首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   332篇
  免费   11篇
  国内免费   1篇
电工技术   7篇
化学工业   167篇
金属工艺   8篇
建筑科学   5篇
矿业工程   5篇
能源动力   25篇
轻工业   17篇
水利工程   3篇
石油天然气   12篇
无线电   1篇
一般工业技术   50篇
冶金工业   29篇
原子能技术   1篇
自动化技术   14篇
  2023年   4篇
  2022年   37篇
  2021年   31篇
  2020年   11篇
  2019年   13篇
  2018年   20篇
  2017年   8篇
  2016年   5篇
  2015年   10篇
  2014年   20篇
  2013年   19篇
  2012年   25篇
  2011年   13篇
  2010年   12篇
  2009年   12篇
  2008年   16篇
  2007年   10篇
  2006年   9篇
  2005年   7篇
  2004年   12篇
  2003年   6篇
  2002年   8篇
  2001年   2篇
  2000年   6篇
  1999年   4篇
  1998年   2篇
  1996年   3篇
  1995年   5篇
  1994年   2篇
  1993年   1篇
  1992年   1篇
  1991年   2篇
  1989年   1篇
  1988年   1篇
  1986年   2篇
  1985年   1篇
  1970年   1篇
  1968年   1篇
  1966年   1篇
排序方式: 共有344条查询结果,搜索用时 15 毫秒
321.
Abstract

The seismic active zone is a distributed system consisting of various subareas. To understand a state of the system during a given period of time so called ‘the linear gradient frame’ technique was developed to search the stable characteristics for subareas. The search is based on analysis of geographic components, least-squares inversion and statistical estimators of seismic data. The stable subarea includes hypocenters of earthquakes, the space-time trajectories of which are restricted by a certain domain (seismic attractor). Fractal structures obtained in south of Iceland are in an agreement with geological history. The results are promising for the geothermal exploration.  相似文献   
322.
Milling of wear-resistant steel and titanium carbide powders is studied with an attrition mill rotation rate of 980 rpm. The physical and technological properties of powders and particle size are determined. Particle shape and the change in material chemical composition during milling are studied. It is established that steel powder cannot be milled to particle sizes less than 3.6 μm whereas a mixture of steel and titanium carbide can be milled to a fine state (0.3 μm). Powders with a size of about 1 μm neither flow nor are formable. Use of benzene as a milling medium makes it possible to prevent steel powder oxidation, but the carbon content in titanium carbide decreases. During milling of the main part of the charge to a fine state rather large steel particles (up to 50 μm) remain.  相似文献   
323.
Nano Research - Dimensionality and orientation of hexagonal boron nitride (h-BN) nanosheets are promising to create and control their unique properties for diverse applications. However,...  相似文献   
324.
325.
326.
The experiments on photocatalytic hydrogen production from aqueous solution of Ce2(SO4)3 and photocatalytic oxygen production from aqueous solution of Ce(SO4)2 were carried out on the same catalyst platinized Degussa P25. Pure oxygen was shown to evolve from Ce(SO4)2 solution and pure hydrogen from Ce2(SO4)3 solution with stoichiometric formation of Ce2(SO4)3 and Ce(SO4)2, respectively.  相似文献   
327.
This paper demonstrates the application of a modified Levich equation for chemical systems with varying viscosity. A commonly used technique to analyze rotating disc electrode (RDE) experiments is to fit the data to the Levich equation assuming a constant effective diffusion coefficient which may be valid for conditions where the viscosity does not vary significantly (less than an order of magnitude). However, most diffusion coefficient models (e.g. Stokes–Einstein) show an inverse relationship with viscosity which consequently indicates that a constant effective diffusion coefficient may result in poorer model-to-data agreement. Here, data are presented for a series of RDE experiments for the electrodissolution of Cu in phosphoric acid, water and glycerin based baths. Viscosity changes of greater than one order of magnitude allow for testing the assumption of a constant effective diffusion coefficient. The collected data, as well as data published elsewhere, can be explained by a modified Levich equation which takes into account the viscosity dependence of the diffusion coefficient.  相似文献   
328.
Altered mitochondrial function is currently recognized as an important factor in atherosclerosis initiation and progression. Mitochondrial dysfunction can be caused by mitochondrial DNA (mtDNA) mutations, which can be inherited or spontaneously acquired in various organs and tissues, having more or less profound effects depending on the tissue energy status. Arterial wall cells are among the most vulnerable to mitochondrial dysfunction due to their barrier and metabolic functions. In atherosclerosis, mitochondria cause alteration of cellular metabolism and respiration and are known to produce excessive amounts of reactive oxygen species (ROS) resulting in oxidative stress. These processes are involved in vascular disease and chronic inflammation associated with atherosclerosis. Currently, the list of known mtDNA mutations associated with human pathologies is growing, and many of the identified mtDNA variants are being tested as disease markers. Alleviation of oxidative stress and inflammation appears to be promising for atherosclerosis treatment. In this review, we discuss the role of mitochondrial dysfunction in atherosclerosis development, focusing on the key cell types of the arterial wall involved in the pathological processes. Accumulation of mtDNA mutations in isolated arterial wall cells, such as endothelial cells, may contribute to the development of local inflammatory process that helps explaining the focal distribution of atherosclerotic plaques on the arterial wall surface. We also discuss antioxidant and anti-inflammatory approaches that can potentially reduce the impact of mitochondrial dysfunction.  相似文献   
329.

Carbon monoxide is one of the most dangerous impurities in gas mixtures involved in the hydriding of intermetallic compounds, and up to the present time the concentration limit 0.03 vol.% CO has not been surmounted. The objective of the present work was to investigate the possibility of reversibly hydriding LaNi5 ? x Al x ― Pd composites in gas mixtures containing up to 5 vol.% CO. The experimental specimens were mixtures of palladium black and LaNi5, LaNi4.7Al0.3, LaNi4.5Al0.5, LaNi4.2Al0.8, and LaNi4Al powders cold pressed at 300 MPa. The intermetallics were preliminarily dispersed by hydriding and mechanical grinding. The concentration of palladium black in the powder mixtures was varied from 0 to 1.5 mass%. It was shown that it is possible to reversibly hydride LaNi5 ? x Al x ― Pd composites in mixtures of hydrogen and carbon monoxide containing up to 5 vol.% CO at the temperatures 423 and 473 K. It was established that alloying LaNi5 with aluminum in amounts which raised the stoichiometric concentration above 0.5 stabilized the absorption properties of LaNi5 ? x Al x ― Pd in the presence of CO. The composition LaNi4Al was optimal. Palladium additions to LaNi5 ? x Al x ― Pd composites also increased the stability of hydrogen absorption by the intermetallic. It is noted that the effect of palladium was more positive than that of aluminum.

  相似文献   
330.
A new fatty acid, (5Z,9Z)-22-methyl-5,9-tetracosadienoic acid (1a), and a rare fatty acid, (5Z,9Z)-23-methyl-5,9-tetracosadienoic acid (2a), the predominant constituents of the free fatty acid fraction from the lipids of the sponge Geodinella robusta, were isolated and partly separated by reversed phase high-performance liquid chromatography, followed by multifold crystallization from MeOH to give 1a and 2a in 70% and 60% purity, respectively. These fatty acids were identified as (5Z,9Z)-22-and (5Z,9Z)-23-methyl-5,9-tetracosadienoic acids by nuclear magnetic resonance techniques, including distortionless enhancement by polarization transfer, heteronuclear multiple quantum connectivity, and correlation spectroscopy experiments, as well as from mass-spectrometric data for their methyl esters, the methyl esters of their perhydro derivatives, and their pyrrolidides. Mixtures of 1a and 2a showed cytotoxic activity against mouse Ehrlich carcinoma cells and a hemolytic effect on mouse erythrocytes. The sterol fraction from the same sponge was analyzed by gas liquid chromatography mass spectrometry, and 24-methylenecholesterol was identified as a main constituent of this fraction. The implications of the co-occurrence of membranolytic long-chain fatty acids and 24-methylenecholesterol as a main membrane sterol are discussed in terms of the phenomenon of biochemical coordination.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号