固体电介质中空间电荷分布与极化分布的测量方法及其比较

目前有两种主要的固体电介质中空间电荷分布与极化分布的测量方法,压力波法（ＰＷＰ法）与电声脉冲法（ＰＥＡ法）,本文介绍了这两种方法的基本原理与测量技术。用激光感应的压力波法（也叫ＬＩＰＰ法）和用氟聚合物压电薄膜的电声脉冲法对同一个已极化的Ｐ（ＶＤＦＴｒＦＥ）试样进行了极化分布的测量,并对实际测量结果进行了比较与讨论。     

High-voltage testing on UHV equipment: Overshoot and base curve for oscillating lightning impulse

As the higher impulse testing voltage, residual inductance of the test circuit or the stray capacitance of the test object increases with size. This means that the overshoot superposed on standard lightning impulse voltage would not be neglected because of its larger value during the lightning test. This paper describes the analysis of overshoot and oscillation based on the equivalent circuit containing a residual inductance. The waveform parameters such as relative overshoot magnitude, oscillation frequency are also derived to evaluate the influence of the residual inductance in the impulse testing circuit. The oscillating impulse waveform is related to the base curve of the standard lightning impulse. Furthermore, the base curve for oscillating impulse is proposed by the analysis. Copyright © 2009 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

Characterisation of volatile sulphur-containing compounds generated in crushed leaves of Chinese chive (Allium tuberosum Rottler)

To characterise the composition of sulphur-containing constituents in Chinese chive (Allium tuberosum Rottler), GC–MS and HPLC analyses were carried out, using 12 varieties of Chinese origin, 4 varieties of Japanese origin and 6 commercially available cultivars. Five disulphides (dimethyl, allyl methyl, methyl 1-(E)-propenyl, diallyl, and allyl 1-(E)-propenyl), two trisulphides (dimethyl and allyl methyl), and two vinyldithiins (3-vinyl-[4H]-1,2- and 2-vinyl-[4H]-1,3-) were identified on the basis of their mass spectral and GC-retention data. Among the detected sulphur compounds, sulphides with a methyl group predominated over those with an allyl group. This was supported by the HPLC estimations, suggesting that all cultivars examined had much greater amounts of methiin than alliin. Also, two novel compounds were tentatively identified as [3H,4H]-1,2-dithiin and [2H,4H]-1,3-dithiin on the basis of their mass spectral features, GC-retention data, and some experimental results on their formation in reaction mixtures with different proportions of methiin and alliin. Their formation mechanism was proposed.     

Development of a 400 kJ Nb3Sn superconducting magnet for an SMES system

An Nb₃Sn superconducting magnet to store 400 kJ was developed as a unit magnet for a 2.4-MJ SMES system used for stabilization studies of electrical power systems. The superconducting magnet consists of a cryostat and an Nb₃Sn coil. The dimensions of the coil are: 340 mm inner diameter, 700 mm outer diameter and 177 mm axial length. The pool-cooled coil is a stack of 20 Nb₃Sn double pancakes, and the cooling channels are aligned between pancake coils. To reduce Joule loss in electrical power converters, the maximum operating current of the coil is designed to be 350 A, which is one order of magnitude less than the operating currents of similar scale coils for pulse use. The conductor is an Nb₃Sn monolithic conductor with cross section 1.50 × 2.38 mm. For good superconducting stability and high dielectric strength of the coil, the Nb₃Sn double pancakes were wound by the react-and-wind technique. Operation of dc current to 105% (367.5 A) of the design operating current was achieved without quench. After the whole of the coil was exposed out of liquid helium, the coil did not quench under 120 A current operation for more than 2 hours. It was verified that the coil was stable for the SMES system. © 1998 Scripta Technica, Inc. Electr Eng Jpn, 121(3): 44–52, 1997     

Infrared study of catalytic reduction of lean NOx with alcohols over alumina-supported silver catalyst

Two intense IR absorption bands due to surface isocyanate (-NCO) species have been observed at 2262 and 2232 cm^–1 when an alumina-supported silver catalyst is exposed to a mixture of NO, O₂ and ethanol at 150°C and subsequently heated to > 300°C in vacuum. The intensity of the isocyanate band is hardly affected by the water existing in the mixture. Methanol is less reactive than ethanol for the formation of isocyanate species. The reaction mechanism of catalytic reduction of lean NOx with alcohols is discussed based on these IR spectroscopic findings.     

Development of new‐type outdoor termination using composite insulator with SF6 gas: Commercial use for 77‐kV transmission lines and development for 154‐kV XLPE cable

Recently, composite insulators have been increasingly employed mainly for economic reasons. We have developed a new type of outdoor termination using a composite insulator, which can be installed horizontally on a steel tower in order to reduce the construction cost. In this outdoor termination, SF₆ gas is filled in the composite insulator and a cold shrinkable premolded rubber unit is applied instead of the combined use of a rubber‐molded stress relief cone, epoxy resin insulator and spring unit. The application of the composite insulator, SF₆ gas and cold shrinkable premolded rubber unit reduces the total weight and makes it possible to install the termination horizontally on the tower. The new‐type outdoor termination for 77‐kV XLPE cable has already been applied in commercial use and enabled a reduction of the construction costs for power transmission lines. A 154‐kV new‐type outdoor termination has been developed and its initial electrical tests were successfully completed. This paper describes the design and performance of both 77‐kV and 154‐kV new‐type outdoor termination, and a follow‐up survey of the 77‐kV new termination in a commercial use. © 2007 Wiley Periodicals, Inc. Electr Eng Jpn, 159(4): 18– 26, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20511     

TEM,XPS and SIMS Analyzes on Grain Boundary of Lanthanum Chromites

The morphological characteristics, chromium valence state, and cation transport in the vicinity of grain boundary in La_1-xCa_xCrO₃ were investigated by using TEM/EDS, XPS and SIMS techniques. The width of grain boundary was around 1 nm where anomalous enrichment of calcium was observed. Higher valence state of chromium such as Cr⁶⁺(d⁰) was detected in the grain boundaries whereas Cr³⁺(d³) and Cr⁴⁺(d²) were dominant in the bulk. Very fast interdiffusion of alkaline earths was observed in the Sr²⁺-La_0.75Ca_0.25CrO₃ system. All observed phenomena were correlated by assuming the A-site vacancy which may be induced by the formation of Cr⁶⁺ at grain boundaries.     

Ordered Mesoporous Silica Derived from Layered Silicates

Here, the development of ordered mesoporous silica prepared by the reaction of layered silicates with organoammonium surfactants is reviewed. The specific features of mesoporous silica are discussed with relation to the probable formation mechanisms. The recent understanding of the unusual structural changes from the 2D structure to periodic 3D mesostructures is presented. The formation of mesophase silicates from layered silicates with single silicate sheets depends on combined factors including the reactivity of layered silicates, the presence of layered intermediates, the variation of the silicate sheets, and the assemblies of surfactant molecules in the interlayer spaces. FSM‐16‐type (p6mm) mesoporous silica is formed via layered intermediates composed of fragmented silicate sheets and alkyltrimethylammonium (C_nTMA) cations. KSW‐2‐type (c2mm) mesoporous silica can be prepared through the bending of the individual silicate sheets with intralayer and interlayer condensation. Although the structure of the silicate sheets changes during the reactions with C_nTMA cations in a complex manner, the structural units caused by kanemite in the frameworks are retained. Recent development of the structural design in the silicate framework is very important for obtaining KSW‐2‐based mesoporous silica with molecularly ordered frameworks. The structural units originating from layered silicates are chemically designed and structurally stabilized by direct silylation of as‐synthesized KSW‐2. Some proposed applications using these mesoporous silica are also summarized with some remarks on the uniqueness of the use of layered silicates by comparison with MCM‐type mesoporous silica.     

Remote sensing system for spatial electric field strength using free space light transmission

Most of the breakdowns in an electric power system are caused by lightning to the tower used for high‐voltage transmission wires. To avoid accidents due to lightning, it would be desirable to develop a measurement system for the spatial electric field distribution around the tower. We have developed a new system that can measure the electric field around the steel tower for electric power transmission by using an optical electric sensor. In conventional methods, the sensor is generally illuminated by light transmitted by optical fibers. On the other hand, the new measurement system illuminates the Pockels sensor directly by using a laser to measure the far electric field. Furthermore, our newly proposed feedback system makes it possible to measure the spatial electric field without concern for the change of Pockels sensor's operation point influenced by temperature change. This system is applicable as a remote sensing system to monitor the spatial electric field around a high‐voltage transmission line. © 2007 Wiley Periodicals, Inc. Electr Eng Jpn, 162(2): 10–19, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20552