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951.
Tommy Munk Stefania Baldursdottir Sami Hietala Thomas Rades Markus Nuopponen Katriina Kalliomäki Heikki Tenhu Jukka Rantanen Clare J. Strachan 《Polymer》2013
The use of vibrational spectroscopy to investigate complex structural changes in polymers yields chemically rich data, but interpretation can be challenging and subtle but meaningful spectral changes may be missed through visual inspection alone. Multivariate analysis is an efficient approach to gain an oversight of small but systematic spectral differences anywhere within the spectra, providing further insight into structural changes and associated transformation mechanisms. In this study, the novel analytical approach of infrared spectroscopy combined with principal component analysis and Gaussian peak fitting was used to investigate the structural changes in aqueous solutions of a polymer, using poly(N-isopropyl acrylamide) (PNIPAM) in the atactic form and with controlled tacticity as a model system. Subtle spectral changes associated with the dehydration and phase separation upon heating included peak shifts, an area ratio change of the amide I band to the amide II band and formation of a new peak in the amide I band were efficiently detected. Dehydration and phase separation of PNIPAM occurred in two temperature ranges, one for the atactic and one for isotactic rich part, both involving a complex re-organization of the hydrogen bonds and change of the hydration layer. The changes agreed with existing results from other techniques, and new insights were gained into the effect of controlled tacticity on phase transformation behaviour. The study demonstrates that infrared spectroscopy combined with the multivariate analytical method principal component analysis and Gaussian peak fitting is an efficient approach to probing structural change in polymers during heating. The simplicity of the presented approach could find excellent use in analysing and understanding the molecular environment of a range of stimuli-responsive polymers, for instance block or grafted types of polymers, as well as those with controlled tacticity. 相似文献
952.
Martin Härtelt Stefan Fünfschilling Thomas Schwind Heinz Riesch‐Oppermann Theo Fett Jamie J. Kruzic 《Journal of the American Ceramic Society》2013,96(8):2593-2597
Fatigue failure is a concern when high‐strength, high‐toughness silicon nitride ceramics are used in mechanical components and the growth of natural flaws will determine the usable upper bound strength. In this study a fracture resistance curve (R‐curve) model is incorporated into an established method for deducing natural flaw growth rates from a combination of strength and fatigue life data for smooth specimens. Experimental data for a commercial silicon nitride, SL200, were examined. When compared with results deduced using a constant fracture toughness model, the new method gives more physically realistic growth rate results. Specifically, by incorporating the R‐curve the deduced fatigue threshold is equal to the reported intrinsic toughness for crack propagation of 2.2 MPa√m, whereas the constant fracture toughness model gives a physically unrealistic threshold value. Furthermore, much better agreement is achieved with the growth rates measured using macroscopic compact‐tension specimens. Overall, it is concluded that the R‐curve effect should not be ignored when deducing the fatigue crack growth rates of natural flaws in high‐toughness silicon nitride ceramics. 相似文献
953.
Elmar Strassburger Thomas Hutzler Jens Klimke 《Journal of the American Ceramic Society》2013,96(9):2718-2721
Contrary to the moderate ballistic advantage of Al2O3 ceramics over MgAl2O4 polycrystals, the present study shows a reverse ratio of the ballistic strength of alumina and spinel single crystals: Spinel single crystals outperform sapphire and exhibit a similarly high stability as submicrometer Al2O3 ceramics. The results correlate with different cleavage of single crystalline spinel and sapphire, changing the fragmentation on ballistic impact. 相似文献
954.
Klaus Heckmann Manfred Habermann Thomas Paul Martin Stratmann 《The Journal of Adhesion》2013,89(1):65-83
New primer molecules have been synthesized to increase the adhesion strength between a copper leadframe and an epoxy molding compound in microelectronical devices. The coupling agents were preliminarily chemisorbed at the surface of copper plates via special binding groups like thiol, disulfide, ethylene diamine and phthalocyanine. Binding to the epoxy resin was performed via an hydroxyl group. Linear hydrocarbon spacers with various chain lengths connected the copper- and epoxy-binding groups. The self-assembled layers of the organic coupling agents at the metal surface were characterized by X-ray photoelectron spectroscopy. Thermogravimetric analysis was used to study the coating with respect to its corrosion oxidation inhibition. Shear tests clearly indicated that the coupling agents increase adhesion strength and are stable even in extreme humidity and thermal conditions in analogy to IPC-Level-1 pretreatment. Thus, delamination of the microelectronical packages was prevented. 相似文献
955.
Thomas M. Yeh Jacob G. Dickinson Allison Franck Suljo Linic Levi T. Thompson Jr Phillip E. Savage 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2013,88(1):13-24
One of the promising avenues for biomass processing is the use of water as a reaction medium for wet or aquatic biomass. This review focuses on the hydrothermal catalytic production of fuels and chemicals from aquatic biomass. Two different regimes for conversion of aquatic biomass in hydrothermal conditions are discussed in detail. The first is hydrothermal liquefaction, and the second is hydrothermal gasification. The goals of these processes are to produce liquid‐fuel‐range hydrocarbons and methane or hydrogen, respectively. The catalytic upgrading of biocrude resulting from noncatalytic liquefaction and the stability and degradation of catalysts in high temperature water are also discussed. The review concludes with a brief discussion of the outlook for and opportunities within the field of hydrothermal catalytic valorization of biomass. Copyright © 2012 Society of Chemical Industry 相似文献
956.
Zinc oxide (ZnO) nanoparticles of size 20–90 nm and surface area 9.56 m2/g were synthesized from ZnCl2 and Chitosan and characterized by X‐ray diffraction, high resolution transmission electron microscopy (HRTEM), and scanning electron microscopy (SEM). Natural rubber (NR) vulcanizates containing nano ZnO was prepared by mill mixing and characterized by SEM, energy dispersive X‐ray analysis (EDAX), and HRTEM. Cure characteristics, free volume studies, bound rubber, crosslink density, and dynamic mechanical properties were evaluated and compared with that of NR vulcanizate containing conventional micro ZnO. Considering the cure characteristics, it was found that NR vulcanizate with 0.5 phr (parts per 100 g rubber) of nano ZnO showed low values of optimum cure time (t90) and very high cure rate index compared with 5 phr of conventional micro ZnO. The study shows that micro ZnO can be successfully replaced with nano ZnO for accelerated sulfur vulcanization process in NR, and preparation of vulcanizate containing nano ZnO with better properties as that of micro ZnO. The optimum dosage of nano ZnO as a cure activator in NR vulcanization was found to be 0.5 phr compared with conventional grade micro ZnO. This will lead to substantial cost reduction in the manufacture of rubber products and alleviate environmental pollution due to excess ZnO in rubber compounds. POLYM. ENG. SCI., 2013 © 2013 Society of Plastics Engineers 相似文献
957.
An experimental study was conducted to investigate the effect of pressure-cycling on adhesive bond fracture energy of polyurethane/aluminum adhesive bond joints. Initially, two types of peel tests were conducted to characterize adhesive bond strength and challenges associated with pre-mature polyurethane cracking and failure during these tests are discussed. A modified double cantilever beam (MDCB) specimen configuration was specially designed and opening-mode loading conditions were employed to determine the interfacial adhesive bond energy (GC). The test specimens were pressure-cycled in water-filled tanks for 1 to 4 weeks with an increment of 1 week. The GC of pressure-cycled specimens was compared with both control and water-soaked samples (without pressure-cycling). The results indicated that pressure-cycling decreased GC values to those of the control and water-soaked samples: hence, prolonged pressure-cycling could be problematic to polymer/metal adhesive bonds of hardware installed outboard of submarine pressure hulls. 相似文献
958.
Thomas M. Maloney 《The Journal of Adhesion》2013,89(3-4):181-187
Gluing is of tremendous importance to the wood industry. About 70% of all wood used today involves gluing. As an increasing amount of lower quality wood is used in the future, gluing will become even more important. Additional developments in harvesting previously unused species and forest residues and cleaning dirty material, and a means to reclaim urban waste wood, are needed to assure an adequate wood supply. New or improved economical adhesive systems will be important in accelerating the development of glued products. The future of the wood products industry lies with the use of glue, since the wood raw material will continue to be harvested in ever smaller sizes. 相似文献
959.
The “three-liquid” contact angle approach to the surface free energy components of solids was applied to poly (vinyl fluoride), rough and flattened, with and without flame treatment. Lifshitz-van der Waals (LW), γ LW SL , and acid-base (AB), γ LW SL , components were determined and used to calculate ?δG SL (W adhesion SL ) for the formation of interfaces of five liquids with polymer. The automated goniometer allowed the determination of the energy barriers, ?δ G? SL as the advancing liquid moved from pinned configuration to a metastable one. The acid-base component of the barriers was much greater than the LW, and the magnitude of the barriers was only slightly reduced by flattening. 相似文献
960.
Yang Liu Thomas Lafitte Athanassios Z. Panagiotopoulos Pablo G. Debenedetti 《American Institute of Chemical Engineers》2013,59(9):3514-3522
Direct interfacial molecular dynamics simulations are used to obtain the phase behavior and interfacial tension of CO2–H2O–NaCl mixtures over a broad temperature and pressure range (50°C ≤ T ≤ 250°C, 0 ≤ P ≤ 600 bar) and NaCl concentrations (1–4 mol/kg H2O). The predictive ability of several existing water (SPC and TIP4P2005), carbon dioxide (EPM2 and TraPPE), and sodium chloride (SD and DRVH) models is studied and compared, using conventional Lorentz–Berthelot combining rules for the unlike‐pair parameters. Under conditions of moderate NaCl molality (~1 mol/kg H2O), the predictions of the CO2 solubility in the water‐rich and CO2‐rich phase resemble those in the CO2–H2O system [Liu et al., J Phys Chem B. 2011;115:6629–6635]. Consistent with our previous work, the TraPPE/TIP4P2005 model combination gives the best overall performance in predicting coexistence composition and pressure in the water‐rich phase. Critical assessments are also made on the ranges of temperature and pressure where particular model combinations work better. The dependence of the interfacial tension on temperature and pressure is better predicted by the TraPPE/TIP4P2005 and EPM2/SPC models, whereas the EPM2/TIP4P2005 model overestimates this property by 10–20%, possibly due to the inadequacy of the combining rules. It is also found that the interfacial tension increases with salt concentration, consistent with experimental observations. © 2013 American Institute of Chemical Engineers AIChE J, 59: 3514–3522, 2013 相似文献