Synthesis and Polymerization of Cationic bis(cyclopentadienyliron)arene Complexes Containing Arylazo Dyes

The synthesis of the title complexes was achieved via the reaction of -p-dichlorobenzene- -cyclopentadienyliron cations with 4,4′-bis(4-hydroxyphenyl)valeric acid to produce the diiron complexes which were then reacted with a number of arylazo dyes to give cationic bis(cyclopentadienyliron)arene complexes containing the arylazo dyes. These iron-containing monomers were subsequently polymerized via nucleophilic aromatic substitution using 1,8-octanedithiol, 4,4′-thiobisbenzenethiol, or bisphenol A to produce the desired coloured cationic organoiron polymers. The weight – average molecular weights were estimated to range from 11,800 to 31,600. UV–vis studies conducted in dimethylformamide (DMF) showed that the metallated polymers exhibited of 412–491 nm. Addition of HCl to the polymer solution caused a bathochromic shift into the range of 515–530 nm. Thermogravimetric analysis (TGA) revealed that the iron moieties were cleaved between 205 and 248 °C while the polyether/thioether backbone degraded between 380 and 613 °C. Differential scanning calorimetry (DSC) showed that the polymers exhibited glass transition temperatures (Tg) ranging from 106 to 184°C.This paper is dedicated to Professor Richard J. Puddephatt in recognition of his outstanding contribution to the field of metal-containing polymers.     

Synthesis and thermal cure of high molecular weight polybenzoxazine precursors and the properties of the thermosets

High molecular weight polybenzoxazine precursors have been synthesized from aromatic or aliphatic diamine and bisphenol-A with paraformaldehyde. The precursors were obtained as soluble white powder. Molecular weight was estimated from the size exclusion chromatography to be several thousands. The structure of the precursors was confirmed by IR, ¹H NMR and elemental analysis, indicating the presence of cyclic benzoxazine structure. The ratio of the ring-closed benzoxazine structure and the ring-opened structure in the high molecular weight precursor was estimated from ¹H NMR spectrum and also from the exotherm of DSC, showing that the ratio of the ring-closed benzoxazine structure was 77–98%. The precursor solution was cast on glass plate, giving transparent and self-standing precursor films, which was thermally cured up to 240 °C to give brown transparent polybenzoxazine films. The toughness of the crosslinked polybenzoxazine films from the high molecular weight precursors was greatly enhanced compared with the cured film from the typical low molecular weight monomer. Tensile measurement of the polybenzoxazine films revealed that polybenzoxazine from aromatic diamine exhibited the highest strength and modulus. While, polybenzoxazine from longer aliphatic diamine had higher elongation at break. The viscoelastic analyses showed that the glass transition temperature of the polybenzoxazines derived from the high molecular weight precursors were as high as 238–260 °C. Additionally, these novel polybenzoxazine thermosets showed excellent thermal stability.     

Nutritional and physicochemical evaluations of tahina (sesame butter) prepared from heat‐treated sesame seeds

Dehulled sesame seeds were roasted using different heat treatments. The effects of roasting treatments on the nutritive value, physicochemical properties and sensory properties of produced tahina were studied. Resultant tahina contained 586–594 g kg⁻¹ crude oil, 219–226 g kg⁻¹ crude protein and <30 g kg⁻¹ crude fibre and ash. Crude protein, crude fibre, ash and N‐free extract in tahina samples were not affected by roasting treatments. However, crude oil was decreased by steam roasting and hot plate roasting. Hot plate roasting was more effective in reducing raffinose content than other roasting treatments, whereas vacuum roasting was less effective in reducing raffinose content than other roasting treatments. Tahinas were good sources of essential amino acids, especially sulphur‐containing amino acids, aromatic amino acids and tryptophan. Hot air roasted tahina followed by vacuum roasted tahina had higher total essential amino acid contents than steam roasted and hot plate roasted tahinas. Lysine was the first limiting amino acid in tahinas. Tahinas had a relatively high in vitro protein digestibility (over 83%). Tahina is a good source of niacin. Hot air roasted tahina had the highest content of B group vitamins compared with other tahina samples. Resultant tahinas had relatively high amounts of Na, Mg, K, Cu, Zn and Fe and a low amount of Ca. Roasting treatments did not affect the mineral contents. All roasted samples had a typical protein spectrum with a maximum absorption at 280 nm and minimum at 260 nm. However, the spectrum of hot air roasted tahina proteins was sharper than the spectra of other tahina proteins. Size exclusion HPLC fractionated tahina proteins into two fractions for hot roasted and vacuum roasted tahinas and three fractions for steam roasted and hot plate roasted tahinas. The gel filtration pattern of tahina proteins contained four peaks with identical elution volumes but different proportions. Hot air roasted and vacuum roasted tahinas had higher panel scores than steam roasted and hot plate roasted tahinas for all tested sensory properties. © 2000 Society of Chemical Industry     

Rigorous Full-Wave Analysis of Rectangular Microstrip Patch Antenna on Suspended and Composite Substrates

In this paper, Galerkin’s method in the Fourier transform domain is applied to the determination of the resonant frequencies and half-power bandwidth of rectangular microstrip patch on composite and suspended substrates. Using Galerkin’s method in solving the integral equation numerically, the complex resonant frequency of the microstrip antenna on suspended and composite substrates is studied with sinusoidal functions as basis functions, which show fast numerical convergence. The validity of the solution is tested by comparison of the computed results with experimental data. Finally, numerical results for the effects of suspended and composite substrates on the resonant frequency and half-power bandwidth are also presented.     

Comments on solid state hydrogen storage systems design for fuel cell vehicles

In recent years, significant research and development efforts were spent on hydrogen storage technologies with the goal of realizing a breakthrough for fuel cell vehicle applications. This article scrutinizes design targets and material screening criteria for solid state hydrogen storage. Adopting an automotive engineering point of view, four important, but often neglected, issues are discussed: 1) volumetric storage capacity, 2) heat transfer for desorption, 3) recharging at low temperatures and 4) cold start of the vehicle. The article shall help to understand the requirements and support the research community when screening new materials.     

CFD Simulations of Pool Fires in a Confined and Ventilated Enclosure Using the Peatross–Beyler Correlation to Calculate the Mass Loss Rate

The aim of this paper is to analyse the application of the Peatross–Beyler (P&B) correlation (Fire and safety science—Proceedings of the fifth international symposium, 1997) to calculate the Mass loss rate (MLR) for a pool fire in a confined and ventilated enclosure for a range of conditions.The experimental references considered are the PRISME-SI-D1, D2 and D6 tests (Prétrel et al. in 9th International seminar on fire safety in nuclear power plants and installations, 2005), conducted by the Institut de Radioprotection et de Sûreté Nucléaire.The dimensions of the enclosure used in the experiment are 5 m in length, 6 m in width and 4 m in height. A pool fire, (0.4,hbox {m}^2) hydrogenated tetrapropylene (TPH, (hbox {C}_{12}hbox {H}_{26})), is located in the center of the room. The compartment is connected to the outside through an inlet and outlet. The P&B correlation is implemented as a boundary condition in computational fluid dynamics calculations. The MLR outcome depends on the average (hbox {O}_2) concentration in a predefined volume and the characteristics of the fuel. The influence of the size and location of the predefined volume, the ventilation branch position (at 1 m and 3.65 m from the floor) and the Renewal Rate ((R_r)) ((4.7,hbox {h}^{-1}) and (8.4,hbox {h}^{-1})) are studied. Two types of (hbox {O}_2) predefined volumes have been tested: layer and ring. The layer volume is located in the low part of the compartment, the base of the volume spanning the compartment floor. The ring is a volume around the pit. It is assumed for both approaches that the measured (hbox {O}_2) is representative of the available oxygen for the flame. The P&B boundary condition predicts the influence of the vitiation on the MLR. Other methods, such as imposing the MLR expected in open condition, overpredict the amount of injected fuel. The results show that the P&B correlation provides good agreement with the experimental data. The deviation between experimental data and numerical prediction for the average MLR in the best case is ?5.0% with absolute values of 0.004 kg/s and 0.0038 kg/s for the experiment and the simulation respectively for case PRS-SI-D1. The MLR calculation is influenced by the position of the ventilation opening and the (R_r). The temperature and (hbox {O}_2) concentration profiles are significantly influenced by the ventilation configuration. These differences are related to the transport of the injected air from the inlet to the floor by density difference.     

Immobilization of recombinant strains of Saccharomyces cerevisiae for the hydrolysis of lactose in salted Domiati cheese whey

Intergeneric protoplast fusants SK-26 and SK-35 between Saccharomyces cerevisiae ATCC 4126 and Kluyveromyces lactis CBS 683 produced 2.70 ml dl^-1 and 1.52 ml dl^-1 (v/v) of ethanol during fermentation of lactose at 25vv°C in salted Domiati cheese whey containing 6.1 g dl^-1 (w/v) NaCl when entrapped in alginate spheres, whereas the free recombinant cells produced 2.36 ml dl^-1 and 1.09 ml dl^-1 (v/v) of ethanol. Yeast hybrids spheres can be used nine times with accumulated increases of ethanol production of 9.1 ml dl^-1 and 8.98 ml dl^-1 (v/v), respectively.     

Guest Editorial: Flexible-Joint and Flexible-Link Robots

Editorial Introduction

Guest Editorial: Flexible-Joint and Flexible-Link Robots