Quality of service for voice over IP in networks with congestion avoidance

This paper assesses the impact of active queue management schemes on the quality of service of voice over Internet protocol applications. A new analytical method based on a fixed point approach to estimate the end-user satisfaction is proposed. The results obtained were validated using discrete event simulation techniques. In all the studied cases, it was observed a great deal of agreement between the analytical results and the results obtained through simulation. The theoretical predictions, as well as the presented empirical evidences confirm, as demonstrated in previous works, that the use of active queue management offers better quality of service than the traditional queue control mechanisms used in Internet. From these results, we may reasonably conclude that the presented method can be used for network design in the presence of voice traffic.     

Non‐resonant Element in Slotted Ground Plane for Multiband Antenna Operation

New ways of achieving small, multiband, multifunctional, and standard solutions for mobile handset antennas are demanded in the current wireless market. A non‐resonant element of , a matching network, and a slotted ground plane are proposed to satisfy mobile market demands that require multiband operation and small antenna solutions. The main advantage of the proposed design is that with only one non‐resonant element of considerably small size (0.015λ, 900 MHz), the handset is capable of providing operation at mobile bands.     

Efficient and practical resource block allocation for LTE-based D2D network via graph coloring

In this paper, we construct a practical framework for efficiently allocating long term evolution (LTE) resource blocks (RB) among the users in a device-to-device (D2D) network. For such network that presumably operates under the LTE cellular network, our aim is to improve the overall throughput of D2D connections using opportunistic or fairness-based approach. Taking the practical considerations into account, our proposed framework allows a number of connections to share a single RB whenever possible, thus utilizing the radio resources. To do so, our solution first identifies a superior set of the interference-free D2D reuse groups via graph modeling and graph coloring approach. In particular, we model a D2D network with a two-overlapping disk graph for which a suitable coloring algorithm is proposed and its performance bound is calculated. Once the reuse groups are known, our solution optimizes the RB allocation among these groups based on their reported channel condition as well as the scheduling criterion, whether it is fairness-based or opportunistic. Through numerical experiments, we show that our solution can significantly improve the throughput performance of a D2D network.     

Losses of volatile compounds during fermentation

The ability of fermentative CO₂ to blow off the volatile compounds that are synthesized during fermentation has been studied. Model solutions simulating a fermenting must were purged at different CO₂ flow rates and temperatures, and the amount of volatile compounds blown off by the stream of CO₂ was recorded by high-resolution gas chromatography. Data showed that under normal fermenting conditions, fatty acid ethyl esters and some fusel alcohol acetates are blown off the solution at a high rate. The maximum loss rate was observed for ethyl decanoate. The purging speed is doubled when temperature increases from 17 °C to 27 °C. Losses can be interpreted by a linear model and are a function of the compound and the flow rate of CO₂. These models allow us to reconstruct the volatile synthesis vs time functions through graphic calculus and to estimate the proportion of volatile material retained, hydrolysed and purged. Synthesis takes place during the tumultuous period of fermentation together with CO₂ production that blows off the volatile material. Hydrolysis takes place in the last stages of fermentation. In a 10-1 open fermenter, up to 80% of volatile material can be blown off while an average of 10% is retained. Residual esterase activity accounts for about 20% of the total amount of ester synthesized.     

Comparative analysis of the outdoor performance of a dye solar cell mini‐panel for building integrated photovoltaics applications

New generation photovoltaic (PV) devices such as polymer and dye sensitized solar cells (DSC) have now reached a more mature stage of development, and among their various applications, building integrated PVs seems to have the most promising future, especially for DSC devices. This new generation technology has attracted an increasing interest because of its low cost due to the use of cheap printable materials and simple manufacturing techniques, easy production, and relatively high efficiency. As for the more consolidated PV technologies, DSCs need to be tested in real operating conditions and their performance compared with other PV technologies to put into evidence the real potential. This work presents the results of a 3 months outdoor monitoring activity performed on a DSC mini‐panel made by the Dyepower Consortium, positioned on a south oriented vertical plane together with a double junction amorphous silicon (a‐Si) device and a multi‐crystalline silicon (m‐Si) device at the ESTER station of the University of Rome Tor Vergata. Good performance of the DSC mini‐panel has been observed for this particular configuration, where the DSC energy production compares favorably with that of a‐Si and m‐Si especially at high solar angles of incidence confirming the suitability of this technology for the integration into building facades. This assumption is confirmed by the energy produced per nominal watt‐peak for the duration of the measurement campaign by the DSC that is 12% higher than that by a‐Si and only 3% lower than that by m‐Si for these operating conditions. Copyright © 2013 John Wiley & Sons, Ltd.     

Lithium Phosphonate Functionalized Polymer Coating for High-Energy Li[Ni0.8Co0.1Mn0.1]O2 with Superior Performance at Ambient and Elevated Temperatures

High-energy Ni-rich lithium transition metal oxides such as Li[Ni_0.8Co_0.1Mn_0.1]O₂ (NCM₈₁₁) are appealing positive electrode materials for next-generation lithium batteries. However, the high sensitivity toward moist air during storage and the high reactivity with common organic electrolytes, especially at elevated temperatures, are hindering their commercial use. Herein, an effective strategy is reported to overcome these issues by coating the NCM₈₁₁ particles with a lithium phosphonate functionalized poly(aryl ether sulfone). The application of this coating allows for a substantial reduction of lithium-based surface impurities (e.g., LiOH, Li₂CO₃) and, generally, the suppression of detrimental side reactions upon both storage and cycling. As a result, the coated NCM₈₁₁-based cathodes reveal superior Coulombic efficiency and cycling stability at ambient and, particularly, at elevated temperatures up to 60 ° C (a temperature at which the non-coated NCM₈₁₁ electrodes rapidly fail) owing to the formation of a stable cathode electrolyte interphase with enhanced Li⁺ transport kinetics and the well-retained layered crystal structure. These results render the herein presented coating strategy generally applicable for high-performance lithium battery cathodes.     

Priming Crime and Activating Blackness: Understanding the Psychological Impact of the Overrepresentation of Blacks as Lawbreakers on Television News

Two experiments examined the extent to which U.S. viewers' perceptions that Blacks face structural limitations to success, support for the death penalty, and culpability judgments could be influenced by exposure to racialized crime news. Participants were exposed to a majority of Black suspects, a majority of White suspects, unidentified suspects, and noncrime news stories. In addition, participants' prior news viewing was assessed. In Study 1, heavy news viewers exposed to unidentified perpetrators were less likely than heavy news viewers exposed to noncrime stories to perceive that Blacks face structural limitations to success. In addition, heavy news viewers exposed to unidentified perpetrators were more likely than heavy news viewers exposed to noncrime stories to support the death penalty. In Study 2, participants exposed to a majority of Black suspects were more likely than participants exposed to noncrime stories to find a subsequent race-unidentified criminal culpable for his offense. In addition, heavy news viewers were more likely to exhibit the above effect than light news viewers. The methodological and theoretical implications of these findings are discussed in light of chronic activation and the priming paradigm.     

Toward the Optimized Spintronic Response of Sn‐Doped IrO2 Thin Films

Amorphous and polycrystalline Sn‐doped IrO₂ thin films, Ir_1‐xSn_xO₂, are grown for the first time. Their electrical response and strength of the spin–orbit coupling are studied in order to better understand and tailor its performance as spin current detector material. These experiments prove that the resistivity of IrO₂ can be tuned over several orders of magnitude by controlling the doping content in both the amorphous and the polycrystalline state. In addition, growing amorphous samples increase the resistivity, thus improving the spin current to charge current conversion. As far as the spin–orbit coupling is concerned, the system not only remains in a strong spin–orbit coupling regime but it seems to undergo a slight enhancement in the amorphous state as well as in the Sn‐doped samples.     

Retarding Thermal Degradation in Hybrid Perovskites by Ionic Liquid Additives

Recent years have witnessed considerable progress in the development of solar cells based on lead halide perovskite materials. However, their intrinsic instability remains a limitation. In this context, the interplay between the thermal degradation and the hydrophobicity of perovskite materials is investigated. To this end, the salt 1‐(4‐ethenylbenzyl)‐3‐(3,3,4,4,5,5,6,6,7,7,8,8,8‐tridecafluorooctylimidazolium iodide (ETI), is employed as an additive in hybrid perovskites, endowing the photoactive materials with high thermal stability and hydrophobicity. The ETI additive inhibits methylammonium (MA) permeation in methylammonium lead triiodide (MAPbI₃) occurring due to intrinsic thermal degradation, by inhibiting out‐diffusion of the MA⁺ cation, preserving the pristine material and preventing decomposition. With this simple approach, high efficiency solar cells based on the unstable MAPbI₃ perovskite are markedly stabilized under maximum power point tracking, leading to greater than twice the preserved efficiency after 700 h of continuous light illumination and heating (60 °C). These results suggest a strategy to tackle the intrinsic thermal decomposition of MAI, an essential component in all state‐of‐the‐art perovskite compositions.