Hydrogen-assisted cracking

This article reviews a number of case studies involving hydrogen-assisted cracking in steels. Before the case studies are presented, the current state of understanding of hydrogen-assisted cracking is briefly reviewed. At present there are two leading approaches to the development of a mechanism of hydrogen-assisted cracking, one based upon bond weakening, and the other upon strain localization. As the case studies illustrate, hydrogen-assisted cracking can lead to failures in perhaps unexpected circumstances. The need for the wider dissemination of information about hydrogen cracking to design engineers is indicated.     

Temperature-induced phase change in a fat. A study by electron spin resonance

Electron Spin Resonance, Differential Scanning Calorimetry and rheological techniques have been used to study the physical changes induced by temperature in lard and in the solid and liquid fractions obtained by fractionation of lard at 15 C. The mobilization process of a C18 fatty acid nitroxide derivative dispersed in the molten fat has been observed in the temperature range −50 to +70 C. The mobilization of the probe seemed to be concomitant with the melting of the low melting point glycerides. Above this temperature, all the probes were in the liquid phase and their mobility reflected the viscosity of their liquid environment, or the viscosity of the bulk fat when crystal was no longer present. Probe mobility was temperature dependent, and it was identical for the three fats at the same temperature, despite their different triglyceride compositions.     

Utilisation de couples d'hydrocarbures dans les frigopompes et les thermofrigopompes à absorptionUtilisation of hydrocarbon pairs in absorption heat pumps in cooling applications

The performances of two systems using hydrocarbon pairs are compared. The first system is an absorption heat pump, comprising a rectification column separator and a mixer comprising a single-stage cell. In this case, five hydrocarbon pairs are used. In the second system, the authors compare the performances of three hydrocarbon pairs in two heat pumps with one or two stages in the mixer. It was shown that the best performances are obtained using pairs with the most similar chemical compositions.     

Microscopic Origin of Casimir-Polder Forces

We establish a general relation between dispersion forces. First, based on QED in causal media, leading-order perturbation theory is used to express both the single-atom Casimir-Polder and the two-atom van der Waals potentials in terms of the atomic polarizabilities and the Green tensor for the body-assisted electromagnetic field. Endowed with this geometry-independent framework, we then employ the Born expansion of the Green tensor together with the Clausius-Mosotti relation to prove that the macroscopic Casimir-Polder potential of an atom in the presence of dielectric bodies is due to an infinite sum of its microscopic many-atom van der Waals interactions with the atoms comprising the bodies. This theorem holds for inhomogeneous, dispersing, and absorbing bodies of arbitrary shapes and arbitrary atomic composition on an arbitrary background of additional magnetodielectric bodies.     

Studies of palladium electrodeposition from baths based on Pd(NH3)2X2 Part II: X=Br and X=NO2

The chemistry and electrochemistry of electroplating baths based on Pd(NH₃)₂Br₂ and Pd(NH₃)₂(NO₂)₂ has been investigated and compared with that previously reported for Pd(NH₃)₂Cl₂. It is shown that electroactive species in all the baths is Pd(NH₃) ₄ ²⁺ and, hence, the mechanisms and current efficiencies for the cathodic deposition of palladium metal are similar in all three media. On the other hand, only in bromide electrolytes is the palladium found to dissolve anodically.     

Electrocatalyst performance in industrial water electrolysers

Electrocatalyst materials used in industrial water electrolysis equipment must meet stringent requirements for long-term stability. Low electrode overvoltages must be sustained over prolonged periods of normal operation, including power interruptions. This paper presents an overview of the catalyst systems currently favoured for use in alkaline electrolyte. Performance data covering test periods exceeding 30 000 h are presented for representative commercial electrocatalysts. Results obtained in 100 000-A unipolar cells are correlated in detail with expectations based on measurements in laboratory and pilot-plant equipment.Particular attention is given to the effects of open-circuit conditions on electrode stability. An accelerated reverse-potential cycling test is described which allows identification of materials expected to withstand industrial operating conditions. It is found that the better materials which have been identified can be used with confidence, at least in electrolysers of the unipolar design in which potential variations encountered during current interruptions are modest.     

Multitemporal passive microwave mapping in MACHYDRO'90

MACHYDR0'90 was an experiment conducted in Pennsylvania in 1990 to study the synergistic use of remote sensors in multitemporal hydrologic studies. As part of this mission the pushbroom microwave radiometer was flown and used to produce brightness temperature maps. Verification studies and vegetation algorithms for mixed land cover areas are described     

The cardiovascular interaction between caffeine and nicotine in humans

In a placebo-controlled, double-blind randomized design, we investigated the cardiovascular interaction between caffeine (250 mg intravenously) and nicotine (4 mg chewing gum) in 10 healthy volunteers, both under baseline conditions and during physical and mental stress (standing up and mental arithmetic). Caffeine alone induced a significant increase in blood pressure associated with a decrease in heart rate, whereas nicotine alone increased both blood pressure and heart rate. The combination of caffeine and nicotine increased systolic and diastolic blood pressure by 10.8 +/- 2.0 and 12.4 +/- 1.9 mm Hg, respectively. This pressor response did not differ significantly from the calculated additive effects of caffeine and nicotine on blood pressure, measuring 12.9 +/- 2.0 and 14.2 +/- 2.1 mm Hg, respectively. Heart rate and forearm blood flow also showed a similar response when the combination of caffeine and nicotine was compared with the calculated sum. During physical stress (standing up), blood pressure, heart rate, and plasma catecholamines increased in the placebo test. The pressor response to standing up was less pronounced after the combination of caffeine and nicotine compared with the sum of the separate effects (combination versus sum: delta diastolic blood pressure, 24.7 +/- 1.9 versus 35.2 +/- 2.6 mm Hg [p < 0.01]; delta mean arterial pressure, 22.1 +/- 2.0 mm Hg versus 28.6 +/- 1.6 mm Hg [p < 0.05]). The plasma catecholamine response did not differ between the combination and the sum of both drugs. During mental arithmetic, blood pressure, heart rate, and forearm blood flow increased in the placebo test. The forearm vasodilator response to mental stress was attenuated by the combination of caffeine and nicotine compared with the sum of both drugs (combination versus sum: delta forearm blood flow, -0.1 +/- 0.3 versus 1.4 +/- 0.5 ml/100 ml/min [p < 0.05]). We conclude that the combined administration of caffeine and nicotine shows additive effects on cardiovascular parameters during baseline conditions but less than additive effects during sympathoadrenal stimulation.