Numerical investigation of the impact of gas and cooling flow configurations on current and water distributions in a polymer membrane fuel cell through a pseudo-two-dimensional diphasic model

For optimal performances, proton exchange membrane fuel cells require fine water and thermal management. Accurate modelling of the physical phenomena occurring in the fuel cell is a key issue to improve fuel cell technology. Here, an analytic steady state diphasic 2D model of heat and mass transfer is presented. Through this model, the aim of this work is to study the influence of local events on the global performances of a fuel cell. A part of the complete model is a microscopic representation of the coupling between water transport and charge transfers in the electrodes. The thickness of the liquid layer around the reactive agglomerates is deduced from the saturation. The evolution of the quantity of water within the catalyst layer is monitored and its influence on the global performances of the cell is investigated. In gas diffusion layers (GDLs), liquid and vapour water transport through are computed regarding the temperature. The flow direction of cooling water modifies the current density distribution along the cell. The impact of the direction of air and hydrogen feeding channels are investigated. It can modify greatly the fuel cell mean current density and the net water transport coefficient. The counter-flow mode was preferable. Likewise, thanks to a better membrane hydration, it results in independent performances regarding the hydrogen inlet relative humidity or stoichiometry.     

Ferroelectricity and high tunability in novel strontium and tantalum based layered perovskite materials

The present study reveals the ferroelectric nature of the novel (Sr₂Ta₂O₇)_100-x(La₂Ti₂O₇)_x layered perovskite materials and highlights a large variation of their permittivity under electric fields associated with very low dielectric loss in the radio-frequency range. More precisely, an ideal solid solution has been evidenced within the composition range 0?≤?x?≤?5 with lattice parameters and cell volume varying linearly with x. The relative permittivity also depends on the composition and reaches a maximum value (365 @10?kHz, RT), associated with a high tunability (17.6% @0.38?kV/mm) with very low dielectric loss lower than 2.10^?3. Variation of the relative permittivity as a function of the temperature is also demonstrated, with the existence of a temperature maximum, increasing with the composition. Polarization-electric field (P-E) measurements feature hysteresis loops for compositions x?≥?1.85, in conjunction with current peaks in the I-E curves originating from ferroelectric domains switching.     

Structural studies of the phase separation in the UO2–PuO2–Pu2O3 ternary system

In the oxygen hypo-stoichiometric range of (U_1?yPu_y)O_2?x mixed oxide MOX fuels, the U–Pu–O phase diagram is known to exhibit a large biphasic domain depending on the Pu content. However, the phase equilibria are still to be fully described as various representations are proposed in the literature.In the present work, we notify new insights into the phase separation occurring in the UO₂–PuO₂–Pu₂O₃ domain at room temperature. Our microstructural and X-ray diffraction results are compared to the different representations reported in the literature. We provide, for the first time in the hypo-stoichiometric domain, an indisputable experimental observation of a triphasic region at high Pu content, composed of two fluorite-type structures and of one α-Pu₂O₃ sesquioxyde type structure. These results are in contradiction with previous experimental representations of the U–Pu–O ternary system.     

Characterization of meso-scale mechanical properties of Longmaxi shale using grid microindentation experiments

Mechanical properties,such as the hardness H,Young's modulus E,creep modulus C,and fracture toughness Kc,are essential parameters in the design of hydraulic fracturing systems for prospective shale gas formations.In this study,a practical methodology is presented for obtaining these properties through microindentation experiments combined with quantitative observations of the mineralogical phases using X-ray diffraction(XRD),scanning electron microscopy(SEM) with backscattered electron(BSE)imaging,and energy-dispersive X-ray spectroscopy(EDS) analyses.We apply this method in the case of three types of Longmaxi shales with different mineralogies(i.e.carbonate-,clay-,and quartz-rich,respectively),which allows us to determine the characteristic indentation depth,h_c=8-10 μm,beyond which the mechanical response of the carbonate-rich shale is homogeneous and independent of its complex heterogeneous microstructure.Moreover,exploiting the results of a large number of indentation tests,we demonstrate that the indentation modulus M of the shale increases as a power-law of hardness H,and its creep modulus C increases linearly with H.We also compute the fracture toughness Kc from the indentation data by assuming a perfectly plastic behavior of the sample.Our results are in good agreement with independent measurements of Kc determined by microscratch tests.Finally,further tests on quartz-and clay-rich samples of the Longmaxi shale suggest further variations in the samples' mechanical properties depending on their burial conditions and the mechanical properties of their dominant mineral phases.     

A hybrid genetic algorithm with adaptive diversity management for a large class of vehicle routing problems with time-windows

The paper presents an efficient Hybrid Genetic Search with Advanced Diversity Control for a large class of time-constrained vehicle routing problems, introducing several new features to manage the temporal dimension. New move evaluation techniques are proposed, accounting for penalized infeasible solutions with respect to time-window and duration constraints, and allowing to evaluate moves from any classical neighbourhood based on arc or node exchanges in amortized constant time. Furthermore, geometric and structural problem decompositions are developed to address efficiently large problems. The proposed algorithm outperforms all current state-of-the-art approaches on classical literature benchmark instances for any combination of periodic, multi-depot, site-dependent, and duration-constrained vehicle routing problem with time windows.     

étude du lien entre l'évaluation de la valence et les réponses verbales dans une tache de décision lexicale: Les réponses oui et non sont-elles des réponses affectives?

Evaluation of the positive or negative valence of a stimulus is an activity that is part of any emotional experience that has been mostly studied using the affective priming paradigm. In this study, we use the hypothesis that when a word leads to a positive valence evaluation, this favours a positive verbal response and inversely, a negative valence word favours a negative response. We are testing this hypothesis outside the affective priming paradigm to study to what extent evaluating a word, even when it is not primed, activates both motivational systems and consequently, positive verbal responses for approach and negative responses for avoidance. To validate this hypothesis, we are re-using both versions of the lexical decision task proposed by Wentura (2000). Results show an interaction between the type of response and word valence. It is temporally more onerous to give a no response to positive words than to negative words. This result confirms that there is a direct relation between the evaluation of a valence stimulus and the response to this stimulus, a relation that had up to now been essentially observed with motor behaviours, and more rarely with verbal responses. We propose integrating the existence of this link between evaluation and verbal response (yes and no) in interpreting the effects of affective priming. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Finger pad friction and its role in grip and touch

Many aspects of both grip function and tactile perception depend on complex frictional interactions occurring in the contact zone of the finger pad, which is the subject of the current review. While it is well established that friction plays a crucial role in grip function, its exact contribution for discriminatory touch involving the sliding of a finger pad is more elusive. For texture discrimination, it is clear that vibrotaction plays an important role in the discriminatory mechanisms. Among other factors, friction impacts the nature of the vibrations generated by the relative movement of the fingertip skin against a probed object. Friction also has a major influence on the perceived tactile pleasantness of a surface. The contact mechanics of a finger pad is governed by the fingerprint ridges and the sweat that is exuded from pores located on these ridges. Counterintuitively, the coefficient of friction can increase by an order of magnitude in a period of tens of seconds when in contact with an impermeably smooth surface, such as glass. In contrast, the value will decrease for a porous surface, such as paper. The increase in friction is attributed to an occlusion mechanism and can be described by first-order kinetics. Surprisingly, the sensitivity of the coefficient of friction to the normal load and sliding velocity is comparatively of second order, yet these dependencies provide the main basis of theoretical models which, to-date, largely ignore the time evolution of the frictional dynamics. One well-known effect on taction is the possibility of inducing stick–slip if the friction decreases with increasing sliding velocity. Moreover, the initial slip of a finger pad occurs by the propagation of an annulus of failure from the perimeter of the contact zone and this phenomenon could be important in tactile perception and grip function.     

Proposal for a new hybrid control strategy of a solar desiccant evaporative cooling air handling unit

Correctly controlled solar desiccant evaporative cooling is an interesting option for achieving savings in building air-conditioning consumption. The operation of this system (open loop cooling cycle) is strongly influenced by indoor and outdoor air conditions. This influence is characterized using numerical simulations. First the air conditioned room and the cooling system are simulated using a validated model of the desiccant wheel. Then the influence of each parameter of the desiccant air handling unit is evaluated. The third step is to assess the system cooling power for each operating mode with fluctuating outdoor and indoor air conditions. This allows for making relevant choices for a new control strategy taking into account both indoor and outdoor air conditions. This control strategy is tested for a whole cooling season and compared to a reference compression system with promising results, allowing for energy savings of about 40% for French climate.