全文获取类型
收费全文 | 632篇 |
免费 | 39篇 |
专业分类
电工技术 | 6篇 |
化学工业 | 131篇 |
金属工艺 | 9篇 |
机械仪表 | 13篇 |
建筑科学 | 17篇 |
矿业工程 | 1篇 |
能源动力 | 12篇 |
轻工业 | 61篇 |
水利工程 | 2篇 |
石油天然气 | 1篇 |
无线电 | 77篇 |
一般工业技术 | 134篇 |
冶金工业 | 92篇 |
原子能技术 | 2篇 |
自动化技术 | 113篇 |
出版年
2024年 | 4篇 |
2023年 | 5篇 |
2022年 | 17篇 |
2021年 | 23篇 |
2020年 | 16篇 |
2019年 | 22篇 |
2018年 | 24篇 |
2017年 | 20篇 |
2016年 | 20篇 |
2015年 | 14篇 |
2014年 | 28篇 |
2013年 | 55篇 |
2012年 | 26篇 |
2011年 | 56篇 |
2010年 | 37篇 |
2009年 | 24篇 |
2008年 | 23篇 |
2007年 | 23篇 |
2006年 | 30篇 |
2005年 | 18篇 |
2004年 | 10篇 |
2003年 | 12篇 |
2002年 | 3篇 |
2001年 | 4篇 |
2000年 | 9篇 |
1999年 | 14篇 |
1998年 | 26篇 |
1997年 | 22篇 |
1996年 | 11篇 |
1995年 | 11篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1981年 | 3篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1977年 | 2篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有671条查询结果,搜索用时 31 毫秒
111.
J. Fornell S. González E. Rossinyol S. Suriñach M.D. Baró D.V. Louzguine-Luzgin J.H. Perepezko J. Sort A. Inoue 《Acta Materialia》2010,58(19):6256-6266
Fe36Co36B19.2Si4.8Nb4 bulk glassy rods were synthesized by copper mould casting. The effects of annealing treatments on the microstructure, elastic and mechanical properties of this alloy are investigated. Annealing below the glass transition temperature induces the formation of atomic clusters with pseudo-tenfold symmetry with a close relationship to the Fe23B6 phase. Annealing at sufficiently high temperatures promotes the formation of stable Fe2B and FeB phases and Fe(Co) solid solution. The as-cast alloy exhibits ultra-high hardness (H > 14 GPa), high reduced Young’s modulus (Er > 200 GPa) and good wear resistance. These properties are further enhanced after thermal treatments (H > 18 GPa and Er > 260 GPa are achieved in the fully crystallized sample). The mechanical hardening is accompanied with an increase of the elastic recovery and a decrease of the Poisson’s ratio. The different microstructural mechanisms responsible for these annealing-induced changes in mechanical and elastic properties are discussed. 相似文献
112.
We consider a batch production process that can be either stable or unstable, in which inspection is performed offline after production of the batch is completed. The quality of a batch can be estimated with a desired level of certainty by inspecting only a sample of its units. In order to minimise the expected total cost per batch, which includes the costs of inspection, of false acceptance and of false rejection, we propose an economic inspection plan in which only a fraction of the batches, rather than each batch, is inspected. We prove that the expected total cost is a strictly quasiconvex function of the inspection interval. We establish necessary and sufficient conditions for the optimal inspection interval to be finite and propose an efficient algorithm to obtain its value. We demonstrate for the case of a single-sampling plan where the proposed economic approach outperforms the common procedure of inspecting every batch, and the proposed algorithm is very efficient. 相似文献
113.
Anna Adamczyk Yeping Xu Bernadeta Walaszek Frank Roelofs Tal Pery Karin Pelzer Karine Philippot Bruno Chaudret Hans-Heinrich Limbach Hergen Breitzke Gerd Buntkowsky 《Topics in Catalysis》2008,48(1-4):75-83
In the current study two new classes of stabile, catalytic active nanomaterials are investigated. The first class of nanoparticles consists of an inner metal core. To stabilize their structure the metal core is surrounded by organic ligands or embedded in a polymer. The second class consists of catalysts immobilized on mesoporous silica supports of SBA-3 type silica. Employing a combination of 1H, 2H, 13C and 29Si-solid state NMR spectroscopy the structure of the catalysts is analyzed. As a simple model for the catalytic properties of the particles, the activation of 2H2 gas on the surface of the particles is studied. Employing 1H and 2H gas phase NMR the kinetics of simple catalytic model reactions is studied. Employing 2H-NMR solid state NMR spectroscopy, the interaction of the metal surface with the substrate is characterized and kinetic data, which characterize the mobility of the deuterium on the surface, are extracted. For the interpretation of these data, parallel NMR studies of model η2-bound transition metal complexes are employed, which allow, owing to their simpler geometry and higher sensitivity, a quantitative modeling of the spin dynamics in the NMR experiment. 相似文献
114.
Niels J. Sijbrandi Ad J. Kimenai Edwin P.C. Mes René Broos Georg Bar Martin Rosenthal Yaroslav I. Odarchenko Dimitri A. Ivanov Jan Feijen Pieter J. Dijkstra 《Polymer》2012,53(19):4033-4044
Segmented poly(ether ester amide)s comprising glycine or β-alanine extended bisoxalamide hard segments are highly phase separated thermoplastic elastomers with a broad temperature independent rubber plateau. These materials with molecular weights, Mn, exceeding 30 × 103 g mol?1 are conveniently prepared by polycondensation of preformed bisester–bisoxalamides and commercially available PTHF diols. FT-IR revealed strongly hydrogen bonded and highly ordered bisoxalamide hard segments with degrees of ordering between 73 and 99%. The morphology consists of fiber-like nano-crystals randomly dispersed in the soft polymer matrix. The micro-structural parameters of the copolymers were addressed by simultaneous small- and wide-angle X-ray scattering. It is shown that the crystals have strictly identical thickness, which is close to the contour length of the hard segment. The long dimension of the crystals is identified with the direction of the hydrogen bonds. The melting transitions of the hard segments are sharp, with temperatures up to 170 °C. The studied polymers have an elastic modulus in the range of 139–170 MPa, a stress at break in the range of 19–31 MPa combined with strains at break of higher than 800%. The segmented copolymer comprising the β-alanine based bisoxalamide hard segment with a spacer of 6 methylene groups has a melting transition of 141 °C which is higher than the melting transition of its glycine analogue of 119 °C. Likewise, the fracture stress increased from 22 to 31 MPa when the glycine ester group in the hard segment was replaced with β-alanine. The improved thermal and mechanical properties of the latter polymers is related to the crystal packing of the β-alanine based hard segments in the copolymer compared to the packing of the hard segments comprising glycine ester groups. 相似文献
115.
116.
Murphy K van Ginneken B Reinhardt JM Kabus S Ding K Deng X Cao K Du K Christensen GE Garcia V Vercauteren T Ayache N Commowick O Malandain G Glocker B Paragios N Navab N Gorbunova V Sporring J de Bruijne M Han X Heinrich MP Schnabel JA Jenkinson M Lorenz C Modat M McClelland JR Ourselin S Muenzing SE Viergever MA De Nigris D Collins DL Arbel T Peroni M Li R Sharp GC Schmidt-Richberg A Ehrhardt J Werner R Smeets D Loeckx D Song G Tustison N Avants B Gee JC Staring M Klein S Stoel BC Urschler M 《IEEE transactions on medical imaging》2011,30(11):1901-1920
EMPIRE10 (Evaluation of Methods for Pulmonary Image REgistration 2010) is a public platform for fair and meaningful comparison of registration algorithms which are applied to a database of intrapatient thoracic CT image pairs. Evaluation of nonrigid registration techniques is a nontrivial task. This is compounded by the fact that researchers typically test only on their own data, which varies widely. For this reason, reliable assessment and comparison of different registration algorithms has been virtually impossible in the past. In this work we present the results of the launch phase of EMPIRE10, which comprised the comprehensive evaluation and comparison of 20 individual algorithms from leading academic and industrial research groups. All algorithms are applied to the same set of 30 thoracic CT pairs. Algorithm settings and parameters are chosen by researchers expert in the configuration of their own method and the evaluation is independent, using the same criteria for all participants. All results are published on the EMPIRE10 website (http://empire10.isi.uu.nl). The challenge remains ongoing and open to new participants. Full results from 24 algorithms have been published at the time of writing. This paper details the organization of the challenge, the data and evaluation methods and the outcome of the initial launch with 20 algorithms. The gain in knowledge and future work are discussed. 相似文献
117.
The effectiveness of ozone treatment for the afterclearing of disperse dyed poly (ethylene terephthalate) (PET) fibers has been examined. Two types of disperse dyed PET samples were selected among commercial mass production range of Akbaslar textile mill. The reduction clearing procedure applied during mass production was taken as the reference reduction clearing treatment; these reference samples were taken after dyeing and reduction clearing processes at the mill. Samples of disperse dyed PET were also taken before reduction clearing in order apply ozone treatment in the laboratory as the tested afterclearing method. Color and wash-fastness properties of the reduction cleared and ozone treated fabric samples were compared and reported. Results indicated acceptable color and wash-fastness results comparable to those of reduction cleared samples for ozone treated samples. The success of ozone treatment for the black dyed PET sample at 7.0% depth of shade was especially outstanding. Ozone treatment was applied in cold water without addition of any chemicals for very short treatment times when compared to conventional reduction clearing. Ozone treatment created substantial energy and chemical savings as well as lower environmental impact. 相似文献
118.
Membranes are vital structures for cellular life forms. As thin, hydrophobic films, they provide a physical barrier separating the aqueous cytoplasm from the outside world or from the interiors of other cellular compartments. They maintain a selective permeability for the import and export of water-soluble compounds, enabling the living cell to maintain a stable chemical environment for biological processes. Cell membranes are primarily composed of two crucial substances, lipids and proteins. Bacterial membranes can sense environmental changes or communication signals from other cells and they support different cell processes, including cell division, differentiation, protein secretion and supplementary protein functions. The original fluid mosaic model of membrane structure has been recently revised because it has become apparent that domains of different lipid composition are present in both eukaryotic and prokaryotic cell membranes. In this review, we summarize different aspects of phospholipid domain formation in bacterial membranes, mainly in Gram-negative Escherichia coli and Gram-positive Bacillus subtilis. We describe the role of these lipid domains in membrane dynamics and the localization of specific proteins and protein complexes in relation to the regulation of cellular function. 相似文献
119.
Eva Pellicer Moisés Cabo Emma Rossinyol Pau Solsona Santiago Suriñach Maria Dolors Baró Jordi Sort 《Advanced functional materials》2013,23(7):900-911
Transition metal (Co, Fe, Mn)‐doped In2O3?y mesoporous oxides are synthesized by nanocasting using mesoporous silica as hard templates. 3D ordered mesoporous replicas are obtained after silica removal in the case of the In‐Co and In‐Fe oxide powders. During the conversion of metal nitrates into the target mixed oxides, Co, Fe, and Mn ions enter the lattice of the In2O3 bixbyite phase via isovalent or heterovalent cation substitution, leading to a reduction in the cell parameter. In turn, non‐negligible amounts of oxygen vacancies are also present, as evidenced from Rietveld refinements of the X‐ray diffraction patterns. In addition to (In1?xTMx)2O3?y, minor amounts of Co3O4, α‐Fe2O3, and MnxOy phases are also detected, which originate from the remaining TM cations not forming part of the bixbyite lattice. The resulting TM‐doped In2O3?y mesoporous materials show a ferromagnetic response at room temperature, superimposed on a paramagnetic background. Conversely, undoped In2O3?y exhibits a mixed diamagnetic‐ferromagnetic behavior with much smaller magnetization. The influence of the oxygen vacancies and the doping elements on the magnetic properties of these materials is discussed. Due to their 3D mesostructural geometrical arrangement and their room‐temperature ferromagnetic behavior, mesoporous oxide‐diluted magnetic semiconductors may become smart materials for the implementation of advanced components in spintronic nanodevices. 相似文献
120.
An experimental study was conducted to determine the dependence of the burning rate coefficient of gel fuel droplets on the pressure at different ambient oxygen nitrogen mixtures. Experiments were conducted using a pressure chamber, in which the droplet was suspended and the combustion process was video‐photographed by a high‐speed digital video camera. The tests were conducted at pressures between 0.1–4 MPa at different ambient oxygen nitrogen compositions (air, 40 % O2 – 60 % N2, and 60 % O2 – 40 % N2). The fuel was a compound of 95 % kerosene and 5 % gellant. At sub‐critical pressure conditions, the burning rate coefficient was found to increase with increasing ambient oxygen mass fraction. At supercritical conditions, no dependence of the burning rate coefficient on the ambient mixture was found. The results indicate that the burning rate coefficient depends on the oxygen partial pressure, at least at low pressures. 相似文献