Pollution control of actual flue gas using pulsed power at a thermal power plant

There are several important environmental problems in the world. One of them is acid rain caused by combustion flue gases from thermal power plants, factories, and automobiles. Different kinds of gas discharges, such as surface discharge, dc and ac corona discharge, silent discharge, and electron beam controlled discharge, have been studied for the removal of NO_x and SO₂ from flue gases. The recent development of repetitive pulsed power generators gives the pulsed steamer corona discharges a chance of success in the removal of NO_x and SO₂. In this paper, the experimental results of NO_x and SO₂ removal by a repetitive pulse power generator are described. The actual flue gas at a thermal power plant was used. It is shown that about 90% of the NO was removed at a flow rate of 0.8 liters/min and a repetition rate of 7 pps. © 2001 Scripta Technica, Electr Eng Jpn, 134(4): 28–35, 2001     

Parallel streamer discharges between wire and plane electrodes in water

Streamer discharges in tap water and distilled water have been generated by applying a voltage pulse from 120 to 175 kV and 500 ns duration to a wire-to-electrode configuration. Electrical and optical diagnostics were used to explore the temporal development of the streamers in tap and distilled water, at various applied voltages and both polarities. With the wire serving as anode, multiple, parallel streamer discharges were generated. The number density of these streamers along the wire decreases with decreasing electric field on the surface of the wire. The dependence of the streamer density on electric field indicates the role of field enhancement at inhomogeneous microstructures along the wire as streamer initiation mechanism. The appearance of the discharge was different for tap and distilled water. However, the measured average streamer propagation velocity from the positive wire to the grounded plane electrode, of 32 mm//spl mu/s, was independent of the water conductivity and the applied voltage. This suggests the existence of a self-sustained electric field at the streamer head. With the wire serving as cathode, only a weak light emission from the area close to the wire was observed, and streamers did not appear for the same voltage amplitude as with the positive polarity. This suggests that an ionic current flowing in the water is not dominant in the streamer propagation process.     

N.m.r. study of egg yolk lecithin in aromatic solvents. Magnetic nonequivalence in the methylene protons of the fatty acyl chains

¹H and ¹³C n.m.r. chemical shifts and also spin-lattice relaxation times of phospholipids, mainly egg yolk lecithin, were measured in organic solvents, especially aromatic solvents. The use of aromatic solvents promotes the difference in the magnetic shielding environment of the internal methylene protons of the fatty acyl chains and as a result, a doublet peak for the methylene groups was observed in the solvents, especially mesitylene. The ¹H and ¹³C n.m.r. T₁ measurements indicate the remarkable gradient in the motional freedom along the fatty acyl chains as well as the marked decrease in the motional freedom of the polar head group and also, the high-field component of the doublet peak for internal methylene protons has a shorter T₁ value than the low-field component. Thus, it was concluded that the low-field component in the doublet comes from the methylene protons located relatively in the neighbourhood of the carbonyl groups and the high-field component the methylene protons located relatively in the neighbourhood of the terminal methyl groups of the fatty acyl chains.     

The dilute solution properties of maleic anhydride and maleic acid copolymers: 1. Light scattering, osmotic pressure and viscosity measurements

Dilute solution behaviour of poly(maleic anhydride-co-ethyl vinyl ether) and poly(maleic acid-co-ethyl vinyl ether) has been investigated by light scattering, osmotic pressure, and viscosity measurements. The molecular weights ($\text{M}\text{?}{}_{\mathrm{w}}$ and $\text{M}\text{?}{}_{\mathrm{n}}$), the second virial coefficients A₂, and the intrinsic viscosities [η] have been determined for three states of this copolymer: anhydride-form, H-form, and Na-salt independently. The constants in the Mark-Houwink relations were obtained for the above three states under different solvent conditions. The molecular weight of the anhydride-form is found to be higher than that of the acid-form or the Na-salt, suggesting the degradation in a process of hydrolysis. The second virial coefficient A₂ as well as the Mark-Houwink relation indicates that the anhydride-form and H-form behave as flexible polymer chains in good solvents. However, the polymer coil of Na-salt is highly expanded even at saturated NaCl concentration.     

Hydrothermal Corrosion of Alumina Ceramics

The corrosion behavior and strength degradation of alumina ceramics with 99%, 99.9%, and 99.99% Al₂O₃ were studied in water at 300°C and 8.6 MPa for 1 to 10 d. The weight loss in alumina ceramics was mainly attributed to the dissolution of SiO₂ and Na₂O grain-boundary impurities. Intergranular corrosion proceeded in the alumina ceramics by preferential attack at the grain boundaries. The extent of the strength reduction for corroded alumina ceramics was related to the impurity level in the alumina ceramics.     

Characterization of Class V DyP-Type Peroxidase SaDyP1 from Streptomyces avermitilis and Evaluation of SaDyPs Expression in Mycelium

DyP-type peroxidases are a family of heme peroxidases named for their ability to degrade persistent anthraquinone dyes. DyP-type peroxidases are subclassified into three classes: classes P, I and V. Based on its genome sequence, Streptomyces avermitilis, eubacteria, has two genes presumed to encode class V DyP-type peroxidases and two class I genes. We have previously shown that ectopically expressed SaDyP2, a member of class V, indeed has the characteristics of a DyP-type peroxidase. In this study, we analyzed SaDyP1, a member of the same class V as SaDyP2. SaDyP1 showed high amino acid sequence identity to SaDyP2, retaining a conserved GXXDG motif and catalytic aspartate. SaDyP1 degraded anthraquinone dyes, which are specific substrates of DyP-type peroxidases but not azo dyes. In addition to such substrate specificity, SaDyP1 showed other features of DyP-type peroxidases, such as low optimal pH. Furthermore, immunoblotting using an anti-SaDyP2 polyclonal antibody revealed that SaDyP1 and/or SaDyP2 is expressed in mycelia of wild-type S. avermitilis.     

Absolute Configuration of β- and α-Asymmetric Carbons within β-O-4-Structures in Hardwood Lignin

In this study, we investigated the proportion of erythro- and threo-forms of β-O-4-ether structures and their enantiomeric compositions in hardwood lignin by applying the ozonation method to birch wood meal. Optical activity was not substantially observed in either the erythronic or threonic acids obtained as the ozonation products of β-O-4-structures in birch wood meal. The proportions of the four stereoisomeric forms {(αS,βR)-erythro, (αR,βR)-threo, (αS,βS)-threo, and (αR,βS)-erythro forms} were estimated to be 37-38%, 13-14%, 12-13%, and 36-37% based on the yields of erythronic and threonic acids, and on their optical activities. The proportions suggest that the entire components of β-O-4-ether structures in birch wood lignin have R- and S-configurations at the β-carbon in approximately the same quantities {(βR)-β-O-4-structure: (βS)-β-O-4-structure = 50–52:48–50}; i.e., that the β-ether structures are essentially racemic. This estimation implies that, during lignin biosynthesis, an equal number of enantiomeric forms of β-O-4-bonded quinone methides were formed by radical coupling reactions.     

Modular design of mechatronic systems with function modeling

This paper develops a modularization scheme based on the functional model of a system. The modularization approach makes use of the function–behavior–state (FBS) model of the system to derive the entity relations. The design structure matrix (DSM) is automatically constructed based on the FBS model. In this way, the tedious work of filling the DSM entries based on expert knowledge is avoided. The approach makes use of k-means clustering algorithm to allow the user to try different number of clusters in a fast way. The k-means clustering is adopted for DSM based modularization by defining a proper entity representation, relation measure and objective function. Two modularization schemes are performed, one based on the immediate relations and one on the deeper behavioral relations between the components. Considering the application on the shifting system of the Delft University of Technology (DUT) Formula Student car, the latter modularization resulted in more mechatronic behavior based modules, while the former resulted in modules based on mere disciplinary and spatial closeness.     

Measurement of topcoat thickness of thermal barrier coating for gas turbines using terahertz waves

The topcoat thickness of thermal barrier coating (TBC) samples was measured using terahertz (THz) waves. The index of refraction of yttria‐stabilized zirconia (YSZ), which is the topcoat material, is necessary to obtain the topcoat thickness from time domain re?ectometry. Time domain THz spectroscopy was applied to YSZ samples, and the index of refraction was measured to be 4.8 in the frequency region 0.1 to 1.2 THz. The topcoat thickness of six di?erent TBC samples, which varied from 300 to 600 µm, was measured using THz waves. The results were in agreement with microscope observation results to within measurement error. In addition, the topcoat thickness pro?le of a turbine blade sample was measured with a resolution of 2.4 µm. The pro?le showed a standard deviation of 4 µm, which re?ects the actual variation in the topcoat thickness. The results showed that THz waves are e?ective for high‐resolution measurement of the topcoat thickness. © 2013 Wiley Periodicals, Inc. Electr Eng Jpn, 183(4): 1–9, 2013; Published online in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/eej.22385     

Development of biobased microwave absorbing composites with various magnetic metals and carbons

The preparation and characterization of a biobased electromagnetic absorbing composites derived from natural lacquer as a renewable resource with microwave‐absorption fillers, including Ni–Zn ferrite and carbonyl iron (CI) as magnetic metals and soot and carbon nanotube (CNT) as carbon materials, were investigated in terms of the gel content, hardness, drying properties, and electromagnetic absorption properties. Interestingly, composites with ferrite and CI contained up to 320 and 550 wt %, respectively, of these compounds. This quite high loading capacity of the metal fillers in a natural‐lacquer base could have been due to the high compatibility between the filler and the natural lacquer; this indicated that the natural lacquer worked as a binder for these metals. The morphology of the biobased composite was characterized by scanning electron microscopy. The electromagnetic absorption properties of composites were characterized in the frequency range from 0.05 and 20 GHz by the reflection loss (RL) measurement method in terms of the kind of fillers and filler loading. The natural lacquer did not affect the absorption properties of the fillers. Biobased composites showed over 99% electromagnetic absorption in the frequency range 3.0–4.0 GHz for 280 wt % ferrite and 8.9–9.7 GHz for 200 wt % CI. Conversely, 10 and 20 wt % soot exhibited good performance (RL < ?20 dB) between 16.5 and 17.3 and between 8.8 and 9.2 GHz, respectively. The areas with RL values of less than ?20 dB of the CNT composites were 10.4–11.0 GHz for 5 wt % and 14.6–15.2 GHz for 10 wt %. Hence, natural lacquer can be used as a binder material for electromagnetic absorption composites. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44131.