Structure evolution of conductive polymer composites revealed by solvent vapor induced time-dependent percolation

The authors of this paper synthesized a series of amphiphilic triblock copolymers of polystyrene-b-poly(ethylene glycol)-b-polystyrene (PS-PEG-PS) having different PEG/PS ratios with nearly identical molecular weights of the entire copolymers. The interfacial interactions in the composites consisting of carbon black and the copolymers can thus be tailored. When these conducting composites are exposed to certain solvent vapors, their electrical resistances greatly increase, showing the gas sensitivity. The present work indicated that this switching behavior is controlled by the structural relaxation of the composites because matrix swelling acts as the main mechanism. The response time has been correlated with absolute temperature by Arrhenius equation, and the estimated activation energy reflects mobility of the fillers involved in the solvent induced expansion of the surrounding polymer. Therefore, by using the gas sensibility of the conductive composites, the structure evolution of the composite materials in solid state and the effect of filler/matrix interfacial interaction on the relaxation property of the matrix polymer has been inspected. It was found that lower activation energy represents stronger interfacial interaction in case good solvent of the matrix was used for the test.     

Biomimetic synthesis of spherical nano-hydroxyapatite in the presence of polyethylene glycol

Spherical nano-hydroxyapatite (nano-HA) was synthesized successfully by a biomimetic method using Ca(NO₃)₂·4H₂O and (NH₄)₃PO₄·3H₂O as reagents in the presence of polyethylene glycol (PEG). The crystalline phase, microstructure, chemical composition, and morphology of the obtained samples were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM). The results show that spherical nano-HA with diameter of 30–50 nm can be synthesized in the presence of a certain concentration (2–6%) of PEG. The crystallinity of HA powder synthesized in the presence of PEG was higher than that synthesized in the absence of PEG, but the crystallinity of HA reduced with increasing the concentration of PEG. The electrical conductivity (EC) of the solution revealed that PEG reduced the transfer rate of Ca²⁺ in the process of HA crystallization, indicating the interaction between PEG and HA. The possible mechanism of formation spherical nano-HA was discussed.     

PAN聚合物一次性溶解新技术

阐述了一个全新的聚丙烯腈高聚物溶解理论，取代了以往人们思维中的高聚物大分子必须经过先溶胀再溶解的漫长的静态溶解过程。对于年产50kt/a腈纶装置可减少一次性投资约1500万元，减少运转费用360万元／a，在现有腈纶大装置上实施，经济效益十分可观。     

对某自动驾驶仪可靠性增长的试验研究

对某自动驾驶仪可靠性增长工作进行研究,提出了对现役机载电子设备可靠性增长的一些成功、可借鉴的经验。对增长试验过程中发现的问题和管理方面的不足之处,提出一些建议。     

A new efficient numerical method and the dynamic analysis of composite laminates with piezoelectric layers

Firstly, a numerical method for the inversion of Laplace transform is developed and its accuracy is shown through examples. Then, a state-vector equation for the dynamic problems of piezoelectric plates is deduced directly from a modified mixed variational principle for piezoelectric bodies and its exact solution for the dynamic problems of simply supported rectangle piezoelectric plate is simply given. For multilayered hybrid plates, we derive the solution in terms of the propagator matrices. The techniques accounts for the compatibility of generalized displacements and generalized stresses on the interface both the elastic layers and piezoelectric layers, and the transverse shear deformation and the rotary inertia of laminate are also considered in the global algebraic equation of structure. Meanwhile, there is no restriction on the thickness and the number of layers. As an application of the numerical inversion of Laplace transform presented in this paper, typical numerical examples of the harmonic vibration and transient response are proposed and discussed. Since the highly accurate numerical results, they can serve as benchmarks to test various thick plate theories and various numerical methods, such as the finite and boundary element methods for transient response problems.     

压裂预处理技术的现场实施与评价

通常，压裂目的层的储层特征、物性及生产史差异较大，为保证压裂施工成功并取得较好的压裂效果，进行油层预处理十分必要。介绍了酸预处理、前置液氮预处理、柴油十互溶剂混合液预处理3种技术，阐述了各种预处理方法的目的及适应性，介绍了各种预处理技术在现场取得的效果，提出了各种预处理技术的适用条件及常用做法。     

��չ����Ȼ��Ϊԭ�ϵ�ȼ�ϵ������

研究燃料汽车及其氢源系统是当今国内外能源工业与汽车工业的共同课题，而优选制氢能源则是这一课题的关键。章介绍了利用能源、经济、环境(EEE)——生命周期评估(LCA)这一综合评估方法，针对以天然气、煤或石油作为制氢能源的多种燃料电池氢源供应方式以及配套的燃料电池汽车系统，从经济性、能源利用效率和环境影响三个方面进行了生命周期清单分析和EEE综合评价。结果显示：天然气作为发展燃料电池汽车氢源的一次能源，具有氢制取技术路线多样化、经济上竞争力强、能源利用效率高和环境效益好等诸多优势，应为燃料电池汽车的首选制氢能源。对这一评估模型的敏感性分析显示，即使在天然气价格波动较大时，天然气制甲醇--甲醇车载重整车和天然气制氢--纯氢车这两个方案仍然最具优势。     

长输管线变电所备用电源自动投入系统的改造

根据管道储运公司下属的各变电所目前的运行方式以及备用电源自动投入系统(以下简称“备自投”)的运行情况，指出了备自投使用中的不足之处，并通过增加对应断路器的辅助触点来完善备自投，使变电所运行更加可靠。     

钢包炉(LF)预熔精炼渣的研究

预熔精炼渣具有成分均匀，性能稳定，储存时不吸水等特点，钢包炉中使用预熔精炼渣时成渣均匀且速度快，具有较强的吸附钢中非金属夹杂的能力。综合脱硫率高等冶金效果。有显著净化钢液作用。     

A high-resolution burst-mode laser transmitter with fast and accurate level monitoring for 1.25 Gb/s upstream GPONs

An innovative burst-mode laser transmitter (BM-TX) is presented for gigabit-capable passive optical network (GPON) upstream transmission at 1.25 Gb/s. The laser bias and modulation current each can reach 80 mA with a resolution of 0.1 mA providing a total drive current up to 160 mA. Both currents are generated by 10-bit current steering digital-to-analog converters (DACs), the architecture of which is specially adapted to yield a monotonic current setting at settling times below 12.8 ns. Tests show that fast automatic power control (APC) can stabilize and track the launched optical power with a tolerance of less than 1 dB over a wide temperature range for outdoor operation. The APC only requires a straightforward calibration of the "0" and the "1" level at room temperature. Optical level monitoring on strings of four consecutive "0" bytes and two consecutive "1" bytes at 1.25 Gb/s is demonstrated. APC based on such short strings of data has not been shown before. The circuits have been designed in a 0.35 /spl mu/m SiGe BiCMOS process. Experimental results show that this dc-coupled BM-TX meets the specifications of the recently approved ITU-T Recommendation G.984.2 supporting an intelligent power leveling mechanism (PLM).