稀土钕对激光快速成形TC4合金组织及性能的影响

针对氢化脱氢钛合金粉末氧含量较高的问题，研究了添加稀土钕对激光快速成形TC4合金组织及性能的影响。结果发现，添加稀土Nd后，激光快速成形TC4合金的宏观晶粒尺寸变化不大；但随稀土添加量的增加，初始β列状晶逐渐转化为全β等轴晶，晶粒内部的魏氏α组织逐渐转变为网篮α，粗化α条不断增多，呈现团束聚集趋势，晶界α集束体积分数也不断增大；随稀土添加量的增加，激光快速成形TC4合金的室温塑性先大幅度提高，然后急剧降低；稀土添加量为0．1％～0．2％（质量分数，下同）时，氧含量为0．26％的氢化脱氢TC4合金粉末激光快速成形件沉积态的抗拉强度达975MPa，延伸率9．5％，满足锻件标准要求。     

Facile synthesis of nitrogen and oxygen co-doped hierarchical porous carbon materials for high performance super capacitors

Journal of Porous Materials - Nitrogen and oxygen co-doped hierarchical porous carbons (NOPCs) is prepared by the pyrolysis of polyethylene glycol-200 (PEG) and triazine carbon forming agent (CFA)...     

稀土对ZA27合金阻尼性能的影响

研究了稀土对ZA27合金阻尼性能的影响规律。结果表明：稀土变质可提高ZA27合金的阻尼性能，经稀土变质后的试样，其内耗是未变质的试样的1．4倍。ZA27合金为发挥其阻尼作用，在频率高于70Hz时，效果明显，且经稀土变质后的试样强迫振动衰减效果比未变质的试样强。     

Effects of microlens array orientation errors on plenoptic imaging of flame radiative properties and uncertainty analysis

Science China Technological Sciences - Plenoptic imaging (PI) systems can flexibly record both spatial and angular information on flame radiation, enabling volumetric reconstruction of complex...     

Photocatalytic syngas synthesis from CO2 and H2O using ultrafine CeO2-decorated layered double hydroxide nanosheets under visible-light up to 600 nm

The rational design of photocatalyst that can effectively reduce CO₂ under visible light(l>400 nm),and simultaneously precise control of the products syngas(CO/H2)ratio is highly desirable for the Fischer-Tropsch reaction.In this work,we synthesized a series of CeO₂-decorated layered double hydroxides(LDHs,Ce-x)samples for photocatalytic CO₂ reduction.It was found that the selectivity and productivity of CO and H₂ from photoreduction of CO₂ in conjunction with Ru-complex as photosensitizer performed an obvious“volcano-like”trend,with the highest point at Ce-0.15 and the CO/H₂ ratio can be widely tunable from 1/7.7 to 1/1.3.Furthermore,compared with LDH,Ce-0.15 also drove photocatalytic CO₂ to syngas under 600 nm irradiation.It implied that an optimum amount of CeO₂ modifying LDH promoted the photoreduction of CO₂ to syngas.This report gives the way to fully utilize the rare earth elements and provides a promising route to enhance the photo-response ability and charge injection efficiency of LDH-based photocatalysts in the synthesis of syngas with a tunable ratio under visible light irradiation.     

Design,Synthesis, and Biological Evaluation of Novel 6H-Benzo[c]chromen-6-one Derivatives as Potential Phosphodiesterase II Inhibitors

Urolithins (hydroxylated 6H-benzo[c]chromen-6-ones) are the main bioavailable metabolites of ellagic acid (EA), which was shown to be a cognitive enhancer in the treatment of neurodegenerative diseases. As part of this research, a series of alkoxylated 6H-benzo[c]chromen-6-one derivatives were designed and synthesized. Furthermore, their biological activities were evaluated as potential PDE2 inhibitors, and the alkoxylated 6H-benzo[c]chromen-6-one derivative 1f was found to have the optimal inhibitory potential (IC₅₀: 3.67 ± 0.47 μM). It also exhibited comparable activity in comparison to that of BAY 60-7550 in vitro cell level studies.     

Supplementation with Docosahexaenoic Acid and Vitamin E Improves Hepatic Triglyceride Accumulation Induced by High-Fat Diet in Mice

The study aims to investigate the effect of combined supplementation with docosahexaenoic acid (C22:6 n-3, DHA) and vitamin E (VE) on the oxidative stress and liver triglycerides (TG) accumulation induced by high-fat diet (HFD) in mice. C57BL/6J mice are fed either a control diet or an HFD for 8 weeks. Animals are supplemented with DHA, VE, or DHA + VE, respectively. Supplementation with DHA alone shows significant improvement in oxidative stress and hepatic steatosis in mice. Supplementation with DHA significantly reduces the liver TG and total cholesterol contents, and the alanine aminotransferase (ALT) and aspartate aminotransferase (AST) levels, compared with the HFD. Supplementation with DHA also significantly decreases the mRNA expression level of sterol regulatory element-binding protein 1C. However, supplementation with VE alone does not show improvement in oxidative stress and hepatic steatosis. DHA + VE supply obtains a superior effect in alleviation of hepatic steatosis than DHA supplementation alone in mice fed by HFD. The efficacy of DHA potentiated by VE can be due to that VE enhances the effect of DHA in decrease of ALT and AST levels and increase of antioxidant enzyme activity and glutathione level in mice fed by HFD. Practical Applications: Supplementation with DHA significantly improves the oxidative stress and hepatic steatosis induced by HFD in mice. The efficacy of DHA in the alleviation of hepatic steatosis induced by HFD is potentiated by VE. These findings may provide a rational basis for the use of DHA and VE co-supplementation in patients with liver steatosis.     

磷石膏提质降杂实验研究

磷石膏的综合利用对保护环境、促进企业可持续健康发展具有重要意义,但是磷石膏中的磷、氟、二氧化硅等杂质影响其利用。针对云南磷石膏中二氧化硅含量高的问题,采用正浮选工艺开展了磷石膏提质降杂的实验研究。通过单因素条件实验获得了合适的工艺参数：浮选温度为15 ℃、矿浆pH为2、十二胺用量为300 g/t。在此条件下,进行了“一粗二精”的正浮选开路流程实验,获得了二水石膏（CaSO₄·2H₂O）质量分数为97.5%、二氧化硅质量分数为1.17%的精矿,所得精矿达到了GB/T 23456—2018《磷石膏》一级品指标的要求;二水石膏回收率为98.58%、二氧化硅去除率为92.23%。通过正浮选不仅成功实现了二水石膏和二氧化硅的有效分离,而且磷石膏中的水溶磷和水溶氟也得到了有效去除,从而提高了磷石膏的品质。     

Studying the formation process of chromate conversion coatings on aluminium using continuous electrochemical noise resistance measurements

A unique electrochemical technique, namely continuous noise resistance calculation (CNRC), was used to obtain electrochemical kinetic information from the formation process of chromate conversion coatings (CCC) on aluminium electrodes. It was found that the noise resistance (R_n) of aluminium electrodes remained almost unchanged during electrodes' immersion in a chromate containing acidic solution where the CCC films were supposed to form rapidly. This result indicates that the formation of CCC was associated with continuous corrosion of the aluminium electrodes and that the CCC films formed on aluminium surface were not intact barrier films, but most likely porous layers. The CCCs became protective only after they were aged in the environment. Based on these findings, the formation and inhibition mechanisms of CCC have been discussed.     

高纯钛的反复弯曲疲劳

通过对不同应力幅度下高纯钛的反复弯曲疲劳的研究，发现在较低应力幅度下（～±１００ＭＰａ），材料表现出循环软化，伴随表面滑移带数量的增加、发达的滑移带挤出片的出现。疲劳裂纹萌生主要与滑移带相关，在挤出物内存在两类疲劳损伤形式：沿滑移带的孔洞和与滑移带垂直的微裂纹。在较高应力幅度下（～±２００ＭＰａ），则表现为硬化，次滑移及晶界附近多个滑移系同时起动，有大的形变孪晶出现。裂纹于滑移带、李晶界和晶界结点萌生。断口特征复杂，但与表面变形特征有对应关系。ＴＥＭ亚结构分析表明，随应力幅度的提高，位错组态分别为散乱分布于滑移面的偶极子、位错束带和位错胞。李晶内存在复杂的精细结构，而且有堆垛层错出现。