Thermodynamic screening of suitable oxygen carriers for a three reactor chemical looping reforming system

Hydrogen (H₂) production by using a three reactor chemical looping reforming (TRCLR) technology is an innovative process which utilizes fossil fuels as feed stocks. This process occurs in three steps by employing an oxygen carrier (OC), which is generally a transition metal. As the OC plays an important role, its selection should be done after carefully considering the chemical and physical properties of the material. In this study, various candidate materials for use in a TRCLR process, with methane (CH₄) as a fuel stock, were investigated. The results show that the iron (Fe)- and molybdenum (Mo)-based OCs oxidize CH₄ completely in the FR at low temperatures. In terms of H₂ yield, tungsten (W)-based OCs produce the highest yield, ～3.9 mol-H₂/mol-CH₄. The equilibrium oxygen partial pressures and the solid circulation rates are the highest for Fe-based OCs. The oxygen carrying capacity of Fe-based OCs is relatively high while its price is low. Therefore, among the OCs investigated, Fe-based OCs were identified as the preferred OC option for a TRCLR process.     

A Novel Algebraic Technique for the Construction of Strong Substitution Box

Magnetic induction applications mostly rely on resonance for inducing maximum magnetic fields to system loads and hence for each resonant frequency dedicated circuits are required. Unfortunately, the frequency responses of such inductive systems manifest several peaks (frequency splitting) when their coupling coefficients are equal to or larger than critical coupling. Such frequency responses with several peaks are detrimental when the objective is to transfer maximum energy. Frequency splitting between inductive coils have been seen to date as detrimental to wireless power transfer and inductive communication systems. In this paper it is demonstrated that frequency splitting is a welcome phenomenon with advantage in the design of inductive filter banks and multi-frequency inductive systems. The centre frequencies of the filter banks result from split bands of inductive systems. This phenomenon is applied in conjunction with an innovative recursive algorithm to design inductive filter banks. The filters straddle both sides of the resonant frequency position and can be resolved individually.     

Influence of metal‐oxide‐supported bentonites on the pyrolysis behavior of polypropylene and high‐density polyethylene

In this article, we report on the pyrolysis of polypropylene (PP) and high‐density polyethylene (HDPE) in the absence and presence of plain and metal‐oxide‐impregnated bentonite clays [BCs; acid‐washed bentonite clay (AWBC), Zn/AWBC, Ni/AWBC, Co/AWBC, Fe/AWBC, and Mn/AWBC] into useful products. Thermal and catalytic runs were performed at 300°C in the case of PP and at 350°C in the case of HDPE for a contact time of 30 min. The effects of different catalysts and their concentrations on the overall yields and the yields of liquid, gas, and residue were studied. The efficacy of each catalyst is reported on the basis of the highest liquid yields (in weight percentage). The derived liquid products were analyzed by Fourier transform infrared spectroscopy and gas chromatography–mass spectroscopy; this confirmed the presence of paraffins, olefins, and naphthenes. The results indicate the catalytic role of impregnated BCs compared to plain BC with the optimum efficiency shown by Co/AWBC in the case of PP and Zn/AWBC in the case of HDPE toward the formation of liquid products in a desirable C range with the enrichment of olefins and naphthenes in the case of PP and paraffins and olefins in the case of HDPE compared to the thermal run. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41221.     

The study of welded semi‐rigid connections in fire

Considering the deterioration of steel properties by temperature increase and the importance of the influence of connection behavior on the behavior of steel structures, we find that the exact understanding of the behavior of a specific steel connection in fire as well as the information about the effect of fire on the principal constitutive characteristics of the connection is necessary for safe design against fire. Thus, in this paper, the behavior of welded angle connections is studied at elevated temperatures using the abaqus finite element software. Steel members and connection components are considered to behave nonlinearly; the degradation of steel properties with increasing temperature is considered according to EC3, BS5950 recommendations. The results of finite element and experimental tests conducted on welded angle connections are compared, and the obtained failure modes and moment–rotation–temperature characteristics are in good agreement with those associated with the experimental tests. In the following, since the knowledge about moment–temperature–rotation behavior of a specific connection is needed for a fire‐resistant design, these properties are accurately determined, and finally, the effect of some parameters such as the moment applied on beam, change of column axial force and change of beam shear force on the stiffness of these connections at elevated temperatures is determined. Copyright © 2011 John Wiley & Sons, Ltd.     

An ambipolar polymer additive for enhanced open circuit voltage in a bulk heterojunction solar cells

Open circuit voltage (V_OC) of organic bulk heterojunction solar cell is extended by the addition of a 20 wt % of F8TBT, an ambipolar polymer in the active layer matrixes (P3HT:PCBM) and then spin casted (1000 rpm/30 s) in the optimized devices on the PEDOT:PSS layer of the ITO glass. A substantial increase in the open circuit voltage from approximately 0.61–0.88 V (44.26%) has been observed with slight increase in efficiency up to 1.91% in the fabricated devices. However, further increment of F8TBT content to 40 wt % reduces the photovoltaic efficiency and affects the J_SC values remarkably, possibly due the excess amount of resistance developed. The enhancement of V_OC is attributed to the ambipolar nature of F8TBT polymer which facilitates the generated electron and hole transfer at the respective electrodes, enhanced π–π* conjugation in polymer matrix, a superior nanoscale separation, and better molecular conformation at the film interface, thus giving an ample opportunities to explore the impact of blending of materials rather than depositing a thin buffer layer by expensive vapor phase technologies. The details of electrical and microstructure characterization of the film were analyzed by AFM, SEM, UV–Vis, J–V characteristics, and EQE techniques. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43042.     

Simultaneous control of rod length and pore diameter of SBA-15 for PPL loading

Mesoporous silica materials are attractive materials for immobilizing enzymes because of their well-ordered structures, large surface area are pore volume. Diffusion of large enzyme molecules such as porcine pancreatic lipase (PPL) through the lengthy channels of MPS takes place too slowly. Therefore, the squat of the enzyme at the pore mouth entrance, actually makes the rest of the channel useless. In this study, to overcome this problem, synthesis parameters of SBA-15 were changed, since along with pore diameter increasing, the mesochannel length becomes shorter. The main point to obtain a well-ordered 2D hexagonal pore structure was the pre-hydrolysis of tetraethyl orthosilicate (TEOS) before the addition of 1,3,5-trimethyl benzene as a micelle swelling agent. Due to the strong effect of zirconium in changing the morphology of SBA-15 particles, we modified SBA-15 in the presence of a small amount of ZrOCl₂ in the synthesis solution under acidic conditions. As a result, mesochannel length of SBA-15-Zr was shortened from 600 to <200 nm. The morphology of mesoporous silica was also changed from rod-like to platelet, because of the accelerating effect of Zr(IV) on the self-assembly rate of P123 and TEOS condensation. Characteristic results conducted by low angle XRD, high resolution transmission electron microscopy and nitrogen adsorption, confirmed tuning effect of Zr(IV) in SBA-15. Furthermore, it was shown that the number of pore entrances increases with decreasing the length of SBA-15 mesochannels, leading to obvious improvement of enzyme uptake. PPL has been successfully immobilized in the mesoporous channels of SBA-15-Zr. The total amount of lipase adsorbed on the mesoporous SBA-15-Zr was measured by thermal gravimetric analysis. The largest PPL adsorption capacity was 784 mg/g belonging to the SBA-15-Zr with the length of 150 nm and the mean pore size diameter of 9.22 nm.     

Carbon nanotubes growth on sub-surface catalyst layer of Cu–Ni nanoparticles thin film

Cu–Ni nanoparticles (NPs) thin films were prepared by Direct Current (DC) magnetron sputtering with Cu and Ni targets. The products were used as catalysts for Thermal CVD (TCVD) growing of carbon nanotubes (CNTs) from acetylene gas at 825°C. In order to characterize the nano catalysts, X-ray Diffraction (XRD) and Atomic Force Microscopy (AFM) and to study the synthesized CNTs Scanning Electron Microscopy (SEM) and Raman Spectroscopy were applied. A remarkable CNT grown on the sub-surface of catalyst layer compared to its top is deduced from SEM images. Despite the poor catalytic activity of the top-surface, these considerations led us to conclude more catalytic activity of the sub-surface.