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101.
Conductive heat transfer plays an important role in dissipating thermal energy to achieve lower operating temperatures in various devices. Topology optimization has the potential to provide efficient structural solutions for such devices. The traditional topology optimization approach considers a single material. Adding additional materials with unique properties not only can expand the design options but also may improve the structural performance of the final structure. In this work, a multi-resolution topology optimization approach is employed to design multi-material structures for efficient heat dissipation. The implementation blends an efficient multi-resolution approach to obtain high-resolution designs with an alternating active phase algorithm to handle multi-material giving greater design flexibility. It solves the steady-state heat equation using finite element analysis and iteratively minimizes thermal compliance (maximizes conductivity). Several examples are presented to show the efficacy of the numerical implementation, which involves benchmark problems. Results indicate good prospects when quantitatively compared with single-material structures.  相似文献   
102.
The manipulation of single magnetic molecules may enable new strategies for high-density information storage and quantum-state control. However, progress in these areas depends on developing techniques for addressing individual molecules and controlling their spin. Here, we report success in making electrical contact to individual magnetic N@C(60) molecules and measuring spin excitations in their electron tunnelling spectra. We verify that the molecules remain magnetic by observing a transition as a function of magnetic field that changes the spin quantum number and also the existence of non-equilibrium tunnelling originating from low-energy excited states. From the tunnelling spectra, we identify the charge and spin states of the molecule. The measured spectra can be reproduced theoretically by accounting for the exchange interaction between the nitrogen spin and electron(s) on the C(60) cage.  相似文献   
103.
Supported liquid membranes are used here to establish steady-state concentration profiles across ion-selective membranes rapidly and reproducibly. This opens up new avenues in the area of nonequilibrium potentiometry, where reproducible accumulation and depletion processes at ion-selective membranes may be used to gain valuable analytical information about the sample. Until today, drifting signals originating from a slowly developing concentration profile across the ion-selective membrane made such approaches impractical in zero current potentiometry. Here, calcium- and silver-selective membranes were placed between two identical aqueous electrolyte solutions, and the open circuit potential was monitored upon changing the composition of one solution. Steady state was reached in approximately 1 min with 25-microm porous polypropylene membranes filled with bis(2-ethylhexyl) sebacate doped with ionophore and lipophilic ion exchanger. Ion transport across the membrane resulted on the basis of nonsymmetric ion-exchange processes at both membrane sides. The steady-state potential was calculated as the sum of the two membrane phase boundary potentials, and good correspondence to experiment was observed. Concentration polarizations in the contacting aqueous phases were confirmed with stirring experiments. It was found that interferences (barium in the case of calcium electrodes and potassium with silver electrodes) induce a larger potential change than expected with the Nicolsky equation because they influence the level of polarization of the primary ion (calcium or silver) that remains potential determining.  相似文献   
104.
As more than 50% construction and demolition (C&D) wastes are composed of concrete debris in Hong Kong, recycling this debris into Recycled Aggregate (RA) for production of Recycled Aggregate Concrete (RAC) is an efficient way to alleviate the burden on landfill areas. Since RA is generated from concrete debris which has undergone years of services, the resulting RAC bears the weaknesses of lower density, higher water absorption, and higher porosity that limit them to lower-grade applications. Pinpointing to these weaknesses, Tam et al. [2005, Cement Concrete Res 35(6):1195–1203] developed the Two-Stage Mixing Approach (TSMA) for improving the strength of RAC, leading to the possibility in applying RAC for higher-grade applications. While the improvement in strength by TSMA has been proven in Tam et al.’s work [2005, Cement Concrete Res 35(6):1195–1203], the durability, in terms of deformation (shrinkage and creep) and permeability (water, air and chloride permeability), remains to be verified. In this paper, 0%, 20% and 100% of RA substitutions have been experimented to compare the durability performance of the Normal Mixing Approach (NMA) and the TSMA. Experiment results highlight that: (i) the higher the substitutions of RA, the weaker the performance of RAC; and (ii) the deformation and permeability of RAC can be enhanced when adopting TSMA. Therefore, it demonstrates that TSMA can help to improve the durability of RAC, on top of the previously verified strength improvement, and thus opening up wider applications of RAC.  相似文献   
105.
The price of computers is a key factor in explaining the growth of computer spending. However, it remains unclear whether the price elasticity of the demand for computers is constant over time. Findings on the pattern of price elasticity will have important implications in the study of information technology (IT) innovation diffusion. To test the hypothesis of dynamic price elasticity, we extend existing growth models to include a price factor with different elasticity specifications. Nested specifications of three growth models were tested using spending data from 1955 to 1984 adjusted by a quality price index for computers. The results indicate that three out of four competing models depict dynamic price elasticity over the investigated period. A similar pattern is also observed when the models are estimated using more recent data on mainframe computer spending. Our results underscore the dynamic behavior of price sensitivity in computer spending over time. They offer a new perspective to study innovation attributes and to examine their impacts empirically over time. Implications for information systems (IS) management and IT suppliers are also discussed  相似文献   
106.
Film archives are continuously in need of automatic restoration tools to accelerate the correction of film artifacts and to decrease the costs. Blotches are a common type of film degradation and their correction needs a lot of manual interaction in traditional systems due to high false detection rates and the huge amount of data of high resolution images. Blotch detectors need reliable motion estimation to avoid the false detection of uncorrupted regions. In case of erroneous detection, usually an operator has to remove the false alarms manually, which significantly decreases the efficiency of the restoration process. To reduce manual intervention, we developed a two-step false alarm reduction technique including pixel- and object-based methods as post-processing. The proposed pixel-based algorithm compensates motion, decreasing false alarms at low computational cost, while the following object based method further reduces the residual false alarms by machine learning techniques. We introduced a new quality metric for detection methods by measuring the required amount of manual work after the automatic detection. In our novel evaluation technique, the ground truth is collected from digitized archive sequences where defective pixel positions are detected in an interactive process.  相似文献   
107.
Heating of the Er/Yb-codoped fiber lasers due to strong pump absorption was found to cause large frequency fluctuation in addition to lasing wavelength shift. Laser frequency fluctuation of up to 1.7 GHz was measured by using an absorption line of an acetylene gas cell. The large frequency fluctuation was reduced to less than 80 MHz with proper cooling of the laser  相似文献   
108.
Examined the effects of Kinder Training on selected kindergarten and first grade students' behavior, social skills, and early literacy skills, as well as its effects on teacher behavior in the classroom. Kinder Training involves the teacher in play sessions with a child who is exhibiting discouragement in the classroom. The participants in this study included 7 kindergarten teachers, 4 kindergarten paraprofessionals, 3 first grade teachers, and their 14 selected students (median age 5 yrs, 9 mo). The teacher conducts play sessions while receiving supervision from a counselor, learning skills that are both appropriate for the playroom and valuable for the classroom. As a result of the play sessions, the teacher–student relationship is enhanced, the student feels more encouraged in the classroom, and the teacher transfers the newly obtained skills to his or her work with other students. This transfer included an increase in facilitative statements, encouragement, and limit-setting. Additionally, the teachers decreased the number of praise statements and ineffective limit-setting. The results suggest that Kinder Training is an effective intervention for struggling students and a successful proactive approach for teacher skill development. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
109.
The thermodynamic properties of metals and alloys are studied using the moment method in the statistical dynamics, which allows us to take into account the anharmonicity of thermal lattice vibrations and size mismatch of constituent atoms, going beyond the quasi-harmonic approximation. Within the fourth-order moment approximation, the free energy and equilibrium lattice spacing of the binary alloys are given explicitly in terms of the effective pair potentials and the second- and fourth-order vibrational constants. The long-range order (LRO) parameter η and order-disorder transition temperatures (ODTs) Tc of binary alloys are obtained by solving the explicit transcendental equations. The numerical calculations of thermodynamic quantities for Cu3Au and β-CuZn alloys show that the inclusion of the anharmonicity of lattice vibration plays an essentially important role in determining the phase stabilities of metals and alloys.  相似文献   
110.
Power management holds the key to over $400 billion annual savings in electrical energy and is relieving critical bottlenecks in the Internet backbone, Internet appliances and portable electronics. The latest analog integrated circuits and power semiconductors are enabling these improvements. This paper focuses on these leading-edge devices, used in conjunction with innovative architectures. The authors examine future trends in silicon-based power transistors and diodes and discuss how the changing requirements of end users are driving new analog ICs, as well as different power management architectures. Trends in architecture for DC-DC power conversion and motion control set the stage for improvements needed and planned in the power management products over the next several years. They examine various technologies for analog ICs and their interface with the digital world. They also compare the pros and cons of different techniques and levels of “power-plus-control integration”. The discussion on power MOSFETs (including IGBTs) focuses on performance and technology trends in DC-DC power conversion and motion control. State-of-the-art and future device topologies are presented. The future of diodes is also discussed. DC-DC conversion and motion control is the context. State of the art and future device topologies are presented. Less than 25% of all the world's electricity is efficiently managed. Roadmaps must focus not only on making existing applications more efficient and cost-effective, but also on enabling the new applications that can address the remaining 75%  相似文献   
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