997年 | 62篇 |
1996年 | 56篇 |
1995年 | 23篇 |
1994年 | 25篇 |
1993年 | 25篇 |
1992年 | 11篇 |
1991年 | 11篇 |
1990年 | 17篇 |
1989年 | 13篇 |
1988年 | 8篇 |
1987年 | 11篇 |
1986年 | 6篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1977年 | 3篇 |
1976年 | 10篇 |
1975年 | 8篇 |
1974年 | 3篇 |
排序方式: 共有1656条查询结果,搜索用时 15 毫秒
92.
Kenji Goto Takuya Kawashima Nobuo Tanabe 《Solar Energy Materials & Solar Cells》2006,90(18-19):3251-3260
We developed new heat-resisting transparent conductive oxide (TCO) films with resistivity of 1.4×10−4 Ω cm, an optical transmittance of above 80% (at 550 nm) and heat-resisting temperature at above 600 °C. The TCO films consists of fluorine-doped tin oxide films coated on indium–tin oxide films. They were prepared by a spray pyrolysis deposition method on glass substrates. The 100×100 mm2 dye-sensitized solar cells (DSCs) were prepared with the TCO films. An energy conversion efficiency of the DSC was improved drastically in comparison to the case with conventional TCO films. 相似文献
93.
The effects of the polymorphic form on the compression mechanism of forms A, B, and F of phenobarbital were investigated using a compression simulator, mercury porosimetry, X-ray diffraction analysis, BET gas absorption method, and scanning electron microscopic (SEM) photography. The order of tablet hardness obtained from all phenobarbital polymorphs was form A ≥ form B ≥ form F in accordance with that of the specific surface area. The Cooper and Eaton method was applied to evaluate two individual compression processes: particle rearrangement (phase I) and fragmentation and/or deformation (phase II). The parameters for compression processes were calculated using a nonlinear regression analyses program, and the compression energies of phases I and II were calculated from these parameters. The relationship between specific surface area after compression and compression energy at phase I showed a good linear correlation, but their ratio did not. In contrast, the specific surface area ratio showed a linear relationship with the compression energy on phase II, but again the ratio of these two parameters did not. The tablet hardness showed a linear relationship with the specific surface area ratio, but not with the specific surface area. Again, the ratio of these two parameters did not show a linear relationship. 相似文献
94.
Atsushi Watarai Keigo Kubota Masaki Yamagata Takuya Goto Toshiyuki Nohira Rika Hagiwara Koichi Ui Naoaki Kumagai 《Journal of power sources》2008,183(2):724-729
The physicochemical properties of molten alkali bis(trifluoromethylsulfonyl)amide, MTFSI (M = Li, K, Cs), mixture (xLiTFSI = 0.20, xKTFSI = 0.10, xCsTFSI = 0.70) were studied to develop a new rechargeable lithium battery operating at intermediate temperature (100–180 °C). The viscosity and ionic conductivity of this melt at 150 °C are 87.2 cP and 14.2 mS cm−1, respectively. The cyclic voltammetry revealed that the electrochemical window at 150 °C is as wide as 5.0 V, and that the electrochemical deposition/dissolution of lithium metal occurs at the cathode limit. A Li/MTFSI (M = Li, K, Cs)/LiFePO4 cell showed an excellent cycle performance at a constant current rate of C/10 at 150 °C; 95% of the initial discharge capacity was maintained after 50 cycles. Except for the initial few cycles, the coulombic efficiencies were approximately 100% for all the cycles, indicating the stabilities of the molten MTFSI mixture and all the electrode materials. 相似文献
95.
Tomohiro Toigawa Yasuhiro Tsubata Takeshi Kai Takuya Furuta Yuta Kumagai Tatsuro Matsumura 《溶剂提取与离子交换》2021,39(1):74-89
ABSTRACT Absorbed-dose estimation is essential for evaluation of the radiation tolerance of minor-actinide-separation processes. We propose a dose-evaluation method based on radiation permeability, with comparisons of heterogeneous structures seen in the solvent-extraction process, such as emulsions forming in the mixture of the organic and aqueous phases. A demonstration of radiation-energy-transfer simulation is performed with a focus on the minor-actinide-recovery process from high-level liquid waste with the aid of the Monte Carlo radiation-transport code PHITS. The simulation results indicate that the dose absorbed by the extraction solvent from alpha radiation depends upon the emulsion structure, and that from beta and gamma radiation depends upon the mixer-settler-apparatus size. Non-negligible contributions of well-permeable gamma rays were indicated in terms of the plant operation of the minor-actinide-separation process. 相似文献
96.
Katsuhiko Ariga Takashi Nakanishi Yukiko Terasaka Jun-ichi Kikuchi 《Journal of Porous Materials》2006,13(3):427-430
As a soft and flexible porous structure, a pore array of a steroid cyclophane SC(OH), which consists of the rigid 1,6,20,25-tetraaza[6.1.6.1]paracyclophane
ring connected to four steroid moieties (cholic acid) through flexible L-lysine spacers, was prepared at the air-water interface.
As confirmed by surface pressure (π)-molecular area (A) isotherms, transition between open conformation and cavity conformation
of the SC(OH) molecule was reversibly induced upon repeated compression and expansion of its monolayer at pH 11 where amino
groups of the lysine residues are not fully deprotonated. Capture and release of an aqueous fluorescent guest (TNS) by SC(OH)
was observed upon dynamic cavity formation through surface fluorescence spectroscopy. At pH 12, dynamic cavity formation of
SC(OH) was sufficiently suppressed, and the capture and release of an aqueous TNS by the monolayer was not virtually observed.
Lessened electrostatic repulsion between the SC(OH) molecules due to conversion of ammonium to free amine may prevent the
cavity from reopening. The importance of dynamic nature of cavity formation on the guest binding was also proved by control
experiments using SC(H), which cannot form cavity conformation at any surface pressures at both pH 11 and 12. 相似文献
97.
Oikawa D Nakanishi T Nakamura Y Takahashi Y Yamamoto T Shiba N Tobisa M Takagi T Iwamoto H Tachibana T Furuse M 《Lipids》2003,38(6):609-614
This study investigated the influence of PUFA on the properties of mouse skin. Mice (3 wk old) were given free access to oils
high in linoleic acid, CLA, or DHA for 4 wk. At the end of the experiment, their skins were compared by both biochemical and
histological methods. No significant differences in lipid and collagen contents were detected among treatments, although the
FA composition in the skin was altered depending upon the FA composition of the supplemented oils. Electron microscopy revealed
that the subcutaneous tissue layers in the CLA and DHA groups were significantly thinner than that in the high linoleic acid
group, whereas no differences in the thickness of dermis layers were observed among the three groups. These results suggest
that skin properties in mice are readily modified by dietary FA sources within 4 wk of dietary oil supplementation. 相似文献
98.
The main sources of dioxin emissions are municipal solid waste incinerators. The Japanese national government has set an emission standard for dioxins to reduce dioxin exposure levels. In this study, cost-effectiveness analyses are carried out regarding countermeasures that were recently taken and are being taken at municipal solid waste incinerators in Japan. Annual costs were estimated by telephone survey and model calculations. Annual decrease in the incidence of cancer was estimated in three steps. First, the annual decrease in the volume of dioxin emissions was estimated. Next, using a mathematical model, the annual decrease in human exposure was estimated. Finally, the annual decrease in the incidence of cancer was estimated by applying the cancer slope factor. When annual costs are divided by the annual number of life-years saved, cost per life-year saved (CPLYS) was obtained. CPLYS was estimated to be 7.9 million yen for emergency countermeasures and 150 million yen for long-term countermeasures. However, it must be noted that these obtained CPLYSs are highly dependent on the cancer slope factor and should be considered as an upper limit since there may be a cancer effect threshold. 相似文献
99.
Md. Zaved Hossain Khan Takuya Nakanishi Shigeki Kuroiwa Yoichi Hoshi Tetsuya Osaka 《Electrochimica acta》2011,(24):8657
The effect of surface modification of indium tin oxide (ITO) electrode on its potential response to tryptophan was investigated for ITO substrates with different surface roughness. It was found that a small difference in surface roughness, between ∼1 and ∼2 nm of Ra evaluated by atomic force microscopy, affects the rest potential of ITO electrode in the electrolyte. A slight difference in In:Sn ratio at the near surface of the ITO substrates, measured by angle-resolved X-ray photoelectron spectrometry and Auger electron spectroscopy is remarkable, and considered to relate with surface roughness. Interestingly, successive modification of the ITO surface with aminopropylsilane and disuccinimidyl suberate, of which essentiality to the potential response to indole compounds we previously reported, improved the stability of the rest potential and enabled the electrodes to respond to tryptophan in case of specimens with Ra values ranging between ∼2 and ∼3 nm but not for those with Ra of ∼1 nm. It was suggested that there are optimum values of effective work function of ITO for specific potential response to tryptophan, which can be obtained by the successive modification of ITO surface. 相似文献
100.
Naoto Kitamura Takuya Hasegawa Yoshiharu Uchimoto Koji Amezawa Yasushi Idemoto 《Electrochimica acta》2011,(25):9453
LiNi0.5Mn0.5O2 was heat-treated under high oxygen-pressure and Ar-reducing conditions, and then the cathode properties, thermodynamic stability and average and local structures were investigated. From X-ray diffraction and ICP measurements, it was found that the pristine LiNi0.5Mn0.5O2 had a single phase of the layered rock-salt structure although the Ni content was slightly rich compared with the nominal one. These characteristics were kept even after the heat-treatments. Charge–discharge cycle tests clarified that the cycle performance of LiNi0.5Mn0.5O2 was improved by both the reducing and oxidizing treatments. From neutron diffraction and X-ray absorption fine structure measurements, the local distortion around the transition metal, especially Ni, was supposed to be one of the important factors to determine the cathode properties. It was also found that the sample with higher thermodynamic stability exhibited better capacity retention in the discharge–charge cycle tests. 相似文献